Citation:
MA Qiang, HU Yongsheng, LI Hong, CHEN Liquan, HUANG Xuejie, ZHOU Zhibin. An Sodium Bis (trifluoromethanesulfonyl) imide-based Polymer Electrolyte for Solid-State Sodium Batteries[J]. Acta Physico-Chimica Sinica,
;2018, 34(2): 213-218.
doi:
10.3866/PKU.WHXB201707172
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A solid polymer electrolyte (SPE), composed of sodium bis(trifluoromethanesulfonyl)imide (NaTFSI) and poly(ethylene oxide) (PEO), is prepared by a simple solution-casting method. The physicochemical and electrochemical properties of the NaTFSI/PEO ([EO]/[Na+]=15) SPE in terms of its phase transitions, crystallization, thermal stability, ionic conductivity, and anodic electrochemical stability are systematically investigated. We demonstrate that the NaTFSI/PEO SPE has a relatively high ionic conductivity (σ ≈ 10-3 S·cm-1) at 80℃, excellent electrochemical stability (4.86 V vs. Na+/Na), and thermal stability up to 350℃. More importantly, the NaTFSI-based SPE delivers not only excellent chemical and electrochemical stability with sodium metal, but also good cycling and rate performances in an Na|SPE|NaCu1/9Ni2/9Fe1/3Mn1/3O2 cell.
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[1]
-
[2]
-
[3]
-
[4]
-
[5]
-
[6]
-
[7]
-
[8]
-
[9]
-
[10]
-
[11]
-
[12]
-
[13]
-
[14]
-
[15]
-
[16]
-
[17]
-
[18]
-
[19]
-
[20]
-
[21]
-
[22]
-
[1]
-
-
-
[1]
LI Ya-Juan , ZHAN Hui , LIU Su-Qin , HUANG Ke-Long , ZHOU Yun-Hong . Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte. Acta Physico-Chimica Sinica, 2010, 26(09): 2387-2391. doi: 10.3866/PKU.WHXB20100818
-
[2]
Cui Minhui , Wu Zhenghua , Qiu Sichou , Xie Hongquan . Electrochromic Window Based on Polyoxyethylene-Lithium Perchlorate Complex. Chinese Journal of Applied Chemistry, 1996, 13(6): 39-41.
-
[3]
Jing Xiabin , Wang Baochen , Peng Xinsheng , Feng Li , Song Yongxian . All Solid State Polyaniline Lithium Battery. Chinese Journal of Applied Chemistry, 1994, 11(1): 50-53.
-
[4]
XIN Zhi-Rong , DING Yong-Tao , KE Zhuo , CAI Chuan-Lun , GAO Ying , YIN Jing-Hua . Preparation and Characterization of the New Nonionic Surfactants. Chinese Journal of Applied Chemistry, 2002, 19(8): 723-726.
-
[5]
Yao Song-Nian . Studies of the Fractal Dimension of Aggregation of Polystyrene Labices Sterically Stabilized by Poly(ethyleneoxide) in the Solution of MgSO4. Acta Physico-Chimica Sinica, 1995, 11(10): 945-949. doi: 10.3866/PKU.WHXB19951019
-
[6]
Hai Ming-Tan , Gao Jie , Han Bu-Xing , Yan Hai-Ke , Liu Yun , Han Qi-Yong . Vapour Pressure and Surface Tension of Aqueous Solution SDS-PEO. Acta Physico-Chimica Sinica, 1998, 14(08): 747-751. doi: 10.3866/PKU.WHXB19980815
-
[7]
LIANG Gui-Jie , ZHONG Zhi-Cheng , XU Jie , ZHANG Zeng-Chang , CHEN Mei-Hua , LI Zai-Fang , HE Ping . Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte. Acta Physico-Chimica Sinica, 2012, 28(12): 2852-2860. doi: 10.3866/PKU.WHXB201210091
-
[8]
Tang Zhi-uan , WANG Zhan-Liang , XUE Jian-Jun , LIU Chun-Yan . Influence of Plasticizers on Polymer Electrolyte Lithium Ion Battery. Chinese Journal of Applied Chemistry, 2002, 19(6): 560-563.
-
[9]
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-
[10]
SONG Zhao-Shuang , QI Lu , QIU Jing-Yi , MA Jian-Wei . Preparation and Characterization of γ-Ray Irradiated Gel Polymer Electrolyte for Lithium-Ion Polymer Batteries. Acta Physico-Chimica Sinica, 2007, 23(12): 1932-1936. doi: 10.3866/PKU.WHXB20071219
-
[11]
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-
[12]
CHEN Lang , RAO Mu-Min , LI Wei-Shan , XU Meng-Qing , LIAO You-Hao , TAN Chun-Lin , YI Jin . Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent. Acta Physico-Chimica Sinica, 2011, 27(07): 1689-1694. doi: 10.3866/PKU.WHXB20110712
-
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FENG Hua-Jun , CHEN Yuan , DAI Ke-Hua , SONG Zhao-Shuang , MA Jian-Wei , QI Lu . Preparation and Characterization of a Novel Kind of Polymer Electrolyte Composite Membrane for Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2007, 23(12): 1922-1926. doi: 10.3866/PKU.WHXB20071217
-
[14]
GUO Xue-Yi , YI Peng-Fei , WANG Wei-Jia , YANG Ying . Electrochemical Properties of an Agarose-Based Magnetic Polymer Electrolyte in Dye-Sensitized Solar Cells. Acta Physico-Chimica Sinica, 2012, 28(03): 585-590. doi: 10.3866/PKU.WHXB201112302
-
[15]
CHEN Xiaohua , GUO Jianping , CHEN Lin , TANG Binyan , YIN Dulin . Preparation and Modification of Poly(methyl methacrylate)-based Gel Polymer Electrolytes Containing [AMIM] BF4. Chinese Journal of Applied Chemistry, 2011, 28(8): 869-873. doi: 10.3724/SP.J.1095.2011.00515
-
[16]
GU Ningyu , YU Dianbao , XIE Yuanyuan , YANG Zhenyu , ZHANG Rongbin , LIU Feng . Preparation and Electrochemical Performance of PEO Based Polymer Electrolyte Containing Pentaerythritol Tetrakis(2-methoxyethyl ether) and Lithium Methoxy Oligo(oxyethylene) sulfate. Chinese Journal of Applied Chemistry, 2011, 28(1): 48-54. doi: 10.3724/SP.J.1095.2011.00251
-
[17]
Kang Shusen , Yang Chengxiang , Yang Zelin , Wu Ningning , Zhao Shan , Chen Xiaotao , Liu Fuliang , Shi Bin . Blending Based PEO-PAN-PMMA Gel Polymer Electrolyte Prepared by Spaying Casting for Solid-state Lithium Metal Batteries. Acta Chimica Sinica, 2020, 78(12): 1441-1447. doi: 10.6023/A20080356
-
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-
[19]
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-
[20]
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