微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

引用本文: 蒙延双, 王琛, 王磊, 王功瑞, 夏军, 朱福良, ZHANG Yue. 微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料[J]. 物理化学学报, 2017, 33(9): 1915-1922. doi: 10.3866/PKU.WHXB201705083 shu

Citation: MENG Yan-Shuang, WANG Chen, WANG Lei, WANG Gong-Rui, XIA Jun, ZHU Fu-Liang, ZHANG Yue. Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid[J]. Acta Physico-Chimica Sinica, 2017, 33(9): 1915-1922. doi: 10.3866/PKU.WHXB201705083 shu

微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

蒙延双 ^1,3, ,
王琛 ^1, ,
王磊 ^1, ,
王功瑞 ^1, ,
夏军 ^1, ,
朱福良 ^1,3, ,
ZHANG Yue ^2,

1.
兰州理工大学材料科学与工程学院, 兰州 730050;
2.
Department of Mechanical and Industrial Engineering, Texas A&M University-Kingsville, Kingsville, Texas 78363, USA;
3.
省部共建有色金属先进加工与再利用国家重点实验室, 兰州 730050
基金项目:
国家自然科学基金（51364024, 51404124），甘肃省自然科学基金（1506RJZA100），甘肃省基础研究创新群体计划项目（1606RJIA322）资助

摘要: 采用一步微波辅助裂解离子液体法制备了硫氮共掺杂多孔碳材料。用傅里叶变换红外（FT-IR）光谱，拉曼光谱，X射线衍射（XRD），电子显微镜和X射线光电子能谱（XPS）等检测手段对裂解产物的结构和形貌进行了表征。对微波辐照下离子液体1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐（EMImNTf₂）的裂解机理进行了分析。结果表明，微波辐照能够促进EMImNTf₂的裂解，使其在320 ℃下裂解得到硫氮共掺杂的多孔碳材料。离子液体EMImNTf₂的阳离子作为多孔碳材料骨架的前驱体，而阴离子作为硫源和造孔剂。制备的硫氮共掺杂多孔碳材料具有含缺陷的石墨结构。石墨碳基体中氮和硫的原子百分含量分别为12.84%和1.07%，其中N原子主要取代C成为活性点，而S原子主要存在于边界和缺陷处。

关键词:

English

Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid

1.
School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China;
2.
Department of Mechanical and Industrial Engineering, Texas A&M University-Kingsville, Kingsville, Texas 78363, USA;
3.
State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou 730050, P. R. China
Received Date: 22 March 2017
Revised Date: 28 April 2017
Available Online: 08 May 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (51364024, 51404124), Natural Science Foundation of Gansu Province, China (1506RJZA100), and the Foundation for Innovation Groups of Basic Research inGansuProvince, China (1606RJIA322).

Abstract: Sulfur and nitrogen co-doped porous carbon (SNDPC) was successfully synthesized using one-step microwave-assisted pyrolysis of ionic liquid. The structure and morphology of the pyrolysis products were characterized by Fourier-transform infrared (FT-IR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD), electron microscopy, and X-ray photoelectron spectroscopy (XPS). The pyrolysis mechanism of the ionic liquid 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide (EMImNTf₂) under microwave irradiation was discussed. Microwave irradiation was found to accelerate the pyrolysis of EMImNTf₂. The cation of EMImNTf₂ works as the precursor of the carbon backbone of the porous carbon, while the anion acts as sulfur source and porosity-directing regulator. The SNDPC was obtained at 320 ℃ and exhibited graphitic structure with numerous surface defects. The atomic percentages of N and S in SNDPC were 12.84% and 1.07%, respectively. The N atoms mainly substitute the C sites in the graphitic carbon matrix, whereas the S atoms mainly bond to the ledges and defects of the carbon matrix.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

English

Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

微波辅助裂解离子液体制备硫氮共掺杂多孔碳材料

English

Efficient Synthesis of Sulfur and Nitrogen Co-Doped Porous Carbon by Microwave-Assisted Pyrolysis of Ionic Liquid

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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