两种疏水型膦类离子液体的密度、动力粘度及电导率

引用本文: 郑其格, 刘惠, 夏泉, 刘青山, 牟林. 两种疏水型膦类离子液体的密度、动力粘度及电导率[J]. 物理化学学报, 2017, 33(4): 736-744. doi: 10.3866/PKU.WHXB201612293 shu

Citation: ZHENG Qi-Ge, LIU Hui, XIA Quan, LIU Qing-Shan, MOU Lin. Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 736-744. doi: 10.3866/PKU.WHXB201612293 shu

两种疏水型膦类离子液体的密度、动力粘度及电导率

郑其格 ^1, ,
刘惠 ^2,3, ,
夏泉 ^1, ,
刘青山 ^1,4, ,
牟林 ^1,

1.
沈阳农业大学理学院, 沈阳 110866;
2.
上海环境卫生工程设计院, 上海 200232;
3.
上海污染场地修复工程技术研究中心, 上海 200232;
4.
沈阳农业大学土地与环境学院, 沈阳 110866
基金项目:
辽宁省高等学校优秀人才支持计划（LJQ2015099）资助项目

摘要: 通过传统的方法，制备了两种对水和空气稳定的四烷基膦类离子液体。离子液体是：己基三丁基膦四氟化硼和己基三丁基膦双三氟甲基磺酸亚胺。在T = 283.15-353.15 K温度范围内，测定了两个离子液体的密度、动力粘度及电导率。讨论了温度、阴离子结构对离子液体的性质的影响。结合文献报道的其它离子液体，讨论了该类离子液体性质随阳离子结构的变化规律，并与咪唑类离子液体的性质进行了比较。通过经验方程，利用密度数据计算了两个离子液体的重要热力学性质参数，例如：分子体积、标准摩尔熵及晶格能等。并将估算性质与传统的咪唑、吡啶类离子液体进行了对比。通过密度和电导率确定了离子液体的摩尔电导率。讨论了Vogel-Fulcher-Tamman （VFT）方程和Arrhenius 方程对于粘度和电导率拟合的可行性，并估算了电导活化能及流动活化能。通过Walden 规则，描述了密度、粘度及电导率之间的联系。有关研究对新型离子液体的合成及其工业化的应用具有十分重要意义。

关键词:

English

Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids

1.
School of Science, Shenyang Agricultural University, Shenyang 110866, P. R. China;
2.
Shanghai Environmental Sanitation Engineering Design Institute, Shanghai 200232, P. R. China;
3.
Shanghai Engineering Research Center of Contaminated Sites Remediation, Shanghai 200232, P. R. China;
4.
College of Land and Environment, Shenyang Agricultural University, Shenyang 110866, P. R. China
Received Date: 10 November 2016
Revised Date: 29 December 2016
Available Online: 29 December 2016
Fund Project:
The project was supported by the Program for Liaoning Excellent Talents in University, China (LJQ2015099).

Abstract: Two air and water stable hydrophobic phosphonium ionic liquids (ILs), tributyl-hexylphosphonium tetrafluoroborate ([P4446][BF4]) and tributyl-hexylphosphonium bis(trifluoromethylsulfonyl)imide ([P4446][NTf2]), were prepared by the traditional method. Their basic physico-chemical properties of density, dynamic viscosity, and electrical conductivity were measured in the temperature range of 283.15-353.15 K. The effect of the temperature and structure of the anion on the thermodynamic properties were discussed. The properties are compared with the cation structures changing of the phosphonium type ILs. The most important thermodynamic properties for their practical application, such as molecular volume, standard molar entropy, and lattice energy, were calculated from their density using empirical equations. The calculated values were compared with those of imdazolium and pyridinium type ILs. Molar electrical conductivity was determined from density and electrical conductivity. The applicability of the Vogel-Fulcher-Tamman (VFT) and Arrhenius equations to the fitting of the dynamic viscosity and electrical conductivity was validated. The activation of the electrical conductivity and dynamic viscosity were obtained from the final VFT equation. According to the Walden rule, the density, dynamic viscosity, and electrical conductivity were described by the Walden equation. The results are very important for academic studies as well as industrial applications of these ILs.

Key words:

1. [1]
  Rantwijk, F. V.; Sheldon, R. A. Chem. Rev. 2007, 107, 2757. doi: 10.1021/cr050946x
2. [2]
  Greaves, T. L.; Drummond, C. J. Chem. Rev. 2008, 108, 206. doi: 10.1021/cr068040u
3. [3]
  Hapiot, P.; Lagrost, C. Chem. Rev. 2008, 108, 2238. doi: 10.1021/cr0680686
4. [4]
  Jessop, P. G.; Subramaniam, B. Chem. Rev. 2007, 107, 2666. doi: 10.1021/cr040199o
5. [5]
  Tsunashima, K.; Sugiya, M. Electrochem. Commun. 2007, 9, 2353. doi: 10.1016/j.elecom.2007.07.003
6. [6]
  Tsunashima, K.; Sugiya, M. Electrochemistry 2007, 75, 734. doi: 10.5796/electrochemistry.75.734
7. [7]
  Vega, J. A.; Zhou, J.; Kohl, P. A. J. Electrochem. Soc. 2009, 156, A253. doi: 10.1149/1.3070657
8. [8]
  Pomaville, R. M.; Poole, S. K.; Davis, L. J.; Poole, C. F. J. Chramatogr. 1988, 438, 1. doi: 10.1016/S0021-9673(00)90227-9
9. [9]
  Breitbach, Z. S.; Armstrong, D.W. Anal. Bioanal. chem. 2008, 390, 1605. doi: 10.1007/s00216-008-1877-3
10. [10]
  Fukumoto, K.; Ohno, H. Angew. Chem. Int. Ed. 2007, 46, 1852. doi: 10.1002/anie.200604402
11. [11]
  Kohno, Y.; Deguchi, Y. Ohno, H. Chem. Commun. 2012, 48, 11883. doi: 10.1039/c2cc36913c
12. [12]
  Kohno, Y.; Arai, H.; Saita, S.; Ohno, H. Aust. J. Chem. 2011, 64, 1560. doi: 10.1071/CH11278
13. [13]
  Kohno, Y.; Arai, H.; Ohno, H. Chem. Commun. 2011, 47, 4772. doi: 10.1039/C1CC10613A
14. [14]
  Wang, C.; Luo, X.; Luo, H.; Jiang, D.; Li, H.; Dai, S. Angew. Chem. Int. Ed. 2011, 50, 4918. doi: 10.1002/anie.201008151
15. [15]
  Wang, C.; Cui, G.; Luo, X.; Xu, Y.; Li, H.; Dai, S. J. Am. Chem. Soc. 2011, 133, 11916. doi: 10.1021/ja204808h
16. [16]
  Blundell, R. K.; Licence, P. Phys. Chem. Chem. Phys. 2014, 16, 15278. doi: 10.1039/C4CP01901F
17. [17]
  Chen, F. F.; Dong, Y.; Sang, X. Y.; Zhou, Y.; Tao, D. J. Acta Phys. -Chim. Sin. 2016, 32, 605. [陈凤凤, 董艳, 桑晓燕, 周言, 陶端健. 物理化学学报, 2016, 32, 605.] doi: 10.3866/PKU.WHXB201512241
18. [18]
  Ferreira, A. F.; Simões, P. N.; Ferreira, A. G. M. J. Chem. Thermodynamics 2012, 45, 16. doi: 10.1016/j.jct.2011.08.019
19. [19]
  Tariq, M.; Forte, P. A. S.; Gomes, M. F. C.; Lopes, J. N. C.; Rebelo, L. P. N. J. Chem. Thermodynamics 2009, 41, 790. doi: 10.1016/j.jct.2009.01.012
20. [20]
  Diogo, J. C. F.; Caetano, F. J. P.; Fareleira, J. M. N. A.; Wakeham, W. A. J. Chem. Eng. Data 2012, 57, 1015. doi: 10.1021/je200830j
21. [21]
  Goodrich, B. F.; Fuente, J. C. de la; Gurkan, B. E.; Lopez, Z. K.; Price, E. A.; Huang, Y.; Brennecke, J. F. J. Phys. Chem. B 2011, 115, 9140. doi: 10.1021/jp2015534
22. [22]
  Baldo, M. A.; Oliveri, P.; Simonetti, R.; Daniele, S. J. Electroanal. Chem. 2014, 731, 43. doi: 10.1016/j.jelechem.2014.08.001
23. [23]
  Li, A.; Tian, Z.; Yan, T.; Jiang, D.; Dai, S. J. Phys. Chem. B 2014, 118, 14880. doi: 10.1021/jp5100236
24. [24]
  Tong, J.; Zhang, Q. G.; Hong, M.; Yang, J. Z. Acta Phys. -Chim. Sin. 2006, 22, 71. [佟静, 张庆国, 洪梅, 杨家振. 物理化学学报, 2006, 22, 71.] doi: 10.3866/PKU.WHXB20060114
25. [25]
  Tong, J.; Chen, T. F.; Zhang, D.; Wang, L. F.; Tong, J.; Yang, J.Z. Acta Phys. -Chim. Sin. 2016, 32, 1161. [佟静, 陈滕飞, 张朵, 王林富, 佟健, 杨家振. 物理化学学报, 2016, 32, 1161.] doi: 10.3866/PKU.WHXB201602232
26. [26]
  Bu, X. X.; Fan, B. H.; Wei, J.; Xing, N. N.; Ma, X. X.; Guan, W. Acta Phys. -Chim. Sin. 2016, 32, 267. [卜晓雪, 樊本汉, 魏杰, 邢楠楠, 马晓雪, 关伟. 物理化学学报, 2016, 32, 267.] doi: 10.3866/PKU.WHXB201510303
27. [27]
  Hoogerstraete, T. V.; Binnemans, K. Green Chem. 2014, 16, 1594. doi: 10.1039/C3GC41577E
28. [28]
  Ferreira, C. E.; Talavera-Pieto, N. M. C.; Fonseca, I. M. A.; Portugal, A. T. G.; Ferreira, A. G. M. J. Chem. Thermodynamics 2012, 47, 183. doi: 10.1016/j.jct.2011.10.012
29. [29]
  Hayyan, M.; Mjalli, F. S.; Hashim, M. A.; AlNashef, I. M.; Tan, X. M.; Chooi, K. L. J. Appl. Sci. 2010, 10, 1176. doi: 10.3923/jas.2010.1176.1180
30. [30]
  Tong, B.; Liu, Q. S.; Tan, Z. C.; Welz-Biermann, U. J. Phys. Chem. A 2010, 114, 3782. doi: 10.1021/jp9047538
31. [31]
  Liu, Q. S.; Yang, M.; Li, P. P.; Sun, S. S.; Welz-Biermann, U.; Tan, Z. C.; Zhang, Q. G. J. Chem. Eng. Data 2011, 56, 4094. doi: 10.1021/je200534b
32. [32]
  Glasser, L. Thermochim. Acta 2004, 421, 87. doi: 10.1021/je200830j
33. [33]
  McEwen, A. B.; Ngo, H. L.; LeCompte, K.; Goldman, J. L. J. Electrochem. Soc. 1999, 146, 1687. doi: 10.1149/1.1391827
34. [34]
  Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172. doi: 10.1039/B513231B
35. [35]
  Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRCPress: Boca Raton, FL, 2001-2002.
36. [36]
  Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Chen, J.; Liu, X. X. J. Chem. Thermodynamics 2 013, 66, 88. doi: 10.1016/j.jct.2013.06.008
37. [37]
  Cheng, Z.; Lee, J. M. J. Phys. Chem. B 2014, 118, 2712. doi: 10.1021/jp411904w
38. [38]
  Zhang, Q. G.; Wei, Y.; Sun, S. S.; Wang, C.; Yang, M.; Liu, Q.S.; Gao, Y. A. J. Chem. Eng. Data 2012, 57, 2185. doi: 10.1021/je300153f
39. [39]
  Liu, Q. S.; Li, P. P.; Welz-Biermann, U.; Liu, X. X.; Chen, J. J. Chem. Eng. Data 2012, 57, 2999. doi: 10.1021/je3004645
40. [40]
  Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.; Welz-Biermann, U. J. Chem. Eng. Data 2010, 55, 4928. doi: 10.1021/je100507n
41. [41]
  Fang, D.W.; Tong, J.; Guan, W.; Wang, H.; Yang, J. Z. J. Phys. Chem. B 2010, 114, 13808. doi: 10.1021/jp107452q
42. [42]
  Fang, D.W.; Guan, W.; Tong, J.; Wang, Z.W.; Yang, J. Z. J. Phys. Chem. B 2008, 112, 7499. doi: 10.1021/jp801269u
43. [43]
  Tong, J.; Song, B.; Wang, C. X.; Li, L.; Guan, W.; Fang, D.W.; Yang, J. Z. Ind. Eng. Chem. Res. 2011, 50, 2418. doi: 10.1021/ie101903t
44. [44]
  Xu, W. G.; Ma, X. X.; Li, L.; Tong, J.; Guan, W. Ind. Eng. Chem. Res. 2012, 51, 4105. doi: 10.1021/ie201530b
45. [45]
  Liu, Q. S.; Tong, J.; Tan, Z. C.; Welz-Biermann, U.; Yang, J. Z. J. Chem. Eng. Data 2010, 55, 2586. doi: 10.1021/je901035d
46. [46]
  Vila, J.; Ginés, P.; Pico, J. M.; Franjo, C.; Jiménez, E.; Varela, L.M.; Cabeza, O. Fluid Phase Equilibria 2006, 242, 141. doi: 10.1016/j.uid.2006.01.022
47. [47]
  Yoshizawa, M.; Xu, W.; Angell, C. A. J. Am. Chem. Soc. 2003, 125, 15411. doi: 10.1021/ja035783d
48. [48]
  Angell, C. A.; Byrne, N.; Belieres, J. P. Acc. Chem. Res. 2007, 40, 1228. doi: 10.1021/ar7001842
49. [49]
  Xu, W.; Cooper, E. I.; Angell, C. A. J. Phys. Chem. B 2003, 107, 6170. doi: 10.1021/jp0275894
50. [50]
  MacFarlane, D. R.; Forsyth, M.; Izgorodina, E. I.; Abbott, A. P.; Annat, G.; Fraser, K. Phys. Chem. Chem. Phys. 2009, 11, 4962. doi: 10.1039/B900201D
51. [51]
  Belieres, J. P.; Angell, C. A. J. Phys. Chem. B 2007, 111, 4926. doi: 10.1021/jp067589u
52. [52]
  Cheng, Z.; Lee, J. M. J. Phys. Chem. B 2014, 118, 2712. doi: 10.1021/jp411904w
53. [53]
  Liu, Q. S.; Yan, P. F.; Yang, M.; Tan, Z. C.; Li, C. P.; Welz-Biermann, U. Acta Phys. -Chim. Sin. 2011, 27, 2762. [刘青山, 颜佩芳, 杨淼, 谭志诚, 李长平, Welz-Biermann, Urs. 物理化学学报, 2011, 27, 2762.] doi: 10.3866/PKU.WHXB20112762

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

两种疏水型膦类离子液体的密度、动力粘度及电导率

English

Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

两种疏水型膦类离子液体的密度、动力粘度及电导率

English

Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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