Citation: WANG Yue, JIANG Quan, SHANG Jie-Kun, XU Jie, LI Yong-Xin. Advances in the Synthesis of Mesoporous Carbon Nitride Materials[J]. Acta Physico-Chimica Sinica, ;2016, 32(8): 1913-1928. doi: 10.3866/PKU.WHXB201605052 shu

Advances in the Synthesis of Mesoporous Carbon Nitride Materials

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China

Received Date: 1 March 2016
Revised Date: 4 May 2016

Fund Project: The project was supported by the National Natural Science Foundation of China (21203014), Postgraduate Innovation Project of Jiangsu Province, China (KYLX14_1097, KYLX15_1119), Project Funded by Priority Academic Program Development of Jiangsu Higher Education Institutions, China, and Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, China (ACGM2016-06-28)

Graphitic carbon nitride (g-C₃N₄) is a new metal-free material. Owing to its multiple unique physicochemical properties, g-C₃N₄ has promising applications in various research fields, including heterogeneous catalysis, photocatalysis, fuel cells, and gas storage. Compared with bulk g-C₃N₄ prepared via direct thermal condensation, mesoporous g-C₃N₄ possesses a higher surface area and abundant accessible mesoporous pores. These features expose many more surface active sites, thereby improving the performance of this material in catalysis as well as in other applications. Thermal condensation is the most convenient strategy to prepare g-C₃N₄ and, when fabricating mesoporous g-C₃N₄, one may employ hard-, soft-, or non-templating method. This paper reviews recent advances in the synthesis of mesoporous g-C₃N₄ using all three routes. Specifically, several crucial issues regarding the hard-templating method are discussed with regard to the synthetic mechanism associated with various precursors and the physicochemical properties of the g-C₃N₄ products. Novel soft- and non-templating approaches for the preparation of mesoporous g-C₃N₄ are also addressed and a detailed comparison to the hard-templating method is provided. Finally, future prospects for the development of mesoporous g-C₃N₄ materials are also assessed.
- Graphitic carbon nitride,
- Mesoporous material,
- Nanocasting method,
- Hard-templating method,
- Soft-templating method
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