Citation: LI Yang, WANG Jia-Dao, FAN Li-Ning, CHEN Da-Rong. Feasible Fabrication of a Durable Superhydrophobic Coating on Polyester Fabrics for Oil-Water Separation[J]. Acta Physico-Chimica Sinica, ;2016, 32(4): 990-996. doi: 10.3866/PKU.WHXB201601131 shu

Feasible Fabrication of a Durable Superhydrophobic Coating on Polyester Fabrics for Oil-Water Separation

1.
State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, P. R. China

Corresponding author: WANG Jia-Dao,
Received Date: 13 November 2015
Available Online: 12 January 2016
Fund Project: 国家自然科学基金(51375253, 51321092)资助项目 (51375253, 51321092)

A durable superhydrophobic coating on polyester fabrics has been fabricated by a simple solutionimmersion method in a solution consisting of a methyl MQ (M: mono-functional silicon-oxygen unit R₃SiO_1/2, Q: tetra-functional silicon-oxygen unit SiO₂) silicone resin and hydrophobic silica nanoparticles. After coating, the microstructured fibers were wrapped by compact hydrophobic nanoparticles that could lower the surface energy of the fibers. Therefore, the obtained fabric exhibited an excellent superhydrophobic property with a water contact angle of 156° and a sliding angle of 5°. It is worth mentioning that the as-prepared fabric was proved to be able to withstand extreme environmental conditions such as mechanical abrasion, acidic and alkaline attack, and UV irradiation. The practical application of the modified fabric for oil-water separation was also demonstrated with a high separation efficiency above 99%. This feasible fabrication method paves the way for using the superhydrophobic fabric on a large scale.
- Superhydrophobicity,
- Polyester fabric,
- Nanoparticle,
- Durability,
- Oil-water separation
1. [1]
  (1) Barthlott, W.; Neinhuis, C. Planta 1997, 202, 1. doi: 10.1007/s004250050096
2. [2]
  (2) Miwa, M.; Nakajima, A.; Fujishima, A.; Hashimoto, K.; Watanabe, T. Langmuir 2000, 16, 5754. doi: 10.1021/la991660o
3. [3]
  (3) Solga, A.; Cerman, Z.; Striffler, B. F.; Spaeth, M.; Barthlott, W. Bioinspir. Biomim. 2007, 2, S126.
4. [4]
  (4) Yao, X.; Song, Y.; Jiang, L. Adv. Mater. 2011, 23, 719. doi: 10.1002/adma.201002689
5. [5]
  (5) Wang, S.; Feng, L.; Jiang, L. Adv. Mater. 2006, 18, 767.
6. [6]
  (6) Zhang, Y. F.;Wu, J.; Yu, X. Q.; Liang, C. H.;Wu, J. Acta Phys. -Chim. Sin. 2014, 30, 1970. [张友法, 吴洁, 余新泉, 梁彩华, 吴俊. 物理化学学报, 2014, 30, 1970.] doi: 10.3866/PKU.WHXB201408045
7. [7]
  (7) Wang, D.; Zhang, Z.; Li, Y.; Xu, C. ACS Appl. Mater. Interfaces 2014, 6, 10014. doi: 10.1021/am405884x
8. [8]
  (8) Xu, L.; Karunakaran, R. G.; Guo, J.; Yang, S. ACS Appl. Mater. Interfaces 2012, 4, 1118. doi: 10.1021/am201750h
9. [9]
  (9) Du, C.;Wang, J.; Chen, Z.; Chen, D. Appl. Surf. Sci. 2014, 313, 304. doi: 10.1016/j.apsusc.2014.05.207
10. [10]
  (10) Ogihara, H.; Xie, J.; Okagaki, J.; Saji, T. Langmuir 2012, 28, 4605. doi: 10.1021/la204492q
11. [11]
  (11) Li, S.; Zhang, S.;Wang, X. Langmuir 2008, 24, 5585. doi: 10.1021/la800157t
12. [12]
  (12) Khalil-Abad, M. S.; Yazdanshenas, M. E. J. Colloid Interface Sci. 2010, 351, 293. doi: 10.1016/j.jcis.2010.07.049
13. [13]
  (13) Zhou, X.; Zhang, Z.; Xu, X.; Guo, F.; Zhu, X.; Men, X.; Ge, B. ACS Appl. Mater. Interfaces 2013, 5, 7208. doi: 10.1021/am4015346
14. [14]
  (14) Xue, C. H.; Jia, S. T.; Zhang, J.; Tian, L. Q. Thin Solid Films 2009, 517, 4593. doi: 10.1016/j.tsf.2009.03.185
15. [15]
  (15) Zhao, Y.; Xu, Z.;Wang, X.; Lin, T. Langmuir 2012, 28, 6328. doi: 10.1021/la300281q
16. [16]
  (16) Hoefnagels, H.;Wu, D.; DeWith, G.; Ming, W. Langmuir 2007, 23, 13158. doi: 10.1021/la702174x
17. [17]
  (17) Synytska, A.; Khanum, R.; Ionov, L.; Cherif, C.; Bellmann, C. ACS Appl. Mater. Interfaces 2011, 3, 1216. doi: 10.1021/am200033u
18. [18]
  (18) Wu, L.; Zhang, J.; Li, B.; Fan, L.; Li, L.;Wang, A. J. Colloid Interface Sci. 2014, 432, 31. doi: 10.1016/j.jcis.2014.06.046
19. [19]
  (19) Zhang, J.; Seeger, S. Adv. Funct. Mater. 2011, 21, 4699. doi: 10.1002/adfm.v21.24
20. [20]
  (20) Wang, L.; Yang, S.;Wang, J.;Wang, C.; Chen, L. Mater. Lett. 2011, 65, 869. doi: 10.1016/j.matlet.2010.12.024
21. [21]
  (21) Gao, X.; Yan, X.; Yao, X.; Xu, L.; Zhang, K.; Zhang, J.; Yang, B.; Jiang, L. Adv. Mater. 2007, 19, 2213.
22. [22]
  (22) Darmanin, T.; Guittard, F. J. Am. Chem. Soc. 2011, 133, 15627. doi: 10.1021/ja205283b
23. [23]
  (23) Zhang, M.;Wang, C.;Wang, S.; Shi, Y.; Li, J. Appl. Surf. Sci. 2012, 261, 764. doi: 10.1016/j.apsusc.2012.08.097
24. [24]
  (24) Dorrer, C.; Rühe, J. Soft Matter 2009, 5, 51. doi: 10.1039/ B811945G
25. [25]
  (25) Xue, C. H.; Ma, J. Z. J. Mater. Chem. A 2013, 1, 4146. doi: 10.1039/C2TA01073A
26. [26]
  (26) Wang, J.; Chen, D. Langmuir 2008, 24, 10174. doi: 10.1021/la801092y
27. [27]
  (27) Chen, S.;Wang, J.; Ma, T.; Chen, D. J. Chem. Phys. 2014, 140, 114704. doi: 10.1063/1.4868641
28. [28]
  (28) Zhu, X.; Zhang, Z.; Yang, J.; Xu, X.; Men, X.; Zhou, X. J. Colloid Interface Sci. 2012, 380, 182. doi: 10.1016/j.jcis.2012.04.063
29. [29]
  (29) Zhou, H.;Wang, H.; Niu, H.; Gestos, A.;Wang, X.; Lin, T. Adv. Mater. 2012, 24, 2409. doi: 10.1002/adma.201200184
30. [30]
  (30) Roach, P.; Shirtcliffe, N. J.; Newton, M. I. Soft Matter 2008, 4, 224. doi: 10.1039/B712575P
31. [31]
  (31) Lu, Y.; Sathasivam, S.; Song, J.; Crick, C. R.; Carmalt, C. J.; Parkin, I. P. Science 2015, 347, 1132. doi: 10.1126/science.aaa0946
32. [32]
  (32) Shi, X.; Chen, Z.; Yang, Y. Eur. Polym. J. 2014, 50, 243. doi: 10.1016/j.eurpolymj.2013.11.005
33. [33]
  (33) Wang, D.; He, J. H.; Liu, H. Y. Imaging Science and Photochemistry 2011, 29, 372. [王东, 贺军辉, 刘红缨. 影像科学与光化学, 2011, 29, 372.]
34. [34]
  (34) Li, H.; Lu, X.;Wu, S. Q. Journal of Functional Materials 2014, 45 (Suppl. 2), 97. [李恒, 卢珣, 吴叔青. 功能材料, 2014, 45 (Suppl. 2), 97.]
35. [35]
  (35) Chu, Z.; Feng, Y.; Seeger, S. Angew. Chem. Int. Edit. 2015, 54, 2328. doi: 10.1002/anie.201405785
36. [36]
  (36) Yuan, J.; Liu, X.; Akbulut, O.; Hu, J.; Suib, S. L.; Kong, J.; Stellacci, F. Nat. Nanotechnol. 2008, 3, 332. doi: 10.1038/nnano.2008.136
37. [37]
  (37) Pan, Q.;Wang, M.;Wang, H. Appl. Surf. Sci. 2008, 254, 6002. doi: 10.1016/j.apsusc.2008.03.034
38. [38]
  (38) Zimmermann, J.; Reifler, F. A.; Fortunato, G.; Gerhardt, L. C.; Seeger, S. Adv. Funct. Mater. 2008, 18, 3662. doi: 10.1002/adfm.v18:22
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