Citation: BU Xiao-Xue, FAN Ben-Han, WEI Jie, XING Nan-Nan, MA Xiao-Xue, GUAN Wei. Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 267-273. doi: 10.3866/PKU.WHXB201510303 shu

Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation

BU Xiao-Xue ¹ ,
FAN Ben-Han ¹ ,
WEI Jie ¹ ,
XING Nan-Nan ^1,2 ,
MA Xiao-Xue ¹ ,
GUAN Wei ^1,,

1.
1 College of Chemistry, Liaoning University, Shenyang 110036, P. R. China;
2.
2 College of Chemistry and Chemical Engineering, Huangshang University, Huangshan 245041, Anhui Province, P. R. China

Corresponding author: GUAN Wei,
Received Date: 9 September 2015
Available Online: 28 October 2015
Fund Project: 国家自然科学基金(21173107) (21173107)辽宁省高等学校优秀人才支持计划(2015025)资助项目 (2015025)

The pyridinium-based ionic liquids [C₆py][DCA] (N-hexyl-pyridinium dicyanamide) was prepared and characterized using ¹H and ¹³C nuclear magnetic responancec (NMR) spectroscopies, Fourier transform infrared (FT-IR) spectroscopy, and differential scanning calorimetry (DSC). The density (ρ), surface tension (γ), and refractive indices (n_D) were measured at the temperature range from 288.15 to 338.15 K. Molecular volume (V_m), energy of surface (E_a), molar polarization (R_m), and polarization coefficient of [C₆py][DCA] (α_p) were calculated from the experimental data. E_a, R_m, and α_p were approximately temperature-independent. The concept of molar surface Gibbs free energy (g_s) was conceived, for which a new Eötvös equation was derived. The g_s, critical temperature (T_c), and Eötvös empirical parameter related to polarity (k_E) were also obtained. The new Eötvös equation was used to predict the surface tension and the predicted values of [C₆py][DCA] are in close agreement with the corresponding experimental ones.
- Pyridinium-based ionic liquid,
- Density,
- Surface tension,
- Molar surface Gibbs free energy,
- Eötvös equation
1. [1]
  (1) Seddon, K. R. J. Chem. Tech. Biotechnol. 1997, 68 (4), 351.
2. [2]
  (2) Tao, G. H.; He, L.; Liu, W. S.; Xu, L.; Xiong, W.; Wang, T.; Kou, Y. Green Chem. 2006, 8, 639. doi: 10.1039/b600813e
3. [3]
  (3) Muhammad, N.; Omar, W. N.; Man, Z.; Bustam, M. A.; Rafiq, S.; Uemura, Y. Ind. Eng. Chem. Res. 2012, 51 (5), 2280. doi: 10.1021/ie2014313
4. [4]
  (4) Rout, A.; Binnemans, K. Ind. Eng. Chem. Res. 2014, 53 (8), 6500.
5. [5]
  (5) Zhong, H. X.; Zhao, C. B.; Luo, H.; Zhang, L. Z. Acta Phys. -Chim. Sin. 2012, 28 (11), 2641. [仲皓想, 赵春宝, 骆浩, 张灵志. 物理化学学报, 2012, 28 (11), 2641.] doi: 10.3866/PKU.WHXB201207181
6. [6]
  (6) Wang, H.; Xu, X. Q.; Shi, J. F.; Xu, G. Acta Phys. -Chim. Sin. 2013, 29 (3), 525. [王海, 徐雪青, 史继富, 徐刚. 物理化学学报, 2013, 29 (3), 525.] doi: 10.3866/PKU.WHXB201301091
7. [7]
  (7) Zhao, D. B.; Fei, Z. F.; Geldbach, T. J.; Scopelliti, R.; Dyson, P. J. J. Am. Chem. Soc. 2004, 126 (48), 15876. doi: 10.1021/ja0463482
8. [8]
  (8) Yunus, N. M.; Abdul Mutalib, M. I.; Man, Z.; Bustam, M. A.; Murugesan, T. Chemical Engineering Journal 2012, 189, 94.
9. [9]
  (9) Calvar, N.; Gomez, E.; Macedo, E. A.; Dominguez, A. Thermochimica Acta 2013, 565, 178. doi: 10.1016/j.tca.2013.05.007
10. [10]
  (10) Crosthwaite, J. M.; Muldoon, M. J.; Dixon, J. K.; Anderson, J. L.; Brennecke, J. F. Journal of Chemical Thermodynamics 2005, 37 (6), 559. doi: 10.1016/j.jct.2005.03.013
11. [11]
  (11) Xu, F.; Gao, H. S.; Dong, H. F.; Wang, Z. L.; Zhang, X. P.; Ren, B. Z.; Zhang, S. J. Fluid Phase Equilibria 2014, 365, 80. doi: 10.1016/j.fluid.2013.12.020
12. [12]
  (12) Ye, Q.; Gao, T. T.; Wan, F.; Yu, B.; Pei, X. M.; Zhou, F.; Xue, Q. J. Journal of Materials Chemistry 2012, 22 (26), 13123. doi: 10.1039/c2jm31527k
13. [13]
  (13) Zeng, S. J.; Gao, H. S.; Zhang, X. C.; Dong, H. F.; Zhang, X. P.; Zhang, S. J. Chemical Engineering Journal 2014, 251, 248. doi: 10.1016/j.cej.2014.04.040
14. [14]
  (14) Jie, X. M.; Chau, J.; Obuskovic, G.; Obuskovic, G.; Sirkar, K. K. Industrial & Engineering Chemistry Research 2014, 53 (8), 3305. doi: 10.1021/ie403596b
15. [15]
  (15) Schneider, S.; Hawkins, T.; Rosander, M.; Vaghjiani, G.; Chambreau, S.; Drake, G. Energy & Fuels 2008, 22 (4), 2871. doi: 10.1021/ef800286b
16. [16]
  (16) Bedrov, D.; Borodin, O. Journal of Physical Chemistry B 2010, 114 (40), 12802. doi: 10.1021/jp1049827
17. [17]
  (17) Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, M. A. B. H.; Watanabe, M. Journal of Physical Chemistry B 2004, 108 (42), 16593. doi: 10.1021/jp047480r
18. [18]
  (18) Krossing, I.; Slattery, J. M.; Daguenet, C.; Dyson, P. J.; Oleinikova, A.; Weingärtner, H. J. Am. Chem. Soc. 2006, 128 (41), 13427.
19. [19]
  (19) Jenkins, H. D. B.; Glasser, L. Inorganic Chemistry 2002, 41 (17), 4378. doi: 10.1021/ic020222t
20. [20]
  (20) Jenkins, H. D. B.; Glasser, L. Inorganic Chemistry 2003, 42 (26), 8702. doi: 10.1021/ic030219p
21. [21]
  (21) Ma, X. X.; Wei, J.; Zhang, Q. B.; Tian, F.; Feng, Y. Y.; Guan, W. Ind. Eng. Chem. Res. 2013, 52, 9490. doi: 10.1021/ie401130d
22. [22]
  (22) Wei, J.; Chang, C.; Zhang, Y. Y.; Hou, S. Y.; Fang, D. W.; Guan, W. J. Chem. Thermodynamics 2015, 90, 310.
23. [23]
  (23) Wei, J.; Zhang, Q. B.; Tian, F.; Zheng, L.; Guan, W.; Yang, J. Z. Fluid Phase Equilibria 2014, 371, 1. doi: 10.1016/j.fluid.2014.03.011
24. [24]
  (24) Guan, W.; Zhang, Q. B.; Ma, X. X.; Wei, J.; Pan, Y.; Yang, J. Z. Fluid Phase Equilibria 2013, 360, 63. doi: 10.1016/j.fluid.2013.09.032
25. [25]
  (25) Ma, X. X.; Wei, J.; Guan, W.; Pan, Y.; Zheng, L.; Wu, Y.; Yang, J. Z. J. Chem. Thermodynamics 2015, 89, 51. doi: 10.1016/j.jct.2015.02.025
26. [26]
  (26) Guan, W.; Wang, C. X.; Wang, Z.; Chen, S. P.; Gao, S. L. Acta Chim. Sin. 2011, 69 (11), 1280. [关伟, 王彩霞, 王珍, 陈三平, 高胜利. 化学学报, 2011, 69 (11), 1280.]
27. [27]
  (27) Earle, M. J.; Gordon, C. M.; Plechkova, N. V.; Seddon, K. R.; Welton, T. Analytical Chemistry 2007, 79 (2), 758. doi: 10.1021/ac061481t
28. [28]
  (28) Gordon, C. M.; Muldoon, M. J.; Wagner, M. Ionic Liquids in Synthesis; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, 2002.
29. [29]
  (29) Zhang, S. G.; Qi, X. J.; Ma, X. Y.; Lu, L. J.; Deng, Y. Q. J. Phys. Chem. B 2010, 114 (11), 3912. doi: 10.1021/jp911430t
30. [30]
  (30) Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001.
31. [31]
  (31) Glasser, L. Thermochimica Acta 2004, 421 (1–2), 87. doi: 10.1016/j.tca.2004.03.015
32. [32]
  (32) Adamson, A. W. Physical Chemistry of Surfaces, 3rd ed.; John Wiley: New York, 1976; translated by Gu, T. R. Science Press: Beijing, 1986. [Adamson, A. W. 表面物理化学. 第三版. 顾惕人译. 北京: 科学出版社, 1986.]
33. [33]
  (33) Ersfeld, B.; Felderhof, B. U. Phys. Rev. E 1998, 57 (1), 1118. doi: 10.1103/PhysRevE.57.1118
34. [34]
  (34) Tong, J.; Liu, Q. S.; Zhang, P.; Yang, J. Z. J. Chem. Eng. Data 2007, 52 (4), 1497. doi: 10.1021/je700102g
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Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C6py][DCA] Using a New Eötvös Equation

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Thermodynamic Properties and Predicting the Surface Tension of Pyridinium-Based Ionic Liquids of [C₆py][DCA] Using a New Eötvös Equation