Citation: HAN Yi-Xiu, ZHOU Hong, WEI Yong-Qiang, MEI Yong-Jun, WANG Hang. Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2124-2130. doi: 10.3866/PKU.WHXB201509112 shu

Effect of TBAB/KCl on Constructing Anionic Wormlike Micelles

1.
The Second Research Institute of Civil Aviation Administration of China, Chengdu 610041, P. R. China

Corresponding author: MEI Yong-Jun,
Received Date: 17 June 2015
Available Online: 11 September 2015
Fund Project: 国家自然科学基金-民航联合研究基金(U1233122)资助项目 (U1233122)

Using rheological measurements, we investigated the wormlike micelles formed by anionic surfactants, sodium oleate (NaOA), and sodium erucate (NaOEr) in the presence of KCl and tetrabutyl ammonium bromide (TBAB). The viscosity of the NaOA solution increased with KCl concentration, but adding TBAB decreased viscosity. In contrast, the apparent viscosity of NaOEr-KCl solution enhances with increasing TBAB concentration. In addition, NaOEr is better than NaOA at encouraging the construction of viscoelastic wormlike micelles, needing less surfactant and a lower salt concentration. We prepared a wormlike micelle system with strong viscoelasticity by using NaOEr, cooperatively induced by KCl and TBAB. Based on these studies, we discussed the complex influence of TBA⁺ on constructing wormlike micelles.
- Anionic surfactant,
- Sodium erucate,
- Tetrabutyl ammonium bromide,
- Wormlike micelles,
- Rheology
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