Citation: ZHANG Qiao-Ling, LI Lei, LIU You-Zhi, WEI Bing, GUO Jia-Xin, FENG Yu-Jie. Grafting Dynamics, Structures and Properties of Nano TiO₂-SA Photocatalytic Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1015-1024. doi: 10.3866/PKU.WHXB201504143 shu

Grafting Dynamics, Structures and Properties of Nano TiO₂-SA Photocatalytic Materials

1.
1 Shanxi Province Key Laboratory of Higee-Oriented Chemical Engineering, North University of China, Taiyuan 030051, P. R. China;
2 State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, P. R. China

Received Date: 26 January 2015
Available Online: 14 April 2015
Fund Project: 山西省自然科学基金(2012011008-2) (2012011008-2)哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金(QA201401)资助项目 (QA201401)

Salicylic acid (SA) was successfully grafted onto nano-TiO₂ surfaces (TiO₂-SA) by post-treatment surface modification. The effects of ultrasound stiring, solvents, material ratio, pH value, and temperature on the grafting process and photocatalytic material properties were investigated, and the grafting reaction kinetics was determined. The structures of the materials were determined using Fourier transform infrared (FT- IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). A structural model was proposed. The properties of the photocatalytic material were examined using contact angle analysis, simultaneous thermogravimetry-differential scanning calorimetry (TG-DSC), ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), and scanning electron microscopy (SEM). Compared with bare TiO₂, the modified TiO₂ had od hydrophobicity and dispersion properties, a lower sedimentation velocity in solvents, better adsorption stability at oil-water interfaces, and extended visible light absorption. The TiO₂-SA gave excellent photocatalytic performances in nitrobenzene degradation under ultraviolet-light irradiation.
- Titanium dioxide,
- Salicylic acid,
- Dispersion,
- Structure model,
- Pickering emulsion
1. [1]
  
  (1) Hu , I. D. L.; Benito, S. R. Photocatalytic Technologies; Science Press: Beijing, 2010; pp ix-xii. [Hu , I. D. L., Benito, S. R. 光催化技术. 北京: 科学出版社, 2010: ix-xii.]
2. [2]
  (2) Han, S. T.; Xi, H. L.; Shi, R. X.; Fu, X. Z.; Wang, X. X. Chin. J. Chem. Phys. 2003, 16 (5), 339. [韩世同, 习海玲, 史瑞雪, 付贤智, 王绪绪. 化学物理学报, 2003, 16 (5), 339.]
3. [3]
  (3) Gao, Y. J.; Xu, Y. M. Acta Phys. -Chim. Sin. 2012, 28 (3), 641. [高岳君, 许宜铭. 物理化学学报, 2012, 28 (3), 641.] doi: 10.3866/PKU.WHXB201201161
4. [4]
  (4) Zhang, J. L.; Zhao, W. J.; Chen, H. J.; Xu, H. S.; Chen, A. P.; Anpo, M. K. Acta Phys. -Chim. Sin. 2004, 20 (4), 424. [张金龙, 赵文娟, 陈海军, 徐华胜, 陈爱平, 安保正一. 物理化学学报, 2004, 20 (4), 424.] doi: 10.3866/PKU.WHXB20040420
5. [5]
  (5) Liu, F. S.; Ji, R.; Wu, M.; Sun, Y. M. Acta Phys. -Chim. Sin. 2007, 23 (12), 1899. [刘福生, 吉仁, 吴敏, 孙岳明. 物理化学学报, 2007, 23 (12), 1899.] doi: 10.3866/PKU.WHXB20071213
6. [6]
  (6) Wang, C. X.; Mao, H. Y.; Wang, C. X.; Fu, S. H. Ind. Eng. Chem. Res. 2011, 50 (21), 11930. doi: 10.1021/ie200887x
7. [7]
  (7) Zhao, J.; Milanova, M.; Warmoeskerken, M. M. C. G.; Dutschk, V. Colloids Surf. A: Physicochem. Eng. Aspects 2012, 413, 273. doi: 10.1016/j.colsurfa.2011.11.033
8. [8]
  (8) Zou, L.; Wu, X. D.; Chen, H. G.; Wang, D. P. Acta Phys. -Chim. Sin. 2001, 17 (4), 305. [邹玲, 乌学东, 陈海刚, 王大璞. 物理化学学报, 2001, 17 (4), 305.] doi: 10.3866/PKU.WHXB20010405
9. [9]
  (9) Kanehira, K.; Banzai, T.; Ogino, C.; Shimizu, N.; Kubota, Y.; Sonezaki, S. J. Colloids Surf. B: Biointerfaces 2008, 64, 10. doi: 10.1016/j.colsurfb.2007.12.018
10. [10]
  (10) Balas, F.; Kokubo, T.; Kawashita, M.; Nakamura, T. J. Mater. Sci. Mater. Med. 2007, 18, 1167.
11. [11]
  (11) Ahn, W.; Sheeley, S. A.; Rajh, T.; Cropek, D. M. Appl. Catal. B: Environ. 2007, 74 (1-2), 103.
12. [12]
  (12) Cropek, D.; Kemme, P. A.; Makarova, O. V.; Chen, L. X.; Rajh, T. J. Phys. Chem. C 2008, 112, 8311.
13. [13]
  (13) Huang, H. Y.; Zhou, J. H.; Liu, H. L.; Zhou, Y. H.; Feng, Y. Y. J. Hazard. Mater. 2010, 178 (1-3), 994. doi: 10.1016/j.jhazmat.2010.02.037
14. [14]
  (14) Li, S. X.; Zheng, F. Y.; Cai, W. L.; Han, A. Q.; Xie, Y. K. J. Hazard. Mater. 2013, B188, 280.
15. [15]
  (15) Faouzi, N. M.; Asma, M.; Noomen, M.; Tarhouni, N.; Massourib, A.; Houasa, A.; Chevalierc, Y. J. Photochem. Photobiol. A: Chem. 2013, 251, 10. doi: 10.1016/j.jphotochem.2012.10.007
16. [16]
  (16) Hu, B.; Pan, H.; Yu, L. G.; Wang, L. G.; Zhao, L.; Zhang, Z. J. J. Inorg. Mater. 2011, 26 (11), 1181. [胡宾, 潘卉, 余来贵, 王龙阁, 赵磊, 张治军. 无机材料学报, 2011, 26 (11), 1181.] doi: 10.3724/SP.J.1077.2011.01181
17. [17]
  (17) Edwni, E. P. Silane and Titanate Coupling Agent; Shanghai Science and Technology Literature Press: Shanghai, 1987; pp 1-2; translated by Liang, F. S., Xie, S. J. [Edwni, E. P. 硅烷和钛酸酯偶联剂. 梁发思, 谢世杰, 译. 上海: 上海科学技术文献出版社, 1987: 1-2.]
18. [18]
  (18) Cui, A. L.; Wang, T. J.; He, H.; Jin, Y. Chin. J. Pro. Eng. 2001, 1 (1), 99. [崔爱莉, 王亭杰, 何红, 金涌. 过程工程学报, 2001, 1 (1), 99.]
19. [19]
  (19) Fan, Z. Y.; Tay, A.; Pera-Titus, M.; Zhou, W. J.; Benhabbari, S.; Feng, X. S.; Malcouronne, G.; Bonneviot, L.; Campo, F. D.; Wang, L. M.; Clacens, J. M. J. Colloids Surf. Sci. 2014, 427, 90.
20. [20]
  (20) Hong, R. Y.; Pan, T. T.; Qian, J. Z. Chem. Eng. J. 2006, 119, 71. doi: 10.1016/j.cej.2006.03.003
21. [21]
  (21) Li, S. T.; Yin, Q. G. Ultrasonic Chemistry; Science and Technology Press: Beijing, 1995; pp 32-61. [李廷盛, 尹其光. 超声化学. 北京: 科学技术出版社, 1995: 32-61.]
22. [22]
  (22) Stuart, C. Prog. Org. Coat 2002, 44, 131. doi: 10.1016/S0300-9440(01)00261-2
23. [23]
  (23) Mao, A. Q. Study on Surface Treatment of Ultrafine Titanium Dioxide and Dispersion inWater. Master Dissertation, Nanjing University of Science and Technology, Nanjing, 2004. [冒爱琴. 超细二氧化钛的表面处理及其在水中分散性的研究[D]. 南京: 南京理工大学, 2004.]
24. [24]
  (24) Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds; Wiley: New York, 1978; p 232.
25. [25]
  (25) Deacon, G. B.; Philips, R. J. J. Coord. Chem. Rev. 1980, 33, 327.
26. [26]
  (26) Zhang, F.; Shi, T. J.; Zhou, X.; Zhou, H. O.; Wu, J. J. Chem. Ind. Eng. 2014, 65 (4), 1526. [张方, 史铁均, 周讯, 周海鸥, 吴竟. 化工学报, 2014, 65 (4), 1526.
1. [1]
  Fengmiao Yu , Yang Sheng , Chanyue Li , Bao Li . The Three Lives of Aspirin. University Chemistry, 2024, 39(9): 115-121. doi: 10.12461/PKU.DXHX202402033
2. [2]
  Jingxuan Zhang , Weihao Jiang , Siyuan Zhang , Hongye Tian , Ziye Huang , Lin Huang , Qikun Wu , Jing Yang , Yibin Jiang , Cheng Wang . Automation and AI-Assisted Investigation of the Chemical Reactivity of Sulfosalicylic Acid. University Chemistry, 2026, 41(1): 332-345. doi: 10.12461/PKU.DXHX202505108
3. [3]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
4. [4]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
5. [5]
  Jianqiang Zheng , Yongbin Huang , Wencan Ming , Yingju Liu . Intelligent Reaction Optimization: Synthesis of Acetylsalicylic Acid Driven by Deep Learning and Optimization Algorithms. University Chemistry, 2025, 40(9): 87-98. doi: 10.12461/PKU.DXHX202411062
6. [6]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Hongbo Hou , Qian Yang , Yi Gao , Yang Ou , Zhuang Wang , Shun Yi , Jingfeng He , Li Ma , Fanbin Meng . Progress in supercritical CO₂ foamed polymer composites for electromagnetic protection: from rational structural design to absorption-dominated performance. Acta Physico-Chimica Sinica, 2026, 42(10): 100300-0. doi: 10.1016/j.actphy.2026.100300
9. [9]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
10. [10]
  Sihan Wang , Chenxi Yu , Shuzhang Ran , Jiawei Chen , Shoutong Rao , Xinyi Liang , Ruiqi Dong , Guixiang Zeng , Guoqiang Wang , Jing Ma . 铁配合物合成与性质探究的数智化改进——大学化学实验中“磺基水杨酸合铁配合物的组成与稳定常数的测定”的创新设计. University Chemistry, 2026, 41(5): 36-49. doi: 10.12461/PKU.DXHX202511137
11. [11]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006
12. [12]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
13. [13]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
14. [14]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
17. [17]
  Hailian Cheng , Shuaiqiang Jia , Chunjun Chen , Haihong Wu , Buxing Han . Electrocatalytic CO₂ Conversion: A Key to Unlocking a Low-Carbon Future. University Chemistry, 2026, 41(2): 1-13. doi: 10.12461/PKU.DXHX202502023
18. [18]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
19. [19]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
20. [20]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117

Get Citation

PDF

XML

Metrics

PDF Downloads(393)
Abstract views(1796)
HTML views(126)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Grafting Dynamics, Structures and Properties of Nano TiO2-SA Photocatalytic Materials

Metrics

通讯作者: 陈斌, bchen63@163.com

Grafting Dynamics, Structures and Properties of Nano TiO₂-SA Photocatalytic Materials