Citation: HUANG Zhi-Peng, GUO Lin-Yu, GUO Chao, ZHAO Meng-Meng, WANG Xue-Hua, JIN Zhao, LUO Jin-Hua, WANG Xin, FENG Ji-Jun. Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method[J]. Acta Physico-Chimica Sinica, ;2015, 31(4): 700-706. doi: 10.3866/PKU.WHXB201501261 shu

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method

1.
1 School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China;
2 School of Chemistry and Biological Engineering, Qilu Institute of Technology, Zhangqiu 250200, Shandong Province, P. R. China

Received Date: 19 November 2014
Available Online: 26 January 2015
Fund Project: 国家自然科学基金(51102114) (51102114) 济南市科技发展计划(201401234) (201401234)国家级大学生创新创业训练计划(201310427010)资助项目 (201310427010)

LiVPO₄F/C, as a cathode material of lithium- ion batteries, was prepared by carbon thermal reduction assisted sol-gel method. X-ray diffraction (XRD), scanning electron microscopy (SEM), galvanostatic charge-discharge cycles, cyclic voltammogram (CV), and electrochemical impedance spectroscopy (EIS) were employed to investigate the effects of sintering time and temperature on the structure and corresponding electrochemical performance of as prepared materials. At a sintering time of 4 h, pure phase LiVPO₄F/C material was obtained when the temperature is settled at 450 ℃. The as-produced LiVPO₄F/C exhibited discharge capacities of 193.2, 175.6, and 173.7 mAh·g^-1 at 0.1C, 0.5C, and 1.0C rates, respectively. Li₃V₂(PO₄)₃ impurities are formed and increased with increasing calcination temperature. When sintered at 650 ℃ Li₃V₂(PO₄)₃ is turn out to be the main phase. On the other hand, optimal duration time at high temperature could also inhibit the decomposition of LiVPO₄F and decrease the formation of Li₃V₂(PO₄)₃ impurities, improving electrochemical performance. Optimal conditions were found at a residence time of 3 h when the precursor is sintered at 550 ℃.
- Lithium-ion battery,
- Cathode material,
- Sol-gel,
- Carbon thermal reduction,
- LiVPO₄F/C
1. [1]
  
  (1) Whittingham, M. S. Chem. Rev. 2004, 104, 4271. doi: 10.1021/cr020731c
2. [2]
  (2) Tarascon, J. M.; Armand, M. Nature 2001, 414, 359. doi: 10.1038/35104644
3. [3]
  (3) Ai, D. J.; Liu, K. Y.; Lu, Z. G.; Zou, M. M.; Zeng, D. Q.; Ma, J. Electrochim. Acta 2011, 56, 2823. doi: 10.1016/j.electacta.2010.12.063
4. [4]
  (4) Padhi, A. K.; Najundaswamy, K. S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188. doi: 10.1149/1.1837571
5. [5]
  (5) Chang, C. X.; Xiang, J. F.; Shi, X. X.; Han, X. Y.; Yuan, L. J.; Sun, J. T. Electrochim. Acta 2008, 54, 623. doi: 10.1016/j.electacta.2008.07.038
6. [6]
  (6) Reimers, J. N.; Dahn, J. R. J. Electrochemi. Soc. 1992, 139, 2091. doi: 10.1149/1.2221184
7. [7]
  (7) Wu, L.; Zhong, S. K.; Liu, J. Q.; Lv, F.; Wan, K. Mater. Lett. 2012, 89, 32. doi: 10.1016/j.matlet.2012.08.076
8. [8]
  (8) Feng, J. J.; Huang, Z. P.; Guo, C.; Chernova, N. A.; Upreti, S.; Whittingham, M. S. ACS Appl. Mater. Interfaces 2013, 5, 10227. doi: 10.1021/am4029526
9. [9]
  (9) Li, Z.; Chernova, N. A.; Feng, J. J.; Upreti, S.; Omenya, F.; Whittingham, M. S. J. Electrochem. Soc. 2012, 159, A116.
10. [10]
  (10) Barker, J.; Saidi, M. Y.; Swoyer, J. L. Lithium Metal Fluorophosphate Materials and Preparation Thereof. US 6387568 B1, 2002.
11. [11]
  (11) Barker, J.; Saidi, M. Y.; Swoyer, J. L. J. Electrochem. Soc. 2003, 150 (10), A1394.
12. [12]
  (12) Zhong, S. K.; Chen, W.; Liu, C. J. Trans. Nonferrous Met. Soc. China 2010, 20, s275.
13. [13]
  (13) Lee, K.; Myung, S.; Yashiro, H.; Sun, Y. Electrochim. Acta 2008, 53, 3065. doi: 10.1016/j.electacta.2007.11.042
14. [14]
  (14) Wang, L.; Huang, Y.; Jiang, R.; Jia, D. Electrochim. Acta 2007, 52, 6778. doi: 10.1016/j.electacta.2007.04.104
15. [15]
  (15) Feng, J. J.; Liu, X. Z.; Zhang, X. M.; Jiang, J. Z.; Zhao, J.; Wang, M. J. Electrochem. Soc. 2009, 156, A768.
16. [16]
  (16) Liu, L.; Tian, F. H.; Wang, X. Y.; Zhou, M. Acta Phys. -Chim. Sin. 2011, 27, 2600. [刘黎, 田方华, 王先友, 周萌. 物理化学学报, 2011, 27, 2600.] doi: 10.3866/PKU.WHXB20111126
17. [17]
  (17) Ellis, B. L.; Ramesh, T. N.; Davis, L. J. M.; ward, G. R.; Nazar, L. F. Chem. Mater. 2011, 23, 5138. doi: 10.1021/cm201773n
18. [18]
  (18) Barker, J.; ver, R. K. B.; Burns, P.; Bryan, A.; Saidi, M. Y.; Swoyer, J. L. J. Power Sources 2005, 146, 516. doi: 10.1016/j.jpowsour.2005.03.126
19. [19]
  (19) Wang, J. X.; Wang, Z. X.; Shen, L.; Li, X. H.; Guo, H. J.; Tang, W. J.; Zhu, Z. G. Trans. Nonferrous Met. Soc. China 2013, 23, 1718. doi: 10.1016/S1003-6326(13)62653-9
20. [20]
  (20) Xiao, P. F.; Lai, M. O.; Lu, L. Solid State Ionics 2013, 242, 10. doi: 10.1016/j.ssi.2013.04.002
21. [21]
  (21) Li, Y. Z.; Zhou, Z.; Gao, X. P.; Yan, J. J. Power Sources 2006, 160, 633. doi: 10.1016/j.jpowsour.2006.01.067
22. [22]
  (22) Xiong, Z. Q.; Zhang, G. Q.; Xiong, J. Q.; Yang, X. Q.; Zhang, Y. Y. Mater. Lett. 2013, 111, 214. doi: 10.1016/j.matlet.2013.08.086
23. [23]
  (23) Piao, Y.; Lin, Lin, C. K.; Qin, Y.; Zhou, D. H.; Ren, Y.; Bloom, I.; Wei, Y. J.; Chen, G.; Chen, Z. H. J. Power Sources 2015, 273, 1250. doi: 10.1016/j.jpowsour.2013.11.127
24. [24]
  (24) Sun, X. F.; Xu, Y. L.; Chen, G. G.; Ding, P.; Zheng, X. Y. Solid State Ionics 2014, 268, 236. doi: 10.1016/j.ssi.2014.08.008
25. [25]
  (25) Wang, Y. L.; Zhao, H. X.; Ji, Y. F.; Wang, L. H.; Wei, Z. Solid State Ionics 2014, 268, 169. doi: 10.1016/j.ssi.2014.10.031
26. [26]
  (26) Huang, H.; Yin, S. C.; Kerr, T.; Taylor, N.; Nazar, L. F. Adv. Mater. 2002, 14, 1525. doi: 10.1002/1521-4095(20021104)14: 21<1525::AID-ADMA1525>3.0.CO;2-3
27. [27]
  (27) Wei, Y.; Wang, L. J.; Yan, J.; Sha, O.; Tang, Z. Y.; Ma, L. Acta Phys. -Chim. Sin. 2011, 27, 2587. [魏怡, 王利娟, 闫继, 沙鸥, 唐致远, 马莉. 物理化学学报, 2011, 27, 2587.] doi: 10.3866/PKU.WHXB20111124
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO4F/C by Carbon Thermal Reduction Assisted Sol-Gel Method

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Fluorinated Polyanionic Lithium Ion Insertion/Extraction Material LiVPO₄F/C by Carbon Thermal Reduction Assisted Sol-Gel Method