Citation: GAO Xiao-Dan, LI Hang, TIAN Rui, LIU Xin-Min, ZHU Hua-Ling. Quantitative Characterization of Specific Ion Effects Using an Effective Charge Number Based on the uy-Chapman Model[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2272-2282. doi: 10.3866/PKU.WHXB201410231 shu

Quantitative Characterization of Specific Ion Effects Using an Effective Charge Number Based on the uy-Chapman Model

1.
Chongqing Key Laboratory of Soil Multi-scale Interfacial Process, College of Resources and Environment, Southwest University, Chongqing 400715, P. R. China

Received Date: 22 July 2014
Available Online: 23 October 2014
Fund Project: 国家自然科学基金(41371249, 41101223) (41371249, 41101223)西南大学研究生科技创新基金(ky2011009)资助项目 (ky2011009)

Specific ion effects have been observed in a wide range of phenomena at solid-liquid interfaces. Recent studies have indicated that the origin of these effects in some relatively low-electrolyte-concentration systems is the ion polarization in the strong electric field near the interface, rather than dispersion forces, classical induction forces, ionic size, or hydration effects. These effects cause the counterions near the interface to become strongly polarized (with a polarization that is nearly ten thousands times stronger than classical polarization). This strong polarization causes that the Coulomb force exerted by the polarized ions near the interface is far greater than the force generated by the ionic charge, which is reflected in the fact that the effective charge number of polarized ions is much larger than their original charge number. We therefore used the effective charge number of strongly polarized cations to quantitatively characterize the strength of specific ion effects in colloid systems. In this study, we observed the strong, specific ion effects of Na⁺, K⁺, Ca²⁺, and Cu²⁺ in the montmorillonite-humic acid composite aggregation process. Furthermore, we established a method to calculate the effective charge number of polarized cations based on the critical coagulation concentration (CCC) measured using dynamic light scattering. We successfully obtained the effective charge number of polarized ions. The experimental effective charge numbers for Na⁺, K⁺, Ca²⁺, and Cu²⁺ were Z_{Na(effective)}=1.46, Z_K(effective)=1.86, Z_{Ca(effective)}=3.92, Z_{Cu(effective)}=6.48, respectively. These results showed that the non-classical polarization greatly enhanced the effective charge number of ions, greatly enhancing the Coulomb force exerted by the ions; and that the more electronic layers the ions had and the stronger the ionic polarization, the more the effective charge of ions increased.
- Hofmeister effect,
- Dynamic light scattering,
- Aggregation kinetics,
- Effective charge coefficient,
- Electric field,
- Non-classical polarization effect
1. [1]
  
  (1) Lo Nostro, P.; Ninham, B.W. Chem. Rev. 2012, 112, 2286. doi: 10.1021/cr200271j
2. [2]
  (2) Hofmeister, F. Archiv für Experimentelle Pathologie und Pharmakologie 1888, 25, 1.
3. [3]
  (3) Izutsu, K. I.; Aoyagi, N. Int. J. Pharm. 2005, 288, 101. doi: 10.1016/j.ijpharm.2004.09.015
4. [4]
  (4) Parsons, D. F.; Boström, M.; Nostro, P. L.; Ninham, B.W. Phys. Chem. Chem. Phys. 2011, 13, 12352. doi: 10.1039/c1cp20538b
5. [5]
  (5) Kunz,W.; Lo Nostro, P.; Ninham, B.W. Curr. Opin. Colloid Interface Sci. 2004, 9, 1. doi: 10.1016/j.cocis.2004.05.004
6. [6]
  (6) Ninham, B.W. Lipid. Polym. -Lipid. Syst. 2002, 120, 1. doi: 10.1007/3-540-45291-5
7. [7]
  (7) Tobias, D. J.; Hemminger, J. C. Science 2008, 319, 1197. doi: 10.1126/science.1152799
8. [8]
  (8) Yu, Y. X.; Fujimoto, S. Sci. China Chem. 2013, 56, 1735. doi: 10.1007/s11426-013-4959-9
9. [9]
  (9) Tielrooij, K.; Garcia-Araez, N.; Bonn, M.; Bakker, H. Science 2010, 328, 1006. doi: 10.1126/science.1183512
10. [10]
  (10) Nucci, N. V.; Vanderkooi, J. M. J. Mol. Liq. 2008, 143, 160. doi: 10.1016/j.molliq.2008.07.010
11. [11]
  (11) Yu, Y. X.; Gao, G. H.; Li, Y. G. Fluid Phase Equilib. 2000, 173, 23.
12. [12]
  (12) Lu, J. F.; Yu, Y. X.; Li, Y. G. Fluid Phase Equilib. 1993, 85, 81. doi: 10.1016/0378-3812(93)80006-9
13. [13]
  (13) Peula-García, J. M.; Ortega-Vinuesa, J. L.; Bastos- nzález, D. J. Phys. Chem. C 2010, 114, 11133.
14. [14]
  (14) Boström, M.;Williams, D. R. M.; Ninham, B.W. Phys. Rev. Lett. 2001, 87, 168103. doi: 10.1103/PhysRevLett.87.168103
15. [15]
  (15) Ninham, B.W.; Duignan, T. T.; Parsons, D. F. Curr. Opin. Colloid Interface Sci. 2011, 16, 612. doi: 10.1016/j. cocis.2011.04.006
16. [16]
  (16) Hu, J. H.; Yang, Z. X.; Zheng, Z. Colloid and Interface Chemistry; South China University of Technology Press: Guangzhou, 1997; pp 254-330. [胡纪华, 杨兆禧, 郑忠. 胶体与界面化学. 广州: 华南理工大学出版社, 1997: 254-330.]
17. [17]
  (17) Jin, L.; Yu, Y. X.; Gao, G. H. J. Colloid Interface Sci. 2006, 304, 77. doi: 10.1016/j.jcis.2006.08.046
18. [18]
  (18) Liu, X. M.; Li, H.; Du,W.; Tian, R.; Li, R.; Jiang, X. J. J. Phys. Chem. C 2013, 117, 6245. doi: 10.1021/jp312682u
19. [19]
  (19) Liu, X. M.; Li, H.; Li, R.; Xie, D. T.; Ni, J. P.;Wu, L. S. Sci. Rep. 2014, 4, 5047.
20. [20]
  (20) Tian, R.; Yang, G.; Li, H.; Gao, X. D.; Liu, X. M.; Zhu, H. L.; Tang, Y. Phys. Chem. Chem. Phys. 2014, 16, 8828. doi: 10.1039/c3cp54813a
21. [21]
  (21) Borukhov, I.; Andelman, D.; Orland, H. Phys. Rev. Lett. 1997, 79, 435. doi: 10.1103/PhysRevLett.79.435
22. [22]
  (22) Kim, H. K.; Tuite, E.; Nordén, B.; Ninham, B.W. Eur. Phys. J. E 2001, 4, 411. doi: 10.1007/s101890170096
23. [23]
  (23) Kanda, Y.; Yamamoto, T.; Higashitani, K. Adv. Powder Technol. 2002, 13, 149. doi: 10.1163/156855202760166505
24. [24]
  (24) Sheng, N.; Boyce, M. C.; Parks, D. M.; Rutledge, G. C.; Abes, J. I.; Cohen, R. E. Polymer 2004, 45, 487. doi: 10.1016/j.polymer.2003.10.100
25. [25]
  (25) Zhu, H. L.; Li, B.; Xiong, H. L.; Li, H.; Jia, M. Y. Acta Phys. -Chim. Sin. 2009, 25, 1225. [朱华玲, 李兵, 熊海灵, 李航, 贾明云. 物理化学学报, 2009, 25, 1225.] doi: 10.3866/PKU.WHXB20090631
26. [26]
  (26) Li, S.; Li, H.; Xu, C. Y.; Huang, X. R.; Xie, D. T.; Ni, J. P. Soil Sci. Soc. Am. J. 2013, 77, 1563. doi: 10.2136/sssaj2013.01.0009
27. [27]
  (27) Xiong, Y. Soil Colloid, 2nd ed.; Science Press: Beijing, 1985; pp 10-14. [熊毅. 土壤胶体(第二册). 北京: 科学出版社, 1985: 10-14.]
28. [28]
  (28) Low, P. F. Soil Sci. Soc. Am. J. 1980, 44, 667. doi: 10.2136/sssaj1980.03615995004400040001x
29. [29]
  (29) Liu, X. M.; Li, H.; Li, R.; Tian, R.; Xu, C. Y. Analyst 2013, 138, 1122.
30. [30]
  (30) Kuwatsuka, S.;Watanabe, A.; Itoh, K.; Arai, S. Soil Sci. Plant Nutr. 1992, 38, 23. doi: 10.1080/00380768.1992.10416948
31. [31]
  (31) Wu, G. F.; Ren, Q.; Tao, Y.; Zhang, H. X. Chin. J. Colloid Polym. 2007, 2, 40. [吴广峰, 任群, 陶悦, 张会轩. 胶体与聚合物, 2007, 2, 40.]
32. [32]
  (32) Jia, M. Y.; Li, H.; Zhu, H. L.; Tian, R.; Gao, X. D. J. Soils Sediments 2013, 13, 325. doi: 10.1007/s11368-012-0608-8
33. [33]
  (33) Gao, X. D.; Li, H.; Zhu, H. L.; Tian, R. Acta Pedol. Sin. 2012, 49, 698. [高晓丹, 李航, 朱华玲, 田锐. 土壤学报, 2012, 49, 698.]
34. [34]
  (34) Noah-Vanhoucke, J.; Geissler, P. L. Proc. Natl. Acad. Sci. 2009, 106, 15125. doi: 10.1073/pnas.0905168106
35. [35]
  (35) Boroudjerdi, H.; Kim, Y.W.; Naji, A.; Netz, R. R.; Schlagberger, X.; Serr, A. Phys. Rep. 2005, 416, 129. doi: 10.1016/j.physrep.2005.06.006
36. [36]
  (36) Manning, G. S. J. Phys. Chem. 1981, 85, 1506. doi: 10.1021/j150611a011
37. [37]
  (37) Stellwagen, E.; Stellwagen, N. C. Biophys. J. 2003, 84, 1855. doi: 10.1016/S0006-3495(03)74993-5
38. [38]
  (38) Logan, E. M.; Pulford, I. D.; Cook, G. T.; Mackenzie, A. B. Eur. J. Soil Sci. 1997, 48, 685. doi: 10.1046/j.1365-2389.1997.00123.x
39. [39]
  (39) Ducker,W. A.; Senden, T. J.; Pashley, R. M. Langmuir 1992, 8, 1831. doi: 10.1021/la00043a024
40. [40]
  (40) Verwey, E. J.W.; Overbeek, J. T. G.; Van Nes, K., Theory of the Stability of Lyophobic Colloids: The Interaction of Sol Particles Having an Electric Double Layer; Elsevier: New York, 1948.
41. [41]
  (41) Hou, J.; Li, H.; Zhu, H. L.;Wu, L. S. Soil Sci. Soc. Am. J. 2009, 73, 1658. doi: 10.2136/sssaj2008.0017
42. [42]
  (42) Li, H.; Qing, C. L.;Wei, S. Q.; Jiang, X. J. J. Colloid Interface Sci. 2004, 275, 172. doi: 10.1016/j.jcis.2003.12.055
43. [43]
  (43) Li, H.; Peng, X. H.;Wu, L. S.; Jia, M. Y.; Zhu, H. L. J. Phys. Chem. C 2009, 113, 4419. doi: 10.1021/jp808372r
44. [44]
  (44) Amal, R.; Coury, J. R.; Raper, J. A.;Walsh,W. P.;Waite, T. D. Colloids Surf. 1990, 46, 1. doi: 10.1016/0166-6622(90)80045-6
45. [45]
  (45) Li, T. C.; Kheifets, S.; Medellin, D.; Raizen, M. G. Science 2010, 328, 1673. doi: 10.1126/science.1189403
46. [46]
  (46) Uhlenbeck, G. E.; Ornstein, L. S. Phy. Rev. 1930, 36, 823. doi: 10.1103/PhysRev.36.823
47. [47]
  (47) Wang, K.; Yu, Y. X.; Gao, G. H. Phys. Rev. E 2004, 70, 011912. doi: 10.1103/PhysRevE.70.011912
48. [48]
  (48) Peng, B.; Yu, Y. X. J. Chem.Phys. 2009, 131, 134703. doi: 10.1063/1.3243873
1. [1]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
2. [2]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-. doi: 10.1016/j.actphy.2025.100084
3. [3]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
4. [4]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
5. [5]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
6. [6]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
7. [7]
  Jiayu Gu , Siqi Wang , Jun Ling . Kinetics of Living Copolymerization: A Brief Discussion. University Chemistry, 2025, 40(4): 100-107. doi: 10.12461/PKU.DXHX202406012
8. [8]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
9. [9]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
10. [10]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . 三聚氰胺泡沫支撑的S型硫铟锌镉/硫掺杂氮化碳异质结的绿色H₂O₂合成：协同界面电荷转移调控与局域光热效应. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-. doi: 10.1016/j.actphy.2025.100093
11. [11]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
12. [12]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
13. [13]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
14. [14]
  Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
15. [15]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
16. [16]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
17. [17]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . Facile synthesis of hierarchical Ti₃C₂/Bi₁₂O₁₇Br₂ Schottky heterojunction with photothermal effect for solar-driven antibiotics photodegradation. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-. doi: 10.1016/j.actphy.2025.100075
18. [18]
  Peipei Sun , Jinyuan Zhang , Yanhua Song , Zhao Mo , Zhigang Chen , Hui Xu . 引入内建电场增强光载流子分离以促进H₂的生产. Acta Physico-Chimica Sinica, 2024, 40(11): 2311001-. doi: 10.3866/PKU.WHXB202311001
19. [19]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
20. [20]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035

Get Citation

PDF

XML

Metrics

PDF Downloads(428)
Abstract views(550)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142