Citation: GUO Zhang-Long, HUANG Li-Qiong, CHU Wei, LUO Shi-Zhong. Effects of Promoter on NiMgAl Catalyst Structure and Performance for Carbon Dioxide Reforming of Methane[J]. Acta Physico-Chimica Sinica, ;2014, 30(4): 723-728. doi: 10.3866/PKU.WHXB201402242 shu

Effects of Promoter on NiMgAl Catalyst Structure and Performance for Carbon Dioxide Reforming of Methane

1.
1 Department of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2 Department of Chemical Engineering, Yunnan Open University, Kunming 650223, P. R. China

Received Date: 6 December 2013
Available Online: 24 February 2014
Fund Project:

Catalysts were prepared by adding different types of promoter (Co, Ir, or Pt) to the supported nickel catalyst NiMgAl samples. These catalysts were characterized by H₂ temperature-programmed reduction (H₂-TPR), CO₂/CH₄ temperature-programmed surface reactions (CO₂/CH₄-TPSR), and CO₂ temperatureprogrammed desorption (CO₂-TPD). The effects of the catalyst structure on catalytic performance in the methane dry reforming reaction with carbon dioxide were investigated. The addition of a small amount of promoter (Pt or Ir) can lower the reduction temperature of the nickel active component, and enhance performance in the methane dry reforming reaction. The catalysts with Co or Ir promoter feature lower activation energies than the unmodified NiMgAl catalyst. The activation energy was 51.8 kJ·mol^-1 for the NiMgAl sample, decreasing to 26.4 kJ·mol^-1 for the NiPtMgAl catalyst, which showed overall better catalytic performance. Results of CH₄-TPSR and CO₂-TPSR demonstrate that the NiPtMgAl catalyst can generate more active carbon species on the catalyst surface. The CO₂-TPD results show that adding a promoter can increase the CO₂ adsorbed/desorbed amount compared with the unmodified NiMgAl catalyst over the same reaction temperature range.
- Carbon dioxide reforming of methane,
- Nickel-based catalyst,
- Pt promoter,
- Catalytic activity,
- Activation energy,
- Temperature-programmed surface reaction
1. [1]
  
  (1) Wang, Q.; Luo, J. Z.; Zhong, Z. Y.; Borgna, A. Energ. Environ. Sci. 2011, 4, 42. doi: 10.1039/c0ee00064g
2. [2]
  (2) Chu,W.; Ran, M. F.; Zhang, X.;Wang, N.;Wang, Y. F.; Xie, H. P.; Zhao, X. S. J. Energy Chem. 2013, 22, 136. doi: 10.1016/S2095-4956(13)60018-2
3. [3]
  (3) Hansen, J.; Sato, M. Proc. Natl. Acad. Sci. U. S. A. 2004, 101, 16109. doi: 10.1073/pnas.0406982101
4. [4]
  (4) von der Assen, N.; Jung, J.; Bardow, A. Energ. Environ. Sci. 2013, 6, 2721. doi: 10.1039/c3ee41151f
5. [5]
  (5) Serrano-Ruiz, J. C.; Dumesic, J. A. Energ. Environ. Sci. 2011, 4, 83. doi: 10.1039/c0ee00436g
6. [6]
  (6) Ashcroft, A. T.; Cheetham, A. K.; Green, M. L. H.; Vernon, P. D. F. Nature 1991, 352, 225. doi: 10.1038/352225a0
7. [7]
  (7) Ramos, L.; Zeppieri, S. Fuel 2013, 110, 141. doi: 10.1016/j.fuel.2012.12.045
8. [8]
  (8) Chu,W.;Wang, L. N.; Chernavsk, P. A.; Khodakov, A. Y. Angew. Chew. Int. Edit. 2008, 47, 5052. doi: 10.1002/anie.v47:27
9. [9]
  (9) Ha, K. S.; Bae, J.W.;Woo, K. J.; Jun, K.W. Environ. Sci. Technol. 2010, 44, 1412. doi: 10.1021/es902784x
10. [10]
  (10) Wang, N.; Chu,W.; Zhang, T.; Zhao, X. S. Chem. Eng. J. 2011, 170, 457. doi: 10.1016/j.cej.2010.12.042
11. [11]
  (11) Aldashukurova, G. B.; Mironenko, A. V.; Mansurov, Z. A.; Shikina, N. V.; Yashnik, S. A.; Kuznetsov, V. V.; Ismagilov, Z. R. J. Energy Chem. 2013, 22, 811. doi: 10.1016/S2095-4956(13)60108-4
12. [12]
  (12) Zhang, J. G.;Wang, H.; Dalai, A. K. J. Catal. 2007, 249, 300 300. doi: 10.1016/j.jcat.2007.05.004
13. [13]
  (13) Crisafulli, C.; Scire, S.; Minico, S.; Solarino, L. Appl. Catal. AGen. 2002, 225, 1. doi: 10.1016/S0926-860X(01)00585-3
14. [14]
  (14) Meshkani, F.; Rezaei, M. Int. J. Hydrog. Energy 2010, 35, 10295. doi: 10.1016/j.ijhydene.2010.07.138
15. [15]
  (15) Chen, Y. G.; Tomishige, K.; Yokoyama, K.; Fujimoto, K. Appl. Catal. A-Gen. 1997, 165, 335. doi: 10.1016/S0926-860X(97)00216-0
16. [16]
  (16) Jose-Alonso, D. S.; Illan- mez, M. J.; Roman-Martinez, M. C. Int. J. Hydrog. Energy 2013, 38, 2230. doi: 10.1016/j.ijhydene.2012.11.080
17. [17]
  (17) Pawelec, B.; Damyanova, S.; Arishtirova, K.; Fierro, J. L. G.; Petrov, L. Appl. Catal. A-Gen. 2007, 323, 188. doi: 10.1016/j.apcata.2007.02.017
18. [18]
  (18) Garcia-Dieguez, M.; Pieta, I. S.; Herrera, M. C.; Larrubia, M. A.; Alemany, L. J. J. Catal. 2010, 270, 136. doi: 10.1016/j.jcat.2009.12.010
19. [19]
  (19) Huang, T.; Huang,W.; Huang, J.; Ji, P. Fuel Process. Technol. 2011, 92, 1868. doi: 10.1016/j.fuproc.2011.05.002
20. [20]
  (20) Xue,W. J.; Zhang, X. Y.; Li, P.; Liu, Z. T.; Hao, Z. P.; Ma, C. Y. Acta Phys. -Chim. Sin. 2011, 27, 1730. [薛雯娟, 张新艳, 李鹏, 刘昭铁, 郝郑平, 麻春艳. 物理化学学报, 2011, 27, 1730.]d oi: 10.3866/PKU.WHXB20110719
21. [21]
  (21) Yao, L.; Zhu, J. Q.; Peng, X. X.; Tong, D. M.; Hu, C.W. Int. J. Hydrog. Energy 2013, 38, 7268. doi: 10.1016/j.ijhydene.2013.02.126
22. [22]
  (22) Wang, L.; Li, D. L.; Koike, M.;Watanable, H.; Xu, Y.; Nakagawa, Y.; Tomishige, K. Fuel 2013, 112, 654. doi: 10.1016/j.fuel.2012.01.073
23. [23]
  (23) Lin,W.W.; Cheng, H. Y.; He, L. M.; Yu, Y. C.; Zhao, F. Y. J. Catal. 2013, 303, 110. doi: 10.1016/j.jcat.2013.03.002
24. [24]
  (24) de Miguel, S. R.; Vilella, I. M. J.; Maina, S. P.; Jose-Alonso, D. S.; Roman-Martinez, M. C.; Illan- mez, M. J. Appl. Catal. AGen. 2012, 435, 10.
25. [25]
  (25) El-Temtamy, S. A.; Ghoneim, S. A.; El-Morsy, A. K.; El-Naggar, A. Y.; El-Salamouny, R. A. Petrol Sci. Technol. 2009, 27, 1661. doi: 10.1080/10916460802455897
26. [26]
  (26) Yu, X. P.;Wang, N.; Chu,W.; Liu, M. Chem. Eng. J. 2012, 209, 623. doi: 10.1016/j.cej.2012.08.037
27. [27]
  (27) Li, C. L.; Fu, Y. L.; Bian, G. Z. Acta Phys. -Chim. Sin. 2003, 19, 902. [李春林, 伏义路, 卞国柱. 物理化学学报, 2003, 19, 902.] doi: 10.3866/PKU.WHXB20031004
28. [28]
  (28) Qin, Z. Q.; Gao,W. G.;Wang, H.; Han, C.; Guo,W. Chemical Industry and Engineering Progress 2013, 32, 820. [覃志强, 高文桂, 王华, 韩冲, 郭伟. 化工进展, 2013, 32, 820.]
29. [29]
  (29) Wang, N.; Shen, K.; Yu, X. P.; Qian,W. Z.; Chu,W. Catal. Sci. Technol. 2013, 3, 2278. doi: 10.1039/c3cy00299c
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