Citation: YANG Bing-Jian, WANG Hong, Li Lei, HUANG Bo-Wen, LIAO Xiao-Zhen, HE Yu-Shi, MA Zi-Feng. Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 150-156. doi: 10.3866/PKU.WHXB201311142 shu

Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells

1.
Institute of Electrochemical and Energy Technology, Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 16 September 2013
Available Online: 14 November 2013
Fund Project: 国家重点基础研究发展规划项目(973) (2014CB932303) (973) (2014CB932303)国家自然科学基金(21073120，21336003，21006063)资助 (21073120，21336003，21006063)

The development of low-cost and effective electrocatalysts for air electrodes is critical for practical applications of lithium/oxygen batteries. In the present work, phenanthroline (phen) was used as a ligand to prepare a Co(phen)₂ complex. The Co(phen)₂ complex was coated on BP2000 and then heat treated at 600, 700, 800, and 900 ℃, to obtain carbon-supported Co-N (Co-N/C) catalysts. The catalytic activities in oxygen reduction reaction/oxygen evolution reaction (ORR/OER) of the prepared catalysts were measured and compared with those of a typical carbon-supported cobalt tetramethoxyphenylporphyrin (CoTMPP/C) catalyst. The influence of the calcination temperature on the composition and structure of the Co-N/C catalysts was investigated. Electrochemical tests showed that the Co-N/C catalysts prepared at 700 and 800 ℃ gave better performances, comparable to that of the CoTMPP/C catalyst. The superior electrochemical performance of the prepared Co-N/C catalysts and the low cost of the phenanthroline chelating agent make Co-N/C a promising cheap catalyst for lithium/oxygen batteries.
- Rechargeable lithium/oxygen battery,
- Oxygen electrode,
- ORR/OER catalyst,
- Cobalt phenanthroline complex,
- Calcination temperature
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O2 Cells

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通讯作者: 陈斌, bchen63@163.com

Influence of Calcination Temperature on Performances of Co-N/C Electrocatalysts for Li/O₂ Cells