Citation: CHEN Yi-Jian, LIU Teng, ZHAI Xue-Ru, XU Gui-Ying. Comparative Study on the Aggregation Behaviors of X-Shaped and Linear Block Polyethers at the Air/Water and n-Heptane/Water Interfaces[J]. Acta Physico-Chimica Sinica, ;2014, 30(1): 102-110. doi: 10.3866/PKU.WHXB201311071 shu

Comparative Study on the Aggregation Behaviors of X-Shaped and Linear Block Polyethers at the Air/Water and n-Heptane/Water Interfaces

1.
Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 11 July 2013
Available Online: 7 November 2013
Fund Project: 国家自然科学基金(20573067，20873077) (20573067，20873077)国家科技重大专项(2011ZX05024-004-08)资助项目 (2011ZX05024-004-08)

Linear block polyethers, i.e., poly(ethylene oxide) (PEO)-poly(propylene oxide) (PPO)-PEO (LPE), and X-shaped block polyethers, i.e., PEO-PPO-PEO (TPE), with same EO/PO ratios and molecular masses were synthesized by anionic polymerization. The aggregation behaviors at air/water and n-heptane/water interfaces were systematically studied. The results show that LPE is more efficient at decreasing the surface tension of water and n-heptane than TPE is. The dynamic interfacial tension curves indicate that the lag-time of the adsorption of the block polyethers at the n-heptane/water interface is smaller than that at the air/water surface, implying that immersion of the PO groups in the oil phase is more energetically favorable than immersion in the air phase. The oil molecules can insert into the adsorption layer, and hydrophobic interactions between oil molecules and PO moieties lead to a relatively ordered arrangement of adsorbed polyether molecules. At the n-heptane/water interface, diffusion of the block polyethers is faster than that at the air/water surface. The dilatational elasticity at the n-heptane/water interface is much higher than that at the air/water surface.
- X-shaped block polyether,
- Interfacial activity,
- Interfacial dilational viscoelasticity,
- Interfacial aggregation behavior
1. [1]
  
  (1) Alexandridis, P.; Hatton, T. A. Colloids Surf. A 1995, 96, 1. doi: 10.1016/0927-7757(94)03028-X
2. [2]
  (2) Zana, R.; Marques, C.; Johner, A. Adv. Colloid Interface Sci. 2006, 123, 345.
3. [3]
  (3) Noskov, B. A.; Lin, S. Y.; Loglio, G.; Rubio, R. G.; Miller, R. Langmuir 2006, 22, 2647. doi: 10.1021/la052662d
4. [4]
  (4) Díez-Pascual, A. M.; Monroy, F.; Ortega, F.; Rubio, R. G.; Miller, R.; Noskov, B. A. Langmuir 2007, 23, 3802. doi: 10.1021/la062936c
5. [5]
  (5) ng, H.; Xu, G.; Ding, H.; Shi, X.; Tan, Y. Eur. Polym. J. 2009, 45, 2540. doi: 10.1016/j.eurpolymj.2009.05.027
6. [6]
  (6) Shou, Q. H.; Guo, C.; Yang, L.; Jia, L. W.; Liu, C. Z.; Liu, H. Z. J. Colloid Interface Sci. 2011, 363, 481. doi: 10.1016/j.jcis.2011.07.021
7. [7]
  (7) Kadam, Y.; Singh, K.; Maran ni, D. G.; Ma, J. H.; Aswal, V. K.; Bahadur, P. J. Colloid Interface Sci. 2010, 351, 449. doi: 10.1016/j.jcis.2010.07.046
8. [8]
  (8) Mansur, C. R.; Barboza, S. P.; nzález, G.; Lucas, E. F. J. Colloid Interface Sci. 2004, 271, 232. doi: 10.1016/j.jcis.2003.11.034
9. [9]
  (9) Washington, C.; King, S. M.; Heenan, R. K. J. Phys. Chem. 1996, 100, 7603. doi: 10.1021/jp953007p
10. [10]
  (10) Zhang, Z. Q.; Xu, G. Y.; Wang, F.; Dong, S. L.; Chen, Y. J. J. Colloid Interface Sci. 2005, 282, 1. doi: 10.1016/j.jcis.2004.08.144
11. [11]
  (11) Zhang, Z. Q.; Xu, G. Y.; Wang, F.; Dong, S. L.; Li, Y. M. J. Colloid Interface Sci. 2004, 277, 464. doi: 10.1016/j.jcis.2004.04.035
12. [12]
  (12) Wang, F.; Xu, G. Y.; Zhang, Z. Q.; Xin, X. Eur. J. Inorg. Chem. 2006, 1, 109.
13. [13]
  (13) Xin, X.; Xu, G. Y.; Zhao, T. T.; Zhu, Y. Y.; Shi, X. F.; ng, H. J.; Zhang, Z. Q. J. Phys. Chem. C 2008, 112, 16377. doi: 10.1021/jp8059344
14. [14]
  (14) ng, H. J.; Xu, G. Y.; Liu, T.; Pang, J. Y.; Dou, W. L.; Xin, X. Colloid. Polym. Sci. 2011, 289, 933. doi: 10.1007/s00396-011-2419-7
15. [15]
  (15) Liu, T.; Xu, G. Y.; Zhang, J.; Zhang, H. H.; Pang, J. Y. Colloid. Polym. Sci. 2013, 291, 691. doi: 10.1007/s00396-012-2776-x
16. [16]
  (16) Cao, X. R.; Xu, G. Y.; Yuan, S. L.; Gao, B. Y. Soft Matter 2011, 7, 9035. doi: 10.1039/c1sm05319a
17. [17]
  (17) Chiappetta, D. A.; Alvarez-Lorenzo, C.; Rey-Rico, A.; Taboada, P.; Concheiro, A.; Sosnik, A. Eur. J. Pharm. Biopharm. 2010, 76, 24. doi: 10.1016/j.ejpb.2010.05.007
18. [18]
  (18) Dong, J. F.; Chowdhry, B. Z.; Leharne, S. A. Colloids Surf. A 2003, 212, 9. doi: 10.1016/S0927-7757(02)00295-9
19. [19]
  (19) nzalez-Lopez, J.; Alvarez-Lorenzo, C.; Taboada, P.; Sosnik, A.; Sandez-Macho, I.; Concheiro, A. Langmuir 2008, 24, 10688. doi: 10.1021/la8016563
20. [20]
  (20) Zhai, X. R.; Xu, G. Y.; Chen, Y. J.; Liu, T.; Zhang, J.; Yuan, J.; Tan, Y. B.; Zhang, J. DOI: 10.1007/s00396-013-3013-y, in press.
21. [21]
  (21) Alexandridis, P.; Athanassiou, V.; Hatton, T. A. Langmuir 1995, 11, 2442. doi: 10.1021/la00007a022
22. [22]
  (22) ng, H. J.; Xu, G. Y.; Liu, T.; Xu, L.; Zhai, X. R.; Zhang, J.; Lv, X. Langmuir 2012, 28, 13590. doi: 10.1021/la303430c
23. [23]
  (23) Mulqueen, M.; Blankschtein, D. Langmuir 2001, 18, 365.
24. [24]
  (24) Kim, Y. H.; Wasan, D. T.; Breen, P. J. Colloids Surf., A 1995, 95, 235. doi: 10.1016/0927-7757(94)03032-U
25. [25]
  (25) Aveyard, R.; Binks, B. P.; Fletcher, P. D. I.; Lu, J. R. J. Colloid Interface Sci. 1990, 139, 128. doi: 10.1016/0021-9797(90)90450-3
26. [26]
  (26) Vieira, J. B.; Li, Z. X.; Thomas, R. K. J. Phys. Chem. B 2002, 106, 5400. doi: 10.1021/jp013286i
27. [27]
  (27) Alexandridis, P.; Athanassiou, V.; Fukuda, S.; Hatton, T. A. Langmuir 1994, 10, 2604. doi: 10.1021/la00020a019
28. [28]
  (28) Liu, T.; Xu, G. Y.; ng, H.; Pang, J.; He, F. Langmuir 2011, 27, 9253. doi: 10.1021/la201676u
29. [29]
  (29) Wanka, G.; Hoffmann, H.; Ulbricht, W. Colloid. Polym. Sci. 1990, 268, 101. doi: 10.1007/BF01513189
30. [30]
  (30) Miller, R.; Fainerman, V. B.; Aksenenko, E. V.; Leser, M. E.; Michel, M. Langmuir 2004, 20, 771. doi: 10.1021/la030332s
31. [31]
  (31) Zhang, H. X.; Xu, G. Y.; Wu, D.; Wang, S. W. Colloids Surf. A 2008, 317, 289. doi: 10.1016/j.colsurfa.2007.10.033
32. [32]
  (32) Phang, T. L.; Liao, Y. C.; Franses, E. I. Langmuir 2004, 20, 4004. doi: 10.1021/la035424w
33. [33]
  (33) Hua X. Y.; Rosen, M. J. J. Colloid Interface Sci. 1988, 124, 652. doi: 10.1016/0021-9797(88)90203-2
34. [34]
  (34) Rosen, M. J.; Song, L. D. J. Colloid Interface Sci. 1996, 179, 261. doi: 10.1006/jcis.1996.0212
35. [35]
  (35) Nahringbauer, I. J. Colloid Interface Sci. 1995, 176, 318. doi: 10.1006/jcis.1995.9961
36. [36]
  (36) Fainerman, V. B.; Lylyk, S. V.; Aksenenko, E. V.; Liggieri, L.; Makievski, A. V.; Petkov, J. T.; Yorke, J.; Miller, R. Colloids Surf. A 2009, 334, 8.
37. [37]
  (37) Knock, M. M.; Bell, G. R.; Hill, E. K.; Turner, H. J.; Bain, C. D. J. Phys. Chem. B 2003, 107, 10801. doi: 10.1021/jp027047m
38. [38]
  (38) Chanda, J.; Bandyopadhyay, S. J. Phys. Chem. B 2006, 110, 23482. doi: 10.1021/jp063205o
39. [39]
  (39) Zhang, L.; Wang, X. C.; ng, Q. T.; Luo, L.; Zhao, S.; Yu, J. Y. J. Colloid Interface Sci. 2008, 327, 451. doi: 10.1016/j.jcis.2008.08.019
40. [40]
  (40) Wang, Z. L.; Li, Z. Q.; Zhang, L.; Huang, H. Y.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Chem. Eng. Data 2011, 56, 2393. doi: 10.1021/je1013312
41. [41]
  (41) Zong, H.; Wang, L.; Fang, H. B.; Mao, L. T.; Wang, Y. H.; Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin., 2010, 26, 2982. [宗华, 王磊, 方洪波, 毛雷霆, 王宇慧, 张路, 赵濉, 俞稼镛. 物理化学学报, 2010, 26, 2982.] doi: 10.3866/PKU.WHXB20101105
42. [42]
  (42) Zhang, L.; Wang, X. C.; ng, Q. T.; Luo, L.; Zhang, L.; Zhao, S.;Yu, J. Y. Acta Phys.-Chim. Sin., 2007, 23, 1652. [张磊, 王晓春, 宫清涛, 罗澜, 张路, 赵濉, 俞稼镛. 物理化学学报, 2007, 23, 1652.] doi: 10.3866/PKU.WHXB20071031
43. [43]
  (43) Li, X. L.; Zhang, L.; ng, Q. T.; Zhang, L.; Zhao, S.; Yu, J. Y. Acta Phys.-Chim. Sin., 2010, 26, 631. [李秀兰, 张磊, 宫清涛, 张路, 赵濉, 俞稼镛. 物理化学学报, 2010, 26, 631.] doi: 10.3866/PKU.WHXB20100319
44. [44]
  (44) Noskov, B. A. Curr. Opin. Colloid Interface Sci. 2010, 15, 229. doi: 10.1016/j.cocis.2010.01.006
45. [45]
  (45) Liggieri, L.; Miller, R. Curr. Opin. Colloid Interface Sci. 2010, 15, 256. doi: 10.1016/j.cocis.2010.02.003
46. [46]
  (46) Huang, Y. P.; Zhang, L.; Zhang, L.; Luo, L.; Zhao, S.; Yu, J. Y. J. Phys. Chem. B 2007, 111, 5640. doi: 10.1021/jp070997t
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