Citation: LIU Wen-Han, YUAN Rong-Hui, TENG Yuan-Jie, MA Chun-An. Electrochemical SERS of Self-Assembled Monolayer of Thiosalicylic Acid Adsorbed on Activated ld Electrodes[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2599-2607. doi: 10.3866/PKU.WHXB201310231 shu

Electrochemical SERS of Self-Assembled Monolayer of Thiosalicylic Acid Adsorbed on Activated ld Electrodes

1.
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 29 July 2013
Available Online: 23 October 2013
Fund Project: 国家自然科学基金(10804099) (10804099) 浙江省科技厅公益项目(2012C37014) (2012C37014)浙江省重点科技创新团队(2011R09002-12)资助 (2011R09002-12)

Amonolayer film of thiosalicylic acid (TSA) adsorbed on activated ld electrodes was investigated by using in situ electrochemical surface-enhanced Raman scattering (EC-SERS). In the SERS spectra of selfassembled monolayers in solutions with different pH values, two peaks with Raman intensities that decreased with increasing pH were observed. The optimum EC-SERS signals were obtained at 0.7 V and 70 s, and it was found that the intensities became weaker, and the peaks eventually disappeared, when the potential was negatively shifted. This showed that the alignments of TSA assembled on the ld surface changed in response to changes in the external conditions. The absorption mechanism of the TSA monolayer was investigated by calculating the distribution fraction of TSA at different pH values and the enhancement factor (EF) at different potentials, using a combination of SERS and EC-SERS. As a result of different electrochemical absorption orientations of TSA and its reduction/desorption behavior at high negative potentials, the Raman enhanced effect of TSA on ld was significantly reduced and the SERS activity was irreversibly lost.
- Electrochemical surface-enhanced Raman scattering,
- Thiosalicylic acid,
- Self-assembled monolayer,
- ld electrode,
- Enhancement factor
1. [1]
  
  (1) Titus, E. J.;Weber, M. L.; Stranahan, S. M.;Willets, K. A. Nano Lett. 2012, 12 (10), 5103. doi: 10.1021/nl3017779
2. [2]
  (2) Su, Q. Q.; Ma, X. Y.; Dong, J.; Jiang, C. Y.; Qian,W. P. ACS Appl. Mater. Interfaces 2011, 3 (6), 1873. doi: 10.1021/am200057f
3. [3]
  (3) Freye, C. E.; Crane, N. A.; Kirchner, T. B.; Sepaniak, M. J.Anal. Chem. 2013, 85(8), 3991. doi: 10.1021/ac303710q
4. [4]
  (4) Wang, Y. Q.; Yan, B.; Chen, L. X. Chem. Rev. 2013, 113 (3),1391. doi: 10.1021/cr300120g
5. [5]
  (5) Chu, H.; Yang, H. F.; Huan, S. Y.; Shen, G. L.; Yu, R. Q. J. Phys. Chem. B 2006, 110 (11), 5490. doi: 10.1021/jp053914m
6. [6]
  (6) Kho, K.W.; Dinish, U. S.; Kumar, A.; Olivo, M. ACS Nano2012, 6 (6), 4892. doi: 10.1021/nn300352b
7. [7]
  (7) Monnell, J. D.; Stapleton, J. J.; Dirk, S. M.; Reinerth,W. A.;Tour, J. M.; Allara, D. L.;Weiss, P. S. J. Phys. Chem. B 2005,109 (43), 20343. doi: 10.1021/jp044186q
8. [8]
  (8) Sumner, J. J.; Creager, S. E. J. Phys. Chem. B 2001, 105 (37),8739. doi: 10.1021/jp011229j
9. [9]
  (9) Napper, A. M.; Liu, H. Y.;Waldeck, D. H. J. Phys. Chem. B2001, 105 (32), 7699. doi: 10.1021/jp0105140
10. [10]
  (10) Bertin, P. A.; Ahrens, M. J.; Bhavsar, K.; Georganopoulou, D.;Wunder, M.; Blackburn, G. F.; Meade, T. Org. Lett. 2010, 12 (15), 3372. doi: 10.1021/ol101180r
11. [11]
  (11) Ameer, F. S.; Hu,W. F.; Ansar, S. M.; Siriwardana, K.; Collier,W. E.; Zou, S. L.; Zhang, D. M. J. Phys. Chem. C 2013, 117 (7),3484.
12. [12]
  (12) Dasary, S. S. R.; Singh, A. K.; Senapati, D.; Yu, H. T.; Ray, P. C.J. Am. Chem. Soc. 2009, 131 (38), 13806. doi: 10.1021/ja905134d
13. [13]
  (13) Xie,W.;Walkenfort, B.; Schlu cker, S. J. Am. Chem. Soc. 2013,135 (5), 1657. doi: 10.1021/ja309074a
14. [14]
  (14) Yang, Y. C.; Xia, Y.; Huang,W.; Zheng, J. F.; Li, Z. L. J. Solid State Electrochem. 2012, 16 (4), 1733. doi: 10.1007/s10008-011-1600-8
15. [15]
  (15) Ohta, N.; Yagi, I. J. Phys. Chem. C 2008, 112 (45), 17603. doi: 10.1021/jp806599r
16. [16]
  (16) Carron, K. T.; Hurley, L. G. J. Phys. Chem. 1991, 95 (24),9979. doi: 10.1021/j100177a068
17. [17]
  (17) Ke, Y. K.; Dong, H. R. Handbook of Analytical Chemistry: Spectrial Analysis; Chemical Industry Press: Beijing, 1998; pp1153-1160. [柯以侃, 董慧茹. 分析化学手册: 光谱分析. 北京: 化学工业出版社, 1998: 1153-1160.]
18. [18]
  (18) Schalnat, M. C.; Pemberton, J. E. Langmuir 2010, 26 (14),11862. doi: 10.1021/la1010314
19. [19]
  (19) Dean, J. A. Lange's Handbook of Chemistry; Science Press:Beijing, 1991; p 59; translated by Shang, J. F., Cao, S. J., Xin,W. M. [Dean, J. A. 兰氏化学手册. 尚久方, 操时杰, 辛无名,译. 北京: 科学出版社, 1991: 59.]
20. [20]
  (20) Gao, X. P.; Davies, J. P.;Weaver, M. J. J. Phys. Chem. 1990, 94 (17), 6858. doi: 10.1021/j100380a059
21. [21]
  (21) Moskovits, M.; Suh, J. S. J. Phys. Chem. 1988, 92 (22),6327. doi: 10.1021/j100333a030
22. [22]
  (22) Kolega, R. R.; Schlenoff, J. B. Langmuir 1998, 14 (19),5469. doi: 10.1021/la980553b
23. [23]
  (23) Ji,W.; Kitahama, Y.; Han, X. X.; Xue, X. X.; Ozaki, Y.; Zhao,B. J. Phys. Chem. C 2012, 116 (46), 24829. doi: 10.1021/jp308805n
24. [24]
  (24) Shafer-Peltier, K. E.; Haynes, C. L.; Glucksberg, M. R.; VanDuyne, R. P. J. Am. Chem. Soc. 2003, 125 (2), 588. doi: 10.1021/ja028255v
25. [25]
  (25) Amaya, R. O.; Rappoport, D.; Munoz, P. A.; Peng, P.; Mazur, E.;Guzik, A. A. J. Phys. Chem. C 2012, 116 (29), 15568. doi: 10.1021/jp302597v
26. [26]
  (26) Le-Ru, E. C.; Blackie, E.; Meyer, M.; Etche in, P. G. J. Phys. Chem. C 2007, 111 (37), 13794. doi: 10.1021/jp0687908
27. [27]
  (27) Jia, H. Y. Synthesis, Characterization of SERS ActiveNanoparticles. Ph. D. Dissertation, Jilin University, Changchun,2006. [贾慧颖. 银纳米粒子的制备、表征及其表面增强拉曼散射活性研究[D]. 长春: 吉林大学, 2006.]
28. [28]
  (28) Stolberg, L.; Lipkowski, J.; Irish, D. E. J. Electroanal. Chem.1990, 296, 171. doi: 10.1016/0022-0728(90)87241-B
29. [29]
  (29) Trasatti, S.; Petrii, O. A. Pure & Appl. Chem. 1991, 63 (5),711. doi: 10.1351/pac199163050711
30. [30]
  (30) Cai,W. B.; Ren, B.; Li, X. Q.; She, C. X.; Liu, F. M.; Cai, X.W.; Tian, Z. Q. Surf. Sci. 1998, 406, 9.
31. [31]
  (31) Álvarez-Puebla, R. A. J. Phys. Chem. Lett. 2012, 3 (7), 857.doi: 10.1021/jz201625j
1. [1]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
2. [2]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
3. [3]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
4. [4]
  Xue Wu , Yupeng Liu , Bingzhe Wang , Lingyun Li , Zhenjian Li , Qingcheng Wang , Quansheng Cheng , Guichuan Xing , Songnan Qu . Rationally assembling different surface functionalized carbon dots for enhanced near-infrared tumor photothermal therapy. Acta Physico-Chimica Sinica, 2025, 41(9): 100109-0. doi: 10.1016/j.actphy.2025.100109
5. [5]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
6. [6]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-0. doi: 10.3866/PKU.WHXB202405002
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Xiaofang Li , Zhigang Wang . 调节金助催化剂的d_z²占据轨道增强光催化合成H₂O₂. Acta Physico-Chimica Sinica, 2025, 41(7): 100080-0. doi: 10.1016/j.actphy.2025.100080
9. [9]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
10. [10]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
11. [11]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
12. [12]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
13. [13]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
14. [14]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
15. [15]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
16. [16]
  Renjie Xue , Chao Ma , Jing He , Xuechao Li , Yanning Tang , Lifeng Chi , Haiming Zhang . Catassembly in the Host-Guest Recognition of 2D Metastable Self-Assembled Networks. Acta Physico-Chimica Sinica, 2024, 40(9): 2309011-0. doi: 10.3866/PKU.WHXB202309011
17. [17]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
18. [18]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
19. [19]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
20. [20]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077

Get Citation

PDF

XML

Metrics

PDF Downloads(661)
Abstract views(1003)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142