Citation: CAO Zhan-Min, XIE Wei, WANG Kun-Peng, NIU Chun-Ju, DU Guang-Wei, QIAO Zhi-Yu. Thermodynamic Optimization of the Al-Fe-P Ternary System[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2148-2156. doi: 10.3866/PKU.WHXB201307291 shu

Thermodynamic Optimization of the Al-Fe-P Ternary System

1.
1 State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science & Technology Beijing, Beijing 100083, P. R. China;
2 School of Materials Science and Engineering, University of Science & Technology Beijing, Beijing 100083, P. R. China

Received Date: 1 April 2013
Available Online: 29 July 2013
Fund Project: 国家自然科学基金(50934011, 51274034) (50934011, 51274034)中央高校基础研究基金(FRF-SD-12-010A)资助项目 (FRF-SD-12-010A)

A critical thermodynamic optimization of the Al-Fe-P ternary system was performed using the CALPHAD method. Among the sub-binary systems in the Al-Fe-P system, the Al-P systemwas reassessed according to its related experimental information. The thermodynamic descriptions of the Al-Fe and Fe-Pbinary systems were taken from previous studies with minor modifications. The parameters of the thermodynamic model of the Al-Fe-P ternary systemwere optimized based on available experimental phase diagramdata and thermodynamic properties. One set of consistent parameters of the Gibbs energies of all phases, which can satisfactorily reproduce most of the experimental phase diagramdata, was obtained. By employing the driving force criterion with the present thermodynamic description, the experimentally reported composition dependence of the glass-forming ability of the Al-Fe-P systemcould be explained thermodynamically.
- Al-Fe-P,
- Phase diagram,
- Thermodynamics,
- Optimization,
- Glass forming ability
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