Citation: QIAO Yin-Po, YIN Hai-Rong, ZHANG Yan-Bin, PAN Yun-Juan, QIAO Lu, LIU Ting. Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃[J]. Acta Physico-Chimica Sinica, ;2013, 29(09): 2056-2061. doi: 10.3866/PKU.WHXB201307091 shu

Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃

1.
School of Materials Science and Engineering, Shaanxi University of Science & Technology, Xi'an 710021, P. R. China

Received Date: 31 January 2013
Available Online: 9 July 2013
Fund Project: 中国博士后科学基金面上项目(20110491640) (20110491640)陕西省教育厅科研计划项目(11JK0839) (11JK0839)陕西科技大学科研启动基金项目(BJ10-11) (BJ10-11)陕西科技大学创新创业训练计划项目(201310708008, 201210708011)资助 (201310708008, 201210708011)

Aseries of luminescent glass composed of CaO-CaF₂-B₂O₃-SiO₂ doped with samariumoxide (CFBS: Sm) were prepared. The structure, infrared transmittance and fluorescent properties of the samples were investigated by X-ray diffraction (XRD), Fourier transforminfrared (FTIR) spectroscopy and photoluminescence (PL) measurements, respectively. The XRD patterns of the CFBS:S msamples showed that the glass matrix had a non-crystalline structure, while the FTIR spectra exhibited shifts of absorption wavelength sensitive to the structure and function of the samples. The PL spectra of the CFBS:Smglasses showed the characteristic emission of Sm³⁺ centered at 566, 603 and 650 nmunder 404 nmexcitation, and their luminescence color was red-orange (x=0.531, y=0.371). Furthermore, the intensity of emission and fluorescent lifetime of Sm³⁺ at 603 nm (⁴G_5/2) increased with the molar ratio of CaF₂ in the glass samples. The enhanced intensity of emission, fluorescent lifetime and quantumefficiency with increasing molar ratio of CaF₂ may result fromthe reduction of phonon energy in the CFBS:S mglass because some CaF₂ substitutes CaO in the glass matrix.
- Rare earth doped,
- Luminescent glass,
- Calciumfluoride,
- Photoluminescence,
- Fluorescent life,
- Quantumefficiency
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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced Photoluminescence Properties of CaF2 in CaO-CaF2-B2O3-SiO2 Glass Doped with Sm2O3

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通讯作者: 陈斌, bchen63@163.com

Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃