Citation: SUN Hong-Yan, ZHAO Lian-Hua, Yu Feng-Chun. Preparation and Characterization of Pt-Ir-SnO₂/C Anode Catalyst for Direct Ethanol Fuel Cell[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 959-965. doi: 10.3866/PKU.WHXB201303042 shu

Preparation and Characterization of Pt-Ir-SnO₂/C Anode Catalyst for Direct Ethanol Fuel Cell

1.
Department of Chemistry, College of Science, Yanbian University, Yanji 133002, China

Received Date: 23 November 2012
Available Online: 4 March 2013
Fund Project: 吉林省科技发展计划(20120741)资助项目 (20120741)

Pt/C, Pt-Ir/C, Pt-SnO₂/C, and Pt-Ir-SnO₂/C anode electrocatalysts were prepared by an improved Bo? nnemann method. The crystal structure, surface morphology, particle size, and surface electronic structure were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). XRD and TEM revealed that Pt nanoparticles had a face-centered cubic structure, and that dispersions were relatively homogeneous with particle sizes of 2-4 nm. Electrocatalytic activities were characterized using linear sweep voltammetry (LSV), cyclic voltammetry (CV), and amperometric (j-t) curve techniques. Catalytic performance improved with increasing temperature, and catalytic activity of Pt-Ir-SnO₂/C was optimal under these conditions. Arrhenius formula calculations showed that the synergy between Ir and Sn reduced the activation energy of Pt-Ir-SnO₂/C catalysts for the oxidation of ethanol.
- Platinum,
- Iridium,
- Stannic oxide,
- Ethanol electrooxidation,
- Activation energy,
- Direct ethanol fuel cell
1. [1]
  
  (1) Li, N. N.; Zhang, S. H.; Lei, L. Southern Metals 2009, 169 (4),1. [李娜娜, 张绍红, 雷力. 南方金属, 2009, 169 (4), 1.]
2. [2]
  (2) Chu, D.;Wang, J.;Wang, S.; Zha, L.; He, J.; Hou, Y.; Yan, Y.;Lin, H.; Tian, Z. Catal. Commun. 2009, 10 (6), 955.doi: 10.1016/j.catcom.2008.12.041
3. [3]
  (3) Lamy, C.; Belgsir, E. M.; L'eger, J. M. J. Appl. Electrochem.2001, 31 (7), 799. doi: 10.1023/A:1017587310150
4. [4]
  (4) Antolini, E. J. Power. Sources 2007, 170, 1. doi: 10.1016/j.jpowsour.2007.04.009
5. [5]
  (5) Li, H. Q.; Sun, G. Q.; Cao, L.; Jiang, L. H.; Xin, Q.Electrochim. Acta 2007, 52, 6622. doi: 10.1016/j.electacta.2007.04.056
6. [6]
  (6) Tang, Y.W.; Ma, G. X.; Zhou, Y. M.; Bao, J. C.; Lu, L. D.; Lu,T. H. Acta Phys. -Chim. Sin. 2008, 24 (9), 1615. [唐亚文, 马国仙, 周益明, 包建春, 陆路德, 陆天虹. 物理化学学报, 2008, 24 (9), 1615.] doi: 10.3866/PKU.WHXB20080915
7. [7]
  (7) Chu, D. B.; Yin, X. J.; Feng, D. X.; Lin, H. S.; Tian, Z.W. ActaPhys. -Chim. Sin. 2006, 22 (9), 1238. [褚道葆, 尹晓娟, 冯德香, 林华水, 田昭武. 物理化学学报, 2006, 22 (9), 1238.]doi: 10.3866/PKU.WHXB20061013
8. [8]
  (8) Song, S. Q.; Chen, L. K.; Liu, J. G.;Wei, Z. B.; Xin, Q.Electrochemistry 2002, 8 (1), 105. [宋树芹, 陈利康, 刘建国,魏昭彬, 辛勤. 电化学, 2002, 8 (1), 105.]
9. [9]
  (9) Gao, H. L.; Liao, S. J.; Zeng, J. H.; Liang, Z. X.; Xie, Y. C. ActaPhys. -Chim. Sin. 2010, 26 (12), 3193. [高海丽, 廖世军, 曾建皇, 梁振兴, 谢义淳. 物理化学学报, 2010, 26 (12), 3193.]doi: 10.3866/PKU.WHXB20101214
10. [10]
  (10) Xu, Z. F.;Wang, Y. X. J. Phys. Chem. C 2011, 115, 20565.doi: 10.1021/jp206051k
11. [11]
  (11) Jiang, L. H. Research on Anode Electrocatalysts for DirectAlcohol Fuel Cell. Physical. Chemistry. Ph. D. Dissertation,Dalian Institute of Chemical Physics, Chinese Academy ofSciences, Dalian, 2005. [姜鲁华. 直接醇类燃料电池阳极铂基电催化剂的研究[D]. 大连: 中国科学院大连化学物理研究所, 2005.]
12. [12]
  (12) Corbel, G.; Topic, M.; Gibaud, A.; Lang, C. I. J. Alloy. Compd.2011, 509, 6532. doi: 10.1016/j.jallcom.2011.03.079
13. [13]
  (13) Jiang, L. H.; Sun, G. Q.; Sun, S. G.; Liu, J. G.; Tang, S. H.; Li,H. Q.; Zhou, B.; Xin, Q. Electrochim. Acta 2005, 50, 5384.doi: 10.1016/j.electacta.2005.03.018
14. [14]
  (14) Zhou,W. J.; Li,W. Z.; Song, S. Q.; Zhou, Z. H.; Jiang, L. H.;Sun, G. Q. J. Power Sources 2004, 131, 217. doi: 10.1016/j.jpowsour.2003.12.040
15. [15]
  (15) Vigier, F.; Coutanceau, C.; Hahn, F.; Belgsir, E. M.; Lamy, C.J. Electroanal. Chem. 2004, 563, 81. doi: 10.1016/j.jelechem.2003.08.019
16. [16]
  (16) Takeguchi, T.;Wang, G. X.; Muhamad, E. N.; Ueda,W. ECSTransactions 2008, 16 (2), 713.
17. [17]
  (17) Li, M.; Kowala, A.; Sasakia, K.; Marinkovicb, N.; Suc, D.;Korachd, E.; Liua, P.; Adzica, R. R. Electrochim. Acta 2010, 55,4331. doi: 10.1016/j.electacta.2009.12.071
18. [18]
  (18) Tayal, J.; Rawat, B.; Basu, S. Int. J. Hydrog. Energy 2012, 37,4597. doi: 10.1016/j.ijhydene.2011.05.188
19. [19]
  (19) Zhao, L. H.; Mitsushima, S.; Ishihara, A.; Matsuzawa, K.; Ota,K. Chin. J. Catal. 2011, 32, 1856. doi: 10.1016/S1872-2067(10)60297-5
20. [20]
  (20) Lee, E.; Park, I. S.; Manthiram, A. J. Phys. Chem. C 2010, 114,10634.
21. [21]
  (21) Patri'cia, S. C.; Elen, L. S.; Renato, F. S.; Cla'udio, R.; Berta,M.; Eva, C.; Ce'lia, F. M. Int. J. Hydrog. Energy 2012, 37, 9314.doi: 10.1016/j.ijhydene.2012.03.022
22. [22]
  (22) Lee, E.; Murthy, A.; Manthiram, A. Electrochim. Acta 2011, 56,1611. doi: 10.1016/j.electacta.2010.10.086
23. [23]
  (23) Cao, L.; Sun, G. Q.; Li, H. Q.; Xin, Q. Electrochem. Commun.2007, 9, 2541. doi: 10.1016/j.elecom.2007.07.031
24. [24]
  (24) Ioroi, T.; Kitazawa, N.; Yasuda, K.; Yamamoto, Y.; Takeraka, H.J.Electrochem. Soc. 2000, 147, 2018. doi: 10.1149/1.1393478
25. [25]
  (25) Ioroi, T.; Yasuda, K.; Yamamoto, Y. J. Electrochem. Soc. 2005,152, A1917.
26. [26]
  (26) Li, M.; Cullen, D. A.; Sasaki, K.; Marinkovic, N. S.; More, K.;Adzic, R. R. J. Am. Chem. Soc. 2013, 135, 132. doi: 10.1021/ja306384x
27. [27]
  (27) Bönnemann, H.; Brijoux,W.; Brinkmann, R.; Dinjus, E.;Joussen, T.; Korall, B. Angew. Chem. Int. Edit. 1991, 30, l312.
28. [28]
  (28) Tayal, J.; Rawat, B.; Basu, S. Int. J. Hydrog. Energy 2011, 36 (22), 14884. doi: 10.1016/j.ijhydene.2011.03.035
29. [29]
  (29) Radmilovic, V.; Gasteiger, H. A.; Ross, P. N. J. Catal. 1995,154, 98. doi: 10.1006/jcat.1995.1151
30. [30]
  (30) Jiang, L. H.; Zhou, Z. H.; Zhou,W. J.;Wang, S. L.;Wang, G.X.; Sun, G. Q.; Xin, Q. Chem. J. Chin. Univ. 2004, 25, 1511.[姜鲁华, 周振华, 周卫江, 王素力, 汪国雄, 孙公权, 辛勤.高等学校化学学报, 2004, 25, 1511.]
31. [31]
  (31) Dohle, H.; Divisek, J.; Mergel, J.; Oetien, H. F.; Zingler, C.;Stolten, D. J. Power Source 2002, 105 (2), 274. doi: 10.1016/S0378-7753(01)00953-3
32. [32]
  (32) Somorjai, G. A. J. Phys. Chem. 1990, 94, 1013. doi: 10.1021/j100366a001
33. [33]
  (33) Chen G. Y.; Delafuente, D. A.; Sarangapani, S.; Mallouk, T. E.Catal. Today 2001, 67, 341. doi: 10.1016/S0920-5861(01)00327-3
34. [34]
  (34) Arico, A. S.; Kim, H.; Shukal, A. K.; Ravikumar, M. K.;Antonucci, V.; Giordano, N. Electrochem. Acta 1994, 39 (5),691. doi: 10.1016/0013-4686(94)80012-X
35. [35]
  (35) Choong, G. L.; Takashi, I.; Mohamed, M. Technological Report2003, 7 (71), 549.
36. [36]
  (36) Wen, G. Y.; Zhang, Y.; Yang, Z. L.; Li, C. Z. Electrochimistry1998, 4 (1), 73. [文纲要, 张颖, 杨正龙, 李长志. 电化学,1998, 4 (1), 73.]
37. [37]
  (37) Wang, J. Q.;Wu,W. H.; Feng, D. M. Electron Spectroscopy(XPS/XAES/UPS) Introduction; National Defence IndustryPress: Beijing, 1992; p 53. [王建祺, 吴文辉, 冯大明. 电子能谱学(XPS/XAES/UPS)引论. 北京: 国防工业出版社, 1992:53.]
1. [1]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
2. [2]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
3. [3]
  Yucheng Shan , Liming Xu , Peng Sun , Zhijing Zhu , Chenglong Wang , Jinliang Li , Guang Yang , Likun Pan . A data-driven approach for rapid revealing of metal doping in MnO₂ cathodes for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(7): 100232-. doi: 10.1016/j.actphy.2025.100232
4. [4]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
5. [5]
  Yucai Zhang , Jun Jiang . Electrochemical Carbon Dioxide Reduction to Ethylene. University Chemistry, 2026, 41(2): 190-196. doi: 10.12461/PKU.DXHX202503006
6. [6]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
7. [7]
  Xincan Zhou , Xueyao Wang , Xiaokang Chen , Di Lan , Yuting Gao , Xiaoxia Wang , Daohao Li , Shuchao Zhang , Lijie Zhang , Guanglei Wu . Charge redistribution on Pd mediated by electronically asymmetric carbon for boosting ethanol oxidation. Acta Physico-Chimica Sinica, 2026, 42(7): 100287-. doi: 10.1016/j.actphy.2026.100287
8. [8]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
9. [9]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
12. [12]
  Hailian Cheng , Shuaiqiang Jia , Chunjun Chen , Haihong Wu , Buxing Han . Electrocatalytic CO₂ Conversion: A Key to Unlocking a Low-Carbon Future. University Chemistry, 2026, 41(2): 1-13. doi: 10.12461/PKU.DXHX202502023
13. [13]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
14. [14]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
15. [15]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
16. [16]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
17. [17]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
18. [18]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
19. [19]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
20. [20]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049

Get Citation

PDF

XML

Metrics

PDF Downloads(884)
Abstract views(1500)
HTML views(95)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of Pt-Ir-SnO2/C Anode Catalyst for Direct Ethanol Fuel Cell

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of Pt-Ir-SnO₂/C Anode Catalyst for Direct Ethanol Fuel Cell