Citation: LIU Li, JIANG Wei, YANG Xi-Wen, CHEN Bin-Hua, WU Shi-Xi, LI Feng-Sheng. Facile Fabrication of Novel Magnetic and Fluorescent Fe₃O₄-CdSe Nanocomposites[J]. Acta Physico-Chimica Sinica, ;2013, 29(05): 1088-1096. doi: 10.3866/PKU.WHXB201302224 shu

Facile Fabrication of Novel Magnetic and Fluorescent Fe₃O₄-CdSe Nanocomposites

1.
National Special Superfine Powder Engineering Research Center,Nanjing University of Science & Technology, 200 Xiaolingwei Street, Xuanwu District, Nanjing, 210094, P. R. China

Received Date: 11 December 2012
Available Online: 22 February 2013
Fund Project: 国家自然科学基金(50972060) (50972060) 南京理工大学自主科研项目(2010ZDJH06) (2010ZDJH06)江苏省应用化学与材料领域研究生开放基金(2010ACMC07)资助 (2010ACMC07)

Novel Fe₃O₄-CdSe nanocomposites were prepared by depositing semiconductor on monodisperse magnetic nanoparticles. First, monodisperse Fe₃O₄ nanoparticles were fabricated by a solvothermal process in which iron acetylacetonate (Fe(acac)₃) was used as precursor, phenyl ether as reaction medium, oleic acid as surfactant and oleylamine (OAm) as both surfactant and reducing agent. Novel Fe₃O₄-CdSe heterostructures were prepared using 1-octadecene as high boiling solvent, cadmium oxide as Cd precursor, trioctyl phosphate (TOP)-Se as Se precursor, n-hexadecylamine (HDA) as surfactant, and stearic acid (SA) as growth promoter and nucleating agent. The structure and properties of the Fe₃O₄-CdSe nanocomposite were fully characterized by transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectrometry, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), UV-Vis spectrum, and photoluminescence (PL). CdSe nanoparticles were successfully attached to the surface of Fe₃O₄ and grew along the c-axis to form novel jujube pit-liked and nail-liked heterostructures with a width of 3.6 nm and length of 14.5 and 32.5 nm, respectively. The novel nanocomposites were a combination of magnetite Fe₃O₄ and hexa nal CdSe rods, and exhibited strong fluorescent emission without obvious quenching and excellent superparamagnetic properties. Fluorescent absorption shifts to longer wavelength as the length of the CdSe rods increases. The saturation magnetization of Fe₃O₄ nanoparticles, jujube pit liked and nail liked Fe₃O₄-CdSe nanocomposites were 57.80, 40.76, and 31.10 emu·g^-1, respectively.
- Iron oxide,
- Cadmium selenide,
- Nanocomposite,
- Magnetic property,
- Fluorescence
1. [1]
  
  (1) Gao, J. H.; Zhang,W.; Huang, P. B.; Zhang, B.; Zhang, X. X.;Xu, B. J. Am. Chem. Soc. 2008, 130, 3710. doi: 10.1021/ja7103125
2. [2]
  (2) Corr, S. A.; Rakovich, Y. P.; Guñko, Y. K. Nanoscale Res. Lett.2008, 3, 87. doi: 10.1007/s11671-008-9122-8
3. [3]
  (3) Burns, A.; Ow, H.;Wiesner, U. Chem. Soc. Rev. 2006, 35, 1028.doi: 10.1039/b600562b
4. [4]
  (4) Chen, S. T.; Xu, J. C.;Wang, Y. P.; Li, H. L. Acta Phys. -Chim.Sin. 2005, 21, 113. [陈书堂, 徐冀川, 汪裕萍, 力虎林. 物理化学学报, 2005, 21, 113.] doi: 10.3866/PKU.WHXB20050201
5. [5]
  (5) Wang, Y.; Tang, Z. Y.; Correa-Duarte, M. A.; Pastoriza-Santos,I.; Giersig, M.; Kotov, N. A.; Liz-Marzán, L. M. J. Phys. Chem.B 2004, 108, 15461. doi: 10.1021/jp048948t
6. [6]
  (6) Yu,W.W.; Peng, X. G. Angew. Chem. 2002, 114, 2474. doi: 10.1002/1521-3757(20020703)114:13<2474::AID-ANGE2474>3.0.CO;2-#
7. [7]
  (7) Hong, X.; Li, J.;Wang, M. J.; Xu, J. J.; Guo,W.; Li, J. H.; Bai,Y. B.; Li, T. J. Chem. Mater. 2004, 16, 4022. doi: 10.1021/cm049422o
8. [8]
  (8) Wang, D. S.; He, J. B.; Rosenzweig, N.; Rosenzweig, Z. NanoLett. 2004, 4, 409. doi: 10.1021/nl035010n
9. [9]
  (9) Kim, J.; Lee, J. E.; Lee, J.; Yu, J. H.; Kim, B. C.; An, K.;Hwang, Y.; Shin, C. H.; Park, J. G.; Kim, J.; Hyeon, T. J. Am.Chem. Soc. 2006, 128, 688. doi: 10.1021/ja0565875
10. [10]
  (10) Wang, Z. X.;Wu, L. M.; Chen, M.; Zhou, S. X. J. Am. Chem.Soc. 2009, 131, 11276. doi: 10.1021/ja903246e
11. [11]
  (11) Zeng,Y.; Hao, R.; Xing, B. G.; Hou, Y. L.; Xu, Z. C. Chem.Commun. 2010, 46, 3920. doi: 10.1039/c0cc00246a
12. [12]
  (12) Sun, S. H.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.;Wang, S. X.; Li, G. X. J. Am. Chem. Soc. 2004, 126, 273. doi: 10.1021/ja0380852
13. [13]
  (13) Song, Q.; Zhang, Z. J. J. Am. Chem. Soc. 2004, 126, 6164. doi: 10.1021/ja049931r
14. [14]
  (14) Trindade, T.; O'Brien, P.; Pickett, N. L. Chem. Mater. 2001, 13,3843. doi: 10.1021/cm000843p
15. [15]
  (15) Talapin, D. V.; Rogach, A. L.; Kornowski, A.; Haase, M.;Weller, H. Nano Lett. 2001, 1, 207. doi: 10.1021/nl0155126
16. [16]
  (16) Dabbousi, B. O.; Rodriguez-Viejo, J.; Mikulec, F. V.; Heine, J.R.; Mattoussi, H.; Ober, R.; Jensen, K. F.; Bawendi, M. G.J. Phys. Chem. B 1997, 101, 9463. doi: 10.1021/jp971091y
17. [17]
  (17) Woo, K.; Hong, J.; Choi, S.; Lee, H.W.; Ahn, J. P.; Kim, C. S.;Lee, S.W. Chem. Mater. 2004, 16, 2814. doi: 10.1021/cm049552x
18. [18]
  (18) Li, J. J.;Wang, Y. A.; Guo,W. Z.; Keay, J. C.; Mishima, T. D.;Johnson, M. B.; Peng, X. G. J. Am. Chem. Soc. 2003, 125,12567. doi: 10.1021/ja0363563
19. [19]
  (19) Cheng, F. Y.; Su, C. H.; Yang, Y. S.; Yeh, C. S.; Tsai, C. Y.;Wu,C. L.;Wu, M. T.; Shieh, D. B. Biomaterials 2005, 26, 729. doi: 10.1016/j.biomaterials.2004.03.016
20. [20]
  (20) Peng, Z. A.; Peng, X. G. J. Am. Chem. Soc. 2001, 123, 1389.doi: 10.1021/ja0027766
21. [21]
  (21) Zhang, J. Z.; Noguez, C. Plasmonics 2008, 3, 127. doi: 10.1007/s11468-008-9066-y
22. [22]
  (22) Yeh, Y.; Patra, D.; Yan, B.; Saha, K.; Miranda, O. R.; Kim, C.K.; Rotello, V. M. Chem. Commun. 2011, 47, 3069. doi: 10.1039/c0cc04975a
23. [23]
  (23) Yordanov, G. G.; Yoshimura, H.; Dushkin, C. D. Colloids andSurfaces A 2008, 322, 177. doi: 10.1016/j.colsurfa.2008.03.002
24. [24]
  (24) Nie, Q. L.; Yuan, Q. L.; Xu, Z. D.; Chen,W. X. ActaPhys. -Chim. Sin. 2003, 19, 1138. [聂秋林, 袁求理, 徐铸德,陈卫祥. 物理化学学报, 2003, 19, 1138.] doi: 10.3866/PKU.WHXB20031209
25. [25]
  (25) Manna, L.; Scher, E. C.; Alivisatos, A. P. J. Am. Chem. Soc.2000, 122, 12700.
26. [26]
  (26) Wang, X. P.; Xu, H. T.; Tao, L. M.;Wu, Y. Q.; An, Y. Q.; Du, Z.L.;Wu, S. X. Acta Phys. -Chim. Sin. 2009, 25, 1769. [王晓坡,许红涛, 陶磊明, 武艳强, 安艳清, 杜祖亮, 武四新. 物理化学学报, 2009, 25, 1769.] doi: 10.3866/PKU.WHXB20090831
27. [27]
  (27) Nirmal, M.; Murray, C. B.; Norris, D. J.; Bawendi, M. G. Z.Phys. D 1993, 26, 361. doi: 10.1007/BF01429195
28. [28]
  (28) Yang, H.; Holloway, P. H. J. Phys. Chem. B 2003, 107, 9705.
29. [29]
  (29) Mattoussi, H.; Mauro, J. M.; ldman, E. R.; Anderson, G. P.;Sundar, V. C.; Mikulec, F. V.; Bawendi, M. G. J. Am. Chem.Soc. 2000, 122, 12142. doi: 10.1021/ja002535y
30. [30]
  (30) Li, L. S.; Hu, J. T.; Yang,W. D.; Alivisatos, A. P. Nano Lett.2001, 1, 349. doi: 10.1021/nl015559r
31. [31]
  (31) Xu, Z. C.; Shen, C. M.; Hou, Y. L.; Gao, H. J.; Sun, S. H. Chem.Mater. 2009, 21, 1778. doi: 10.1021/cm802978z
32. [32]
  (32) Jun, Y.; Choi, J.; Cheon. J. Angew. Chem. Int. Edit. 2006, 45,3414. doi: 10.1002/anie.200503821
33. [33]
  (33) Yu,W.W.;Wang, Y. A.; Peng, X. G. Chem. Mater. 2003, 15,4300. doi: 10.1021/cm034729t
34. [34]
  (34) Dickerson, B. D.; Irving, D. M.; Herz, E.; Claus, R. O.;Spillman,W. B.; Meissner, K. E., Jr. Appl. Phys. Lett. 2005, 86,171915. doi: 10.1063/1.1921347
35. [35]
  (35) Karan, N. S.; Mandal, A.; Panda, S. K.; Pradhan, N. J. Phys.Chem. C 2010, 114, 8873.
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沈阳化工大学材料科学与工程学院沈阳 110142

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Facile Fabrication of Novel Magnetic and Fluorescent Fe₃O₄-CdSe Nanocomposites