Citation: TAO Jing-Liang, XIONG Yuan-Quan. Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 205-211. doi: 10.3866/PKU.WHXB201210264 shu

Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis

1.
Key Laboratory for Energy of Heat Conversion and its Process of Measurement and Control, School of Energy and Environment, SouthEast University, Nanjing, 210096, P. R. China

Received Date: 5 September 2012
Available Online: 26 October 2012
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB227002-02) (973) (2010CB227002-02)国家高技术研究发展计划项目(863) (2011AA05A201)资助 (863) (2011AA05A201)

High-energy electrons play the most important role in the decomposition of ethanol aqueous solutions under glow discharge plasma electrolysis (GDE). The non-Faradaic currents greatly improve, resulting in the actual gas production yield exceeding the theoretical yield. In this paper, we investigated a novel process of hydrogen generation from ethanol decomposition by GDE. The main gaseous products were H₂ and CO; in addition to small amounts of C₂H₄, CH₄, O₂, and C₂H₆. The H₂ volume fraction was above 59% and CO was 20%. We conclude that voltages of points C and D (V_C and V_D) do not change with the electrolyte concentration, but the 'Kellogg area' becomes narrower with increasing electrolyte conductivity and the glow discharge is easier to attain. In addition, with increasing ethanol volume fraction, the H₂ volume fraction decreases. The maximum gas production rate occurred for ethanol volume fractions of 30% and 80%. Improving the discharge voltage and raising the electrolyte conductivity had the same effect on glow discharge plasma electrolysis as the voltage load at both ends of the plasma steam sheath increases. The H₂ volume fraction remains the same upon varying the discharge voltage or electrolyte conductivity, but increasing the electrolyte conductivity is advantageous to reduce Joule heating effects caused by GDE.
- Glow discharge electrolysis,
- Gas generation rate,
- Electrolyte,
- Ethanol,
- Steam sheath,
- Hydrogen generation
1. [1]
  
  (1) Yan, Z. C.; Chen, L.;Wang, H. L. Acta Phys. -Chim. Sin. 2007,23, 835. [严宗诚, 陈砺, 王红林. 物理化学学报, 2007, 23,835.] doi: 10.3866/PKU.WHXB20070608
2. [2]
  (2) Sengupta, S. K.; Singh, O. P. J. Electroanal. Chem. 1994, 369,113. doi: 10.1016/0022-0728(94)87089-6.
3. [3]
  (3) Gao, J. Z.;Wang, X. Y.; Hu, Z. A.; Hou, J. G.; Lu, Q. F. Plasma Sci. Technol. 2001, 3, 765. doi: 10.1088/1009-0630/3/3/003
4. [4]
  (4) Sengupta, S. K.; Singh, R.; Srivastva, A. K. J. Electrochem. Soc.1998, 145, 2209. doi: 10.1149/1.1838621
5. [5]
  (5) Kuznetsova, N. I.; Kuznetsova, L. I.; Likholobov, V. A.; Pez, G.P. Catal. Today 2005, 99, 193. doi: 10.1016/j.cattod.2004.09.040
6. [6]
  (6) Sengupta, S. K.; Sandhir, U.; Misra, N. J. Polym. Sci. Part A: Polym. Chem. 2001, 39, 1584. doi: 10.1002/pola.1134
7. [7]
  (7) ng, J. Y.;Wang, J.; Xie,W. J.; Cai,W. M. J. Appl. Electrochem. 2008, 38, 1749. doi: 10.1007/s10800-008-9626-z
8. [8]
  (8) Yang, H.; Matsumoto, Y.; Tezuka, M. J. Environ. Sci. 2009, 21 (Suppl. 1), 142. doi: 10.1016/S1001-0742(09)60059-0
9. [9]
  (9) Campbell, S. A.; Cunnane, V. J.; Schiffrin, D. J. J. Eletroanal. Soc. 1992, 325, 257. doi: 10.1016/0022-0728(92)80117-M
10. [10]
  (10) Pei, M. X.; Lin, H.; Shangguan,W. F.; Huang, Z. Acta Phys. -Chim. Sin. 2005, 21, 255. [裴梅香, 林赫, 上官文峰,黄震. 物理化学学报, 2005, 21, 255.] doi: 10.3866/PKU.WHXB20050306
11. [11]
  (11) Yu, Q. Q.; Liu, T.;Wang, H.; Xiao, L. P.; Chen, M.; Jiang, X. Y.;Zheng, X. M. Chin. J. Catal. 2012, 33, 783. [于琴琴, 刘彤,王卉, 肖丽萍, 陈敏, 蒋晓原, 郑小明. 催化学报, 2012, 33,783.] doi: 10.1016/S1872-2067(11)60362-8
12. [12]
  (12) Sengupta, S. K.; Rajeshwar, S.; Ashok, K. S. J. Electroanal. Chem. 1997, 427, 23. doi: 10.1016/S0022-0728(96)05044-9
13. [13]
  (13) Hickling, A.; Ingram, M. D. Trans. Faraday Soc. 1964, 60, 783.doi: 10.1039/TF9646000783
14. [14]
  (14) Mandin, P.; Aissa, A. A.; Roustan, H.; Hamburger, J.; Picard, G.Chem. Eng. Process. 2008, 47, 1926. doi: 10.1016/j.cep.2007.10.018
15. [15]
  (15) Mandin, P.; Le Graverend, J. B.;Wuthrich, R.; Roustan, H.ECS Trans. 2009, 16, 49. doi: 10.1149/1.3104647
16. [16]
  (16) Jin, X. L.;Wang, X. Y.; Zhang, H. M.; Xia, Q.;Wei, D. B.; Yue,J. J. Plasma Chem. Plasma Process. 2010, 30, 429. doi: 10.1007/s11090-010-9220-0
17. [17]
  (17) Jin, X. L.;Wang, X. Y.; Yun, J. J.; Cai, Y. Q.; Zhang, H. Y.Electrochim. Acta 2010, 56, 925. doi: 10.1016/j.electactta.2010.09.079
18. [18]
  (18) Yan, Z. C.; Chen, L.;Wang, H. L. J. Phys. D: Appl. Phys. 2008,41, 1. doi: 10.1088/0022-3727/41/15/155205
19. [19]
  (19) Yan, Z. C.; Chen, L.;Wang, H. L. Int. J. Hydrog. Energy 2009,34, 48. doi: 10.1016/j.ijhydene.2008.09.099
20. [20]
  (20) Shen, P. K.;Wang, S. L.; Hu, Z. Y.; Li, Y. L.; Zeng, R.; Huang,Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 107. [沈培康, 汪圣龙,胡智怡, 李永亮, 曾蓉, 黄岳强. 物理化学学报, 2007, 23,107.] doi: 10.3866/PKU.WHXB20070122
21. [21]
  (21) Zeng, K.; Zhang, D. K. Prog. Energy Combust. Sci. 2010, 36,307. doi: 10.1016/j.pecs. 2009.11.002
22. [22]
  (22) Holladay, J. D.; Hu, J.; King, D. L.;Wang, Y. Catal. Today2009, 139, 244. doi: 10.1016/j.cattod.2008.08.039
23. [23]
  (23) Wüthrich, R.; Mandin, P. Electrochim. Acta 2009, 54, 4031. doi: 10.1016/j.electacta. 2009.02.029
24. [24]
  (24) Franklin, R. N. J. Phys. D: Appl. Phys. 2003, 36, 309. doi: 10.1088/0022-3727/36/22/R01
25. [25]
  (25) Yan, Z. C. Hydrogen Generation by Glow Discharge PlasmaElectrolysis of Low Alcohol. Ph. D. Dissertation, South ChinaUniversity of Technology, Guangzhou, 2007. [严宗诚. 低碳醇溶液辉光放电电解及其制氢应用[D]. 广州: 华南理工大学,2007.]
26. [26]
  (26) Luo, Y. R. Handbook of Bond Dissociation Energies in Organic Compounds; Science Press: Beijing, 2005; pp 56-195. [罗渝然. 化学键能数据手册. 北京: 科学出版社, 2005: 56-195.]
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