Citation: JIN Wei-Yang, CHENG Dang-Guo, CHEN Feng-Qiu, ZHAN Xiao-Li. Synthesis of MFI-Type Zeolite Membrane Encapsulated Activated Carbon Particles Using a Modified Seeded Method[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 139-143. doi: 10.3866/PKU.WHXB201210263 shu

Synthesis of MFI-Type Zeolite Membrane Encapsulated Activated Carbon Particles Using a Modified Seeded Method

1.
1 Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
2 Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 24 August 2012
Available Online: 26 October 2012
Fund Project: 国家自然科学基金项目(21176211) (21176211)化学工程联合国家重点实验室开放课题(SKL-ChE-09D02)资助 (SKL-ChE-09D02)

Zeolite membranes with their advantageous separation and catalytic properties can be coated on traditional catalysts to achieve highly effective perfermance. It is difficult to coat zeolite membranes onto activated carbon (AC) particles, a commonly used catalyst support, because of the hydrophobic and rough surfaces of AC. To overcome these shortcomings, a boehmite gel modified seeded method was developed to synthesize MFI-type zeolite membrane encapsulated AC particles. By using the spray-coating process, the boehmite sol precursor was introduced in a gel layer on the AC surface to provide a smooth surface for seed dispersion and a binder for seed fixation. The obtained seed layer was dense and firm even without calcination. After 6 h rotary hydrothermal synthesis, continuous zeolite membrane encapsulated AC particles were obtained. The synthetic membrane type and the composite material morphologies were elucidated by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The results indicate that MFI-type zeolite membrane has a thickness of 5 μm. For comparison, on AC particles without boehmite gel modification, no continuous membrane forms. Our boehmite gel modified seeded strategy provides an efficient way to prepare zeolite membranes on different inert supports.
- Seeded method,
- Spray-coating,
- Boehmite sol,
- Zeolite membrane,
- Activated carbon particle
1. [1]
  
  (1) McLeary, E. E.; Jansen, J. C.; Kapteijn, F. Microporous Mesoporous Mat. 2006, 90, 198. doi: 10.1016/j.micromeso.2005.10.050
2. [2]
  (2) Caro, J.; Noack, M. Microporous Mesoporous Mat. 2008, 115,215. doi: 10.1016/j.micromeso.2008.03.008
3. [3]
  (3) Jin,W. Y.; Cheng, D. G.; Chen, F. Q.; Zhan, X. L. Prog. Chem.2011, 23, 2021. [金炜阳, 程党国, 陈丰秋, 詹晓力. 化学进展2011, 23, 2021.]
4. [4]
  (4) Lin, Y. S.; Kumakiri, I.; Nair, B. N.; Alsyouri, H. Sep. Purif. Methods 2002, 31, 229. doi: 10.1081/SPM-120017009
5. [5]
  (5) Lang, L.; Liu, X. F.; Zhang, B. Q. Appl. Surf. Sci. 2009, 255,4886. doi: 10.1016/j.apsusc.2008.12.030
6. [6]
  (6) Zhong, Y. J.; Xu, X. H.; Xiao, Q.; Jiang, L.; Zhu,W. D.; Ma, C.A. Acta Phys. -Chim. Sin. 2008, 24, 1875. [钟依均, 许晓华,肖强, 姜丽, 朱伟东, 马淳安. 物理化学学报, 2008, 24,1875.] doi: 10.3866/PKU.WHXB20081023
7. [7]
  (7) Ren, N.; Yang, Y. H.; Zhang, Y. H.;Wang, Q. R.; Tang, Y.J. Catal. 2007, 246, 215. doi: 10.1016/j.jcat.2006.11.028
8. [8]
  (8) Li, X.; Asami, K.; Luo, M.; Michiki, K.; Tsubaki, N.; Fujimoto,K. Catal. Today 2003, 84, 59. doi: 10.1016/S0920-5861(03)00301-8
9. [9]
  (9) He, J. J.; Yoneyama, Y.; Xu, B. L.; Nishiyama, N.; Tsubaki, N.Langmuir 2005, 21, 1699. doi: 10.1021/la047217h
10. [10]
  (10) Li, Y.;Wang, T.;Wu, C.; Lv, Y.; Tsubaki, N. Energy & Fuels2008, 22, 1897. doi: 10.1021/ef700625z
11. [11]
  (11) Li, X. G.; He, J. J.; Meng, M.; Yoneyama, Y.; Tsubaki, N.J. Catal. 2009, 265, 26. doi: 10.1016/j.jcat.2009.04.009
12. [12]
  (12) Yang, G. H.; Tsubaki, N.; Shamoto, J.; Yoneyama, Y.; Zhang, Y.J. Am. Chem. Soc. 2010, 132, 8129. doi: 10.1021/ja101882a
13. [13]
  (13) Smith, S. P. J.; Linkov, V. M.; Sanderson, R. D.; Petrik, L. F.;Oconnor, C. T.; Keiser, K. Microporous Mesoporous Mat. 1995,4, 385. doi: 10.1016/0927-6513(95)00023-3
14. [14]
  (14) van der Vaart, R.; Bosch, H.; Keizer, K.; Reith, T. Microporous Mesoporous Mat. 1997, 9, 203. doi: 10.1016/S0927-6513(96)00109-5
15. [15]
  (15) García-Martínez, J.; Cazorla-Amorós, D.; Linares-Solano, A.;Lin, Y. S. Microporous Mesoporous Mat. 2001, 42, 255. doi: 10.1016/S1387-1811(00)00328-0
16. [16]
  (16) Li, X. G.; Zhang, Y.; Meng, M.; Yang, G. H.; San, X. G.;Takahashi, M.; Tsubaki, N. J. Membr. Sci. 2010, 347, 220. doi: 10.1016/j.memsci.2009.10.027
17. [17]
  (17) Yuan,W. H.; Chang, R. R.; Liu, X. C.; Li, L. Acta Phys. -Chim. Sin. 2011, 27, 2493. [袁文辉, 常然然, 刘晓晨, 李莉. 物理化学学报, 2011, 27, 2493.] doi: 10.3866/PKU.WHXB20110917
18. [18]
  (18) Ren, N.; Yang, Y. H.; Shen, J.; Zhang, Y. H.; Xu, H. L.; Gao, Z.;Tang, Y. J. Catal. 2007, 251, 182. doi: 10.1016/j.jcat.2007.07.009
19. [19]
  (19) Zhang, X. F.;Wang, T. H.; Liu, H.; Yeung, K. L. J. Mater. Sci.2004, 39, 5603. doi: 10.1023/B:JMSC.0000039299.76924.82
20. [20]
  (20) Berenguer-Murcia, Á.; Morallón, E.; Cazorla-Amorós, D.;Linares-Solano, Á. Microporous Mesoporous Mat. 2005, 78,159. doi: 10.1016/j.micromeso.2004.10.005
21. [21]
  (21) Meng, L.; Jiang, H.; Chen, R. Z.; Gu, X. H.; Jin,W. Q. Appl. Surf. Sci. 2011, 257, 1928. doi: 10.1016/j.apsusc.2010.09.028
22. [22]
  (22) Buelna, G.; Lin, Y. S. Microporous Mesoporous Mat. 1999, 30,359. doi: 10.1016/S1387-1811(99)00065-7
23. [23]
  (23) Dandekar, A.; Baker, R. T. K.; Vannice, M. A. Carbon 1998, 36,1821. doi: 10.1016/S0008-6223(98)00154-7
24. [24]
  (24) Zárate, J.; Rosas, G.; Pérez, R. Advances in Technology of Materials and Materials Processing Journal (ATM) 2005, 7,181.
25. [25]
  (25) Lin, Y. S.; Burggraaf, A. J. J. Am. Ceram. Soc. 1991, 74, 219.doi: 10.1111/j.1151-2916.1991.tb07320.x
1. [1]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
2. [2]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
3. [3]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
4. [4]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
5. [5]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
6. [6]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
7. [7]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-0. doi: 10.3866/PKU.WHXB202406009
8. [8]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
9. [9]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
10. [10]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
11. [11]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
12. [12]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . High-Precision and Reliable Thermal Conductivity Measurement for Graphene Films Based on an Improved Steady-State Electric Heating Method. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-0. doi: 10.1016/j.actphy.2025.100045
13. [13]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
14. [14]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
15. [15]
  Zhou Fang , Zhihao Zhang , Weihan Jiang , Kin Shing Chan . Warfarin: From Poison to Cure, the Remarkable Journey of a Molecule. University Chemistry, 2025, 40(4): 326-330. doi: 10.12461/PKU.DXHX202406038
16. [16]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
17. [17]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
18. [18]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
19. [19]
  Yuting DU , Jing YUAN , Peiyao DENG . Synthesis and application of a fluorescent probe for the detection of reduced glutathione. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1331-1337. doi: 10.11862/CJIC.20240461
20. [20]
  Xiao Liu , Guangzhong Cao , Mingli Gao , Hong Wu , Hongyan Feng , Chenxiao Jiang , Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043

Get Citation

PDF

XML

Metrics

PDF Downloads(656)
Abstract views(1631)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142