Citation: LI Song-Mei, WANG Bo, LIU Jian-Hua, YU Mei, AN Jun-Wei. Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208292 shu

Synthesis and Microwave Absorption Properties of Nickel Nanoparticles-Graphene Composites with Different Morphologies

1.
Key Laboratory of Aerospace Materials and Performance,Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, P. R. China

Received Date: 2 July 2012
Available Online: 29 August 2012
Fund Project: 航空科学基金(20110251003)资助项目 (20110251003)

Nickel nanoparticles-graphene (Ni-GNs) composites with two different morphologies were successfully synthesized by in situ chemical reduction, and the morphology-dependent electromagnetic absorption properties of the composites was investigated. By changing the sequence of the reactants are added during preparation, spherical and spinous spherical nickel nanoparticle-graphene composites were obtained. The structure, morphology, and microwave absorption properties of the composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vector network analysis (VNA). The results indicated that the spinous spherical nickel nanoparticle-graphene composites had better microwave absorption ability than the spherical nickel nanoparticle-graphene composites. This is due to the unique isotropic antenna morphology of the spinous spherical nickel nanoparticles in the composites, arising from the point discharge effect. This facile in situ chemical reduction method for the preparation of nickel nanoparticle-graphene composites to give different morphologies could be used for the preparation of other composites.
- Graphene,
- Nickel,
- Nanocomposite,
- Microwave absorption,
- In-situ chemical reduction method
1. [1]
  
  (1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306 (5696), 666. doi: 10.1126/science.1102896
2. [2]
  (2) Chae, H. K.; Siberio-Perez, D. Y.; Kim, J.; , Y.; Eddaoudi,M.; Matzger, A. J.; Okeeffe, M.; Yaghi, O. M. Nature 2004, 427(6974), 523. doi: 10.1038/nature02311
3. [3]
  (3) Sclladler, L. S.; Giammris, S. C.; Ajayan, P. M. Appl. Phys. Lett.1998, 73 (26), 3842.
4. [4]
  (4) Zhang, Y. B.; Tan, J.W.; Stormer, H. L.; Kim, P. Nature 2005,438 (7065), 201. doi: 10.1038/nature04235
5. [5]
  (5) Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.;Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008, 146 (9/10), 351.
6. [6]
  (6) Balandin, A. A.; Ghosh, S.; Bao,W. Z.; Calizo, I.;Teweldebrhan, D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3),902. doi: 10.1021/nl0731872
7. [7]
  (7) Reina, A.; Thiele, S.; Jia, X. T.; Bhaviripudi, S.; Dresselhaus, M.S.; Schaefer, J. A.; Kong, J. Nano Res. 2009, 2 (6), 509. doi: 10.1007/s12274-009-9059-y
8. [8]
  (8) Berger, C.; Song, Z.; Li, X.;Wu, X. S.; Brown, N.; Naud, C.;Mayou, D.; Li, T.; Hass, J.; Marchhenkow, A. N.; Conrad, E. H.;First, P. N.; Heer,W. A. Science 2006, 312 (5777), 1191. doi: 10.1126/science.1125925
9. [9]
  (9) Pei, S. F.; Zhao, J. P.; Du, J. H.; Ren,W.C.; Cheng, H. M.Carbon 2010, 48 (15), 4466. doi: 10.1016/j.carbon.2010.08.006
10. [10]
  (10) Stankovich, S.; Piner, R. D.; Chen, X. Q.;Wu, N. Q.; Nguyen,S. T.; Ruoff, R. S. J. Mater. Chem. 2006, 16 (2), 155. doi: 10.1039/b512799h
11. [11]
  (11) Stankovich, S.; Dikin, D. A.; Dommett, G. H.; Kohlhaas, K. M.;Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff,R. S. Nature 2006, 442 (7100), 282. doi: 10.1038/nature04969
12. [12]
  (12) Niu, H. L.; Chen, Q.W.; Ning, M.; Jia, Y. S.;Wang, X, J.J. Phys. Chem. B 2004, 108 (13), 3996. doi: 10.1021/jp0361172
13. [13]
  (13) An, Z. G.; Pan, S. L.; Zhang, J. J. J. Phys. Chem. C 2009, 113 (4), 1346. doi: 10.1021/jp809224j
14. [14]
  (14) Zhao, H. T.; Han, X. J.; Zhang, L. F.;Wang, G. Y.;Wang, C.; Li,X. A.; Xu, P. Radiat. Phys. Chem. 2011, 80 (3), 390. doi: 10.1016/j.radphyschem.2010.11.007
15. [15]
  (15) Ma, F.; Ma, J.; Huang, J. J.; Li, J. G. J. Magn. Magn. Mater.2012, 324 (2), 205. doi: 10.1016/j.jmmm.2011.08.013
16. [16]
  (16) Wang, C.; Han, X. J.; Xu, P.;Wang, J. Y.; Du, Y. C.;Wang, X.H.; Qin,W.; Zhang, T. J. Phys. Chem. C 2010, 114 (7), 3196.doi: 10.1021/jp908839r
17. [17]
  (17) Deng, Y. D.; Zhao, L.; Shen, B.; Liu, L.; Hu,W. B. J. Appl. Phys. 2006, 100 (1), 014304. doi: 10.1063/1.2210187
18. [18]
  (18) Zhao, J. P.; Pei, S. F.; Ren,W. C.; Gao, L. B.; Cheng, H. M. ACS Nano 2010, 4 (9), 5245. doi: 10.1021/nn1015506
19. [19]
  (19) Xu, C.;Wang, X. Small 2009, 5 (19), 2212. doi: 10.1002/smll.v5:19
20. [20]
  (20) Yu, M.; Liu, P. R.; Sun, Y. J.; Liu, J. H.; An, J.W.; Li, S. M.J. Inorg. Mater. 2012, 27 (1), 89. [于美, 刘鹏瑞, 孙玉静, 刘建华, 安军伟, 李松梅. 无机材料学报, 2012, 27 (1), 89.]
21. [21]
  (21) Xu, P.; Han, X. J.;Wang, C.; Zhao, H. T.;Wang, J. Y.;Wang, X.H.; Zhang, B. J. Phys. Chem. B 2008, 112 (10), 2775. doi: 10.1021/jp710259v
22. [22]
  (22) Sue, K.; Suzuki, A.; Suzuki, M.; Arai, K.; Hakuta, Y.; Hayashi,H.; Hiaki, T. Ind. Eng. Chem. Res. 2006, 45 (2), 623. doi: 10.1021/ie0506062
23. [23]
  (23) Sarkar, S.; Sinha, A. K.; Pradhan, M.; Basu, M.; Negish, Y.; Pal,T. J. Phys. Chem. C 2011, 115 (5), 1659. doi: 10.1021/jp109572c
24. [24]
  (24) Li, S. M.; Chen, D. M.; Liu, J. H. Acta Phys. -Chim. Sin. 2004,20 (11), 1389. [李松梅, 陈冬梅, 刘建华. 物理化学学报,2004, 20 (11), 1389. ] doi: 10.3866/PKU.WHXB20041121
25. [25]
  (25) Ferreira, M. G. S.; Duarte, R. G.; Montemor, M. F.; Simoes, A.M. P. Electrochim. Acta 2004, 49 (17-18), 2927. doi: 10.1016/j.electacta.2004.01.051
26. [26]
  (26) Sigh, P.; Babbar, V. K.; Razdan, A.; Puri, R. K.; el, T. C.J. Appl. Phys. 2000, 87 (9), 4362.
27. [27]
  (27) Zhuo, R. F.; Qiao, L.; Feng, H. T.; Chen, J. T.; Yan, D.;Wu, Z.G.; Yan, P. X. J. Appl. Phys. 2008, 104 (9), 094101. doi: 10.1063/1.2973198
28. [28]
  (28) Zhou, Z.W.; Chu, L. S.; Hu, S. C. Mater. Sci. Eng. B 2006, 126 (1), 93. doi: 10.1016/j.mseb.2005.09.009
1. [1]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240065
2. [2]
  Yanan Liu , Xiaogang Su , Di Lan , Jiangyong Liu , Weihai Ma , Yaqing Liu . Bimetallic MOF-derived CoZn-C/MWCNTs composite for lightweight and wideband microwave absorption. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100276
3. [3]
  Baoshun Zhu , Xinyan Wang , Weipeng Mu , Xuanpeng Sun , Yubo Wang , Hongyu Wei , Pangyu Shi , Huilan Hao , Dashuang Wang , Guomin Li , Guizhen Wang . 回收造纸污泥制备低成本Ni改性碳/硅复合材料用于高效微波吸收. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100417
4. [4]
  Jun Wang , Xinxing Li , Yibo Wang , Yafei Mu , Xiaoming Guo , Di Lan , Dashuang Wang , Haifeng Li . 氟碳门控-多级异质界面协同驱动复合泡沫全X波段微波吸收. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100405
5. [5]
  Xiaochuang Di , Mushan Yuan , Junyu Lu , Shenquan Yang , Cuiqing Zhou , Yang Chen , Huawei Zou . Navigating the continuous parameter space for ultra-broadband microwave absorption: a sequence-aware deep learning and evolutionary optimization approach. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100270
6. [6]
  Bo Liang , Yuyijian Zhao , Siyu Wang , Shihan Huang , Fangke Zhou , Chuankun Zhang , Yue Wang , Xiaoming Guo . Synergistic molecular assembly and impedance matching in polyimide-derived porous carbon nanosheets for advanced microwave absorption. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100285
7. [7]
  Liangsen Zhu , Caiyun Cui , Tao Jing , Shihao Tan , Xianguo Liu , Menglin Yu . Strong and broadband microwave absorption under thin thickness induced by multiple dielectric relaxation and multiple magnetic resonances through the dual nanocrystalline phases in amorphous FeSiBCr flakes. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100331
8. [8]
  Gengsu Zhu , Yuanyuan Ma , Chengzhi Sun , Mengting Li , Chunyu Wang , Bo Zhong , Long Xia . Preparation and absorption properties of petal-clustered WS₂/MnFe₂/O₄/GNs composite materials. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100273
9. [9]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202306011
10. [10]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230447
11. [11]
  Liang WANG , Hongxu WU , Yunsong RAO , Dun HAN , Xuan SONG , Jianlong LIN , Dongfang LI , Sheng ZHANG . Research progress in graphene-based materials for hydrogen production via water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20260057
12. [12]
  Yuanchun Pan , Xinyun Lin , Leyi Yang , Wenya Hu , Dekui Song , Nan Liu . Artificial Intelligence Science Practice: Preparation of Electronic Skin by Chemical Vapor Deposition of Graphene. University Chemistry, doi: 10.12461/PKU.DXHX202412052
13. [13]
  Meng Aoyun , Li Zhenhua , Xiong Guoyuan , Li Zhen , Zhang Jinfeng . S-scheme heterojunction Al₆Si₂O₁₃/BiOBr with enhanced charge transfer effect for efficient and stable photocatalytic degradation of triazophos and dichlorvos pesticides. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2025.100186
14. [14]
  Renwei Feng , Congmin Fan , Di Lan , Lanxiang Liu , Qinchuan He , Yiqun Wang . Anchoring strategy-induced conductive loss in Ni-MOF@expanded graphite composites to achieve broadband microwave absorption. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100301
15. [15]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202304027
16. [16]
  Zhimin Sun , Wenyu Xue , Shuangshuang Yang , Chaoyang Zhang , Bo Yu , Xingwei Wang , Qiangliang Yu , Feng Zhou , Weimin Liu . 面向海洋应用的多功能涂层：基于氟硅烷包覆CIP实现防腐、吸波与减阻一体化. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2026.100292
17. [17]
  Shixin SHI , Zhuohang LIU , Yuan SUN , Jingshen LI , Weixiang CHEN . Synthesis and electrochemical lithium storage performance of high-entropy NiCoSnZnFeS_x and reduced graphene oxide composite. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250372
18. [18]
  Hailang JIA , Yujie LU , Pengcheng JI . Preparation and properties of nitrogen and phosphorus co-doped graphene carbon aerogel supported ruthenium electrocatalyst for hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250021
19. [19]
  Zifeng LIN , Shanshan GONG , Yang SHA , Zhenmin ZHANG , Changlin YU . Graphene quantum dots/SnS₂ composite nanosheets: Preparation and photocatalytic performance in reducing Cr(Ⅵ). Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250320
20. [20]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230253

Get Citation

PDF

XML

Metrics

PDF Downloads(1405)
Abstract views(3999)
HTML views(174)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142