Citation: XIE Ting, LIU Hao-Wen, YANG Han-Min. Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201207031 shu

Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene

1.
College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan 430074, P. R. China

Received Date: 15 May 2012
Available Online: 3 July 2012
Fund Project: 中央高校基本科研业务费用专项基金(ZZY10004)资助 (ZZY10004)

Branched palladium nanostructures were synthesized under microwave irradiation using polyvinylpyrrolidone (PVP) as stabilizer and benzyl glycol as the reducing agent of H₂PdCl₄. Morphology and structure were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), and showed that the branched Pd nanostructures were self-assemblies of hundreds of small spherical nanoparticles. Furthermore, catalytic properties of the branched Pd nanostructures were investigated for the hydrogenation of nitrobenzene, which indicated that the catalytic activity of the branched Pd nanostructures for this reaction is higher than that of a conventional Pd/C catalyst.
- Palladium,
- Nanostructure,
- Microwave irradiation,
- Hydrogenation of nitrobenzene,
- Growth process
1. [1]
  
  (1) Boal, A. K.; Ilhan, F.; DeRouchey, J. E.; Thurn-Albrecht, T.;Russell, T. P.; Rotello, V. M. Nature 2000, 404 (3), 746.
2. [2]
  (2) Huang, L. Z.;Wang, Y.;Wang, Y. L. Noble Metal 1997, 18 (3),58. [黄黎中, 王瑛, 王永力. 贵金属, 1997, 18 (3), 58.]
3. [3]
  (3) Nishihata, Y.; Mizuki, J.; Akao, T.; Tanaka, H.; Uenishi, M.;Kimura, M.; Okamoto, T.; Hamada, N. Nature 2002, 418, 164.doi: 10.1038/nature00893
4. [4]
  (4) Huang, L.;Wong, P. K.; Tan, J. J. Phys. Chem. C 2009, 113,10120. doi: 10.1021/jp811188f
5. [5]
  (5) Pacardo, D. B.; Sethi, M.; Jones, S. E.; Naik, R. R.; Knecht, M.R. ACS Nano 2009, 3 (5), 1288. doi: 10.1021/nn9002709
6. [6]
  (6) Xiong, Y. J.; Xia, Y. N. Advanced Materials 2007, 19, 3385. doi: 10.1002/adma.200701301
7. [7]
  (7) Xiong, Y. J.; Chen, J. Y.; Benjamin,W.; Xia, Y. N.; Yin, Y. D.;Li, Z. Y. Nano Letters 2005, 5 (7), 1237. doi: 10.1021/nl0508826
8. [8]
  (8) Xiong, Y. J.; Joseph, M. M.; Yin, Y. D.; Xia, Y. N. Angew. Chem. Int. Edit. 2007, 46, 790. doi: 10.1002/anie.200604032
9. [9]
  (9) Xiong, Y. J.; Cai, H. G.; Yin, Y. D.; Xia, Y. N. Chemical Physics Letters 2007, 440, 273. doi: 10.1016/j.cplett.2007.04.074
10. [10]
  (10) Huang, X. Q.; Tang, S. H.; Mu, X. L.; Dai, Y.; Chen, G. X.;Zhou, Z. Y.; Ruan, F. X.; Yang, Z. L.; Zheng, N. F. Nat. Nanotechnol. 2011, 6, 28.
11. [11]
  (11) Huang, X. Q.; Tang, S. H.; Zhang, H. H.; Zhou, Z. Y.; Zheng, N.F. J. Am. Chem. Soc. 2009, 131, 13916. doi: 10.1021/ja9059409
12. [12]
  (12) Huang, X. Q.; Tang, S. H.; Yang, J.; Tan, Y. M.; Zheng, N. F.J. Am. Chem. Soc. 2011, 133, 15946. doi: 10.1021/ja207788h
13. [13]
  (13) Lin, X. F.; Chen, Z. C.; Lü, D. S.; He, L.; Zhang, D. T. Polymer Science and Engineering 2000, 16 (4), 5. [林贤福, 陈志春,吕德水, 何琳, 张大同. 高分子材料科学与工程, 2000, 16 (4), 5.]
14. [14]
  (14) Sun, Z. C.; Bai, F.;Wu, H. M.; Samantha, K. S.; Daniel, M. B.;Jiang, Z.;Wang, J.; Fan, H. Y. Chem. Eur. J. 2009, 15, 11128.doi: 10.1002/chem.200901786
15. [15]
  (15) Naka, K.; Sato, M.; Chujo, Y. Langmuir 2008, 24 (6), 2719. doi: 10.1021/la7027109
16. [16]
  (16) Zheng, L. Z.; Li, J. H. J. Phys. Chem. B 2005, 109 (3), 1108.doi: 10.1021/jp0456234
17. [17]
  (17) Kochkar, H.; Aouine, M.; Ghorbel, A.; Berhault, G. J. Phys. Chem. C 2011, 115, 11364.
18. [18]
  (18) Tong, X.; Zhao, Y. X.; Huang, T.; Liu, H. F.; Liew, K. Y. Applied Surface Science 2009, 255, 9463. doi: 10.1016/j.apsusc.2009.07.059
19. [19]
  (19) Cheng, C. D.; Ravi, K. G.; Gu, Q.; Haynie, D. T. Nano Letters2005, 5 (1), 175. doi: 10.1021/nl048240q
20. [20]
  (20) Chen, Y.; He, B.; Liu, H. J. Mater. Sci. Technol. 2005, 21 (2),187.
21. [21]
  (21) Handbook of X-ray Photoelectron Spectroscopy;Wagner, C. D.,Riggs,W. M., Davis, L. E., Moulder, F., Muilenberg, G. E. Eds.;Perkin-Elmer: Phys. Electr. Division, Eden Prairie, 1979.
1. [1]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309043
2. [2]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240065
3. [3]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, doi: 10.3866/PKU.DXHX202311024
4. [4]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202402016
5. [5]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240047
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202311030
7. [7]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202310029
8. [8]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2025.100054
9. [9]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, doi: 10.12461/PKU.DXHX202408125
10. [10]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, doi: 10.3866/PKU.DXHX202308060
11. [11]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240075
12. [12]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, doi: 10.3866/PKU.DXHX202307051
13. [13]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, doi: 10.3866/PKU.DXHX202401076
14. [14]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, doi: 10.12461/PKU.DXHX202407017
15. [15]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240088
16. [16]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, doi: 10.1016/j.actphy.2025.100071
17. [17]
  Cuiping Yang , Huiping Ding , Jinpeng Hou , Kai Li , Weiliang Tian . Reform and Exploration of “Comprehensive and Precise Process” Assessment in Chemical Engineering Principle Experimental Course. University Chemistry, doi: 10.3866/PKU.DXHX202309087
18. [18]
  Jianmin Hao , Ruifeng Wu , Ying Wang , Yijia Bai , Xuechuan Gao , Yuying Du . Reform and Practice of Physical Chemistry Course Based on Enhanced Process Assessment and Evaluation. University Chemistry, doi: 10.3866/PKU.DXHX202311103
19. [19]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, doi: 10.3866/PKU.DXHX202311102
20. [20]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, doi: 10.3866/PKU.DXHX202306084

Get Citation

PDF

XML

Metrics

PDF Downloads(771)
Abstract views(1882)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142