Citation: XIONG Li-Long, XU You-Long, ZHANG Cheng, TAO Tao. Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1177-1182. doi: 10.3866/PKU.WHXB201203092 shu

Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries

1.
International Center for Dielectric Research, Electronic Material Research Laboratory of Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P. R. China

Received Date: 26 December 2011
Available Online: 9 March 2012

A doping-coating surface modification method was used to improve the cycle performance of the lithium-ion battery cathode material spinel LiMn₂O₄. Al was chosen as the doping element and Al(NO₃)₃ as the raw material. We investigated Al³⁺ doping of 7.1%(atomic fraction) at the temperatures of 300, 400, 500, 600, 700, 750, and 800 °C. It was found that at increasing temperatures, the maximum specific capacity of the modified samples first increased and then decreased, with a maximum at 700 °C. The fading rate increased initially with temperature as well, and then decreased, followed by a small rise with temperature. This is because the coated layer gradually reacted with the LiMn₂O₄ granule at elevated temperatures and became a completely solid solution layer by 750 °C. The fading rate reached the minimum at the same time. Subsequently, the solid solution layer diffused into the LiMn₂O₄ granule, weakening the granule protection so that the fading rate slightly increased. Among these samples, the maximum specific capacity (133.6 mAh·g^-1) was for the sample treated at 700 °C for 5 h, and the fading rate was 3.4% after 50 cycles. It is shown that doping-coating surface modification with Al³⁺ may enable the commercial application of spinel LiMn₂O₄ cathode material for lithium-ion batteries.
- Lithium-ion battery,
- Cathode material,
- Spinel LiMn₂O₄,
- Doping-coating surface modification,
- Solid solution
1. [1]
  (1) Thackeray, M. M.; David, W. I. F.; Bruce, P. G.; odenough, J.B. Mat. Res. Bull.1983, 18, 461.
2. [2]
  (2) Kim, J.; Manthiram, A. Nature 1997, 390, 265.
3. [3]
  (3) Tarascon, J.M.; Armand, M. Nature 2001, 414, 359.
4. [4]
  (4) Tanaka, T.; Ohta, K.; Arai, N. J. Power Sources 2001, 2, 97.
5. [5]
  (5) Xia, Y.; Yoshio, M. J. Electrochem. Soc. 1996, 143, 825.
6. [6]
  (6) An, H. L.; Wu, N. N.; Lei, X. L.; Xu, J. L.; Qi, L. Acta Phys. -Chim. Sin. 2007, 23, 60. [安洪力, 吴宁宁, 雷向利, 徐金龙, 其鲁, 物理化学学报, 2007, 23, 60.]
7. [7]
  (7) Wang, J.; Li, T., Qi, L. Acta Phys. -Chim. Sin. 2007, 23, 75. [王剑, 李桐进, 其鲁, 物理化学学报, 2007, 23, 75.]
8. [8]
  (8) Katakura, K.; Wada, K.; Kajiki, Y.; Yamamoto, A.; Ogumi, Z. J. Power Sources 2009, 189, 240.
9. [9]
  (9) Jiang, C. H.; Dou, S. X.; Liu, H. K.; M. Ichihara, Zhou, H. S. J. Power Sources 2007, 172, 410.
10. [10]
  (10) Xia, Y.; Zhou, Y.; Yoshio, M. J. Electrochem. Soc. 1997, 144, 2593.
11. [11]
  (11) Jang, D. H.; Oh, S. M. J. Electrochem. Soc. 1997, 144, 3342.
12. [12]
  (12) Moon, H. S.; Park, J. W. J. Power Sources 2003, 119-121, 717.
13. [13]
  (13) Shi, S.; Ouyang, C.; Wang, D. S.; Chen, L.; Huang, X. Solid State Commun. 2003, 126, 531.
14. [14]
  (14) Tang, Z. Y.; Fan, X. H.; Zhang, N. Acta Phys. -Chim. Sin. 2005, 21, 934. [唐致远, 范星河, 张娜, 物理化学学报, 2005, 21, 934.]
15. [15]
  (15) Tang, Z. Y.; Feng, J. J. Acta Phys. -Chim. Sin. 2003, 19, 1025. [唐致远, 冯季军, 物理化学学报, 2003, 19, 1025.]
16. [16]
  (16) Xiong, L. L.; Xu, Y. L.; Zhang, C.; Zhang, Z. W.; Li, J. B. J. Solid State Electrochem. 2011, 15, 1263.
17. [17]
  (17) Xiong, L. L.; Xu, Y. L.; Tao, T.; odenough J.B. J. Power Sources 2012, 199, 214.
18. [18]
  (18) Raja, M. W.; Mahanty, S.; Basu, R. N. J. Power Sources 2009, 192, 618.
19. [19]
  (19) Yuan, A.; Tian, L.; Xu, W.; Wang, Y. J. Power Sources 2010, 195, 5032.
20. [20]
  (20) Matsumoto, K.; Fukutsuka, T.; Okumura. T.; Uchimoto, Y.; Amezawa, K.; Inaba, M.; Tasaka, A. J. Power Sources 2009, 189, 599.
21. [21]
  (21) Ouyang, C. Y.; Zeng, X. M.; Sljivancanin, Z. J. Phys. Chem. C 2010, 114, 4756.
22. [22]
  (22) Gnanaraj, J. S.; Pol, V. G.; Gedanken, A.; Aurbach, D. Electrochem. Commun. 2003, 5, 940.
23. [23]
  (23) Walz, K. A.; Johnson, C. S.; Genthe, J.; Stoiber, L. C.; Zeltner, W. A.; Anderson, M. A.; Thackeray, M. M. J. Power Sources 2010, 195, 4943.
24. [24]
  (24) Li, X. F.; Xu, Y. L. Appl. Surf. Sci. 2007, 253, 8592.
25. [25]
  (25) Li, X. F.; Xu, Y. L. Electrochem. Commun. 2007, 9, 2023.
26. [26]
  (26) Xu, Y. L.; Li, X. F.; Ge, L. P. Appl. Surf. Sci. 2007, 253, 8453.
27. [27]
  (27) Xiong, L. L.; Xu, Y. L.; Tao, T.; Du, X. F.; Li, J. B. J. Mater. Chem. 2011, 13, 4937.
28. [28]
  (28) Yi, T. F.; Hu, X. G.; Gao, K. J. Power Sources 2006, 162, 636.
29. [29]
  (29) Thirunakaran, R.; Sivashanmugam, A.; pukumar, S.; Dunnill, C. W.; Gre ry, D. H. J. Phys. Chem. Solids 2008, 69, 2082.
30. [30]
  (30) Xiao, L.; Zhao, Y.; Yang, Y.; Cao, Y. Electrochim. Acta 2008, 54, 545.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
3. [3]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
4. [4]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
5. [5]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
6. [6]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
7. [7]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . 原位电化学阻抗谱监测长寿命热电池Nb₁₂WO₃₃正极材料的高温双放电机制. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-. doi: 10.1016/j.actphy.2024.100040
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
10. [10]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
11. [11]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
14. [14]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
15. [15]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
16. [16]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
17. [17]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
20. [20]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358

Get Citation

PDF

XML

Metrics

PDF Downloads(805)
Abstract views(2681)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Doping-Coating Surface Modification of Spinel LiMn2O4 Cathode Material with Al3+ for Lithium-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Doping-Coating Surface Modification of Spinel LiMn₂O₄ Cathode Material with Al³⁺ for Lithium-Ion Batteries