Citation: LI Lan, HU Geng-Shen, LU Ji-Qing, LUO Meng-Fei. Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1012-1020. doi: 10.3866/PKU.WHXB201203052 shu

Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 18 November 2011
Available Online: 5 March 2012
Fund Project: 国家自然科学基金(20703039, 21173195)资助项目 (20703039, 21173195)

This review summarizes the current status of the evolution and observation of oxygen vacancies in CeO₂-doped solid solutions as characterized by Raman spectroscopy. Three Raman peaks at 465, 560, and 600 cm^-1 are ascribed to the F_2g symmetrical stretching vibration mode of CeO₂ in a fluorite structure, oxygen vacancies, and a MO₈-type complex, respectively. The presence of oxygen vacancies was related to the ionic valence states of the dopant, while the MO₈-type complex was associated with the ionic radii of the dopant. The oxygen vacancy concentration correlated with the sample absorbance and the surface enrichment of oxygen vacancies. The in situ Raman spectroscopic investigations show that the atmospheric composition and temperature had a large influence on the absorbance of the samples, which in turn alters the detection depth of the Raman laser and the observed oxygen vacancy concentration.
- Raman spectroscopy,
- Oxygen vacancy,
- CeO₂-based solid solution,
- Absorbance
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沈阳化工大学材料科学与工程学院沈阳 110142

Review of Oxygen Vacancies in CeO2-doped Solid Solutions as Characterized by Raman Spectroscopy

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通讯作者: 陈斌, bchen63@163.com

Review of Oxygen Vacancies in CeO₂-doped Solid Solutions as Characterized by Raman Spectroscopy