Citation: TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian. Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1269-1274. doi: 10.3866/PKU.WHXB201202242 shu

Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon

1.
Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 28 November 2011
Available Online: 24 February 2012
Fund Project: 国家自然科学基金(21073038, 21173048)资助项目 (21073038, 21173048)

Because of the chemical reaction between Cr(VI) ions and glutathione, the peak reduction current of Cr(VI) ions decreases while adding glutathione (GSH) into a K₂Cr₂O₇/H₂SO₄ solution. Thus the concentration of GSH can be detected indirectly by differential pulse voltammetry (DPV) analysis. This electrochemical indirect method was used to study the adsorption of GSH on multi-walled carbon nanotubes (MWCNTs) and activated carbon (AC), and can be used to determine the equilibrium relationship between GSH adsorption and its concentration. Unlike the result obtained from the active carbon, GSH adsorption on MWCNTs agrees better with that predicted by the Freundlich equation compared to that predicted by the Langmuir equation. The morphologies of MWCNTs and activated carbon were observed with scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The abundance of aggregated pores in MWCNTs is beneficial for the diffusion and adsorption of small GSH molecules, suggesting that MWCNTs could be developed as an adsorbent for small molecular substances.
- Electrochemical indirect measurement,
- Glutathione,
- MWCNTs,
- Activated carbon,
- Adsorption mechanism
1. [1]
  (1) Iijima, S. Nature 1991, 354, 56.
2. [2]
  (2) Chen, C. L.;Wang, X. K. Ind. Eng. Chem. Res. 2006, 45, 9144.
3. [3]
  (3) El-Sheikh, A. H.; Sweileh, J. A.; Al-Degs, Y. S. Anal. Chim. Acta 2007, 604, 119.
4. [4]
  (4) Hong, Y. N.; Cai, Y. Q.; Shi, Y. L.;Wei, F. S.; Liu, J. M.; Mou, S. F.; Jiang, G. B. Anal. Chim. Acta 2007, 594, 81.
5. [5]
  (5) Li, G. F.;Wan, J. X.; Hang, X. Q.; Zeng, Q.; Tang, J. Chin. J. Biomed. Eng. 2011, 28, 758. [李桂芬, 万建新, 黄向前, 曾峤, 汤儆. 生物医学工程学杂志, 2011, 28, 758.]
6. [6]
  (6) Ye, C.; ng, Q. M.; Lu, F. P.; Liang, J. Acta Phys. -Chim. Sin. 2007, 23, 1321. [叶超, 巩前明, 卢方平, 梁吉. 物理化学学报, 2007, 23, 1321.]
7. [7]
  (7) Jia, Z.;Wang, Z.; Liang, J.;Wei, B.;Wu, D. Carbon 1999, 37, 903.
8. [8]
  (8) Xiong, Z. H.;Wang, L.; Zhou, J. G.; Liu, J. M. Acta Phys. -Chim. Sin. 2010, 26, 2890. [熊振湖, 王璐, 周建国, 刘建明. 物理化学学报, 2010, 26, 2890.]
9. [9]
  (9) Han, B.; Chen,W.;Wang. X.C.; Li, L.; Yan, H.; Li,W. X. New Carbon Mater. 2010, 25, 75. [韩博, 陈文, 王新春, 李乐, 严欢, 李文新. 新型炭材料, 2010, 25, 75.]
10. [10]
  (10) Voet, D.; Voet, J. G. Biochemistry;Wiley: New York, 1990; pp 380-385.
11. [11]
  (11) Chen, P.; Zhang, H. B.; Lin, G. D.; Cai, Q. R. Chem. J. Chin. Univ. 1998, 19, 765. [陈萍, 张鸿斌, 林国栋, 蔡启瑞. 高等学校化学学报1998, 19, 765.]
12. [12]
  (12) Kitagawa, S.; Seki, H.; Kametani, F.; Sakurai, H. Inorg. Chim. Acta 1988, 152, 251.
13. [13]
  (13) Han, X.W.; Qu, M.; Hu, J. H.; Xu, Y. T.; Yang, K. H. Chemistry 1994, 50. [韩秀文, 屈铭, 胡皆汉, 许永庭, 杨开海. 化学通报, 1994, 50.]
14. [14]
  (14) Mah, V.; Jalilehvand, F. Chem. Res. Toxicol. 2010, 23, 1815.
15. [15]
  (15) Podanyi, B.; Rrid, R. S. J. Am. Chem. Soc. 1988, 110, 3805.
16. [16]
  (16) Yang, P. H.; Zhang,W. H.; Zhao, Q. X.; Cai, J. Y. Chin. J. Inorg. Chem. 2005, 21, 495. [杨培慧, 张文豪, 赵秋香, 蔡继业. 无机化学学报, 2005, 21, 495.]
17. [17]
  (17) George, L. E. Arch. Biochem. Biophys. 1959, 82, 70.
18. [18]
  (18) Ba, N. T.; Roll, F. J. Anal. Biochem. 1989, 179, 236.
19. [19]
  (19) Yang, Q. H.; Hou, P. X.; Bai, S.;Wang, M. Z.; Cheng, H. M. Chem. Phys. Lett. 2001, 345, 18.
20. [20]
  (20) Ye, C.; ng, Q. M.; Lu, F. P.; Liang, J. Sep. Purif. Technol. 2007, 58, 2.
21. [21]
  (21) Lu, C.; Chung, Y. L.; Chang, K. F. Water Res. 2005, 39, 1184.
22. [22]
  (22) Negi, A. S.; Anand, S. C. A Textbook of Physical Chemistry; Wiley Eastern: New York, 1985; pp 724-728.
1. [1]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
2. [2]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
3. [3]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
4. [4]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
5. [5]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
6. [6]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
7. [7]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
8. [8]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
9. [9]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . Modulating the d-band center of NNU-55(Fe) for enhanced CO₂ adsorption and photocatalytic activity. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-. doi: 10.1016/j.actphy.2025.100074
10. [10]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
11. [11]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
12. [12]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
13. [13]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
14. [14]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
15. [15]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
16. [16]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
17. [17]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
18. [18]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
19. [19]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
20. [20]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154

Get Citation

PDF

XML

Metrics

PDF Downloads(660)
Abstract views(2246)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142