Citation: ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan. Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 923-927. doi: 10.3866/PKU.WHXB201202081 shu

Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 21 October 2011
Available Online: 8 February 2012

Platinum nanoparticles (d=2.0 nm) were obtained by decomposition of Pt₂(dba)₃ (dba: dibenzalacetone) and captured by active carbon modified with Fe to prepare a Pt-Fe/C catalyst. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray spectrometry (EDS) were used to characterize the size, distribution, electronic state of the Pt and Fe nanoparticles, and surface elements of the catalysts. The catalysts selectively hydrogenated cinnamaldehyde (CAL) to cinnamyl alcohol (COL), and the activity was more than one time that of a Pt/C catalyst prepared by the impregnation method. The 1% (w, mass fraction)Pt-1.5% (w)Fe/C catalyst exhibited the highest activity and selectivity at 60 °C, 2.5 h, and 4.0 MPa H₂. The conversion for CAL was 99.2%, and the selectivity of CAL to COL was 85.0%.
- Pt,
- Fe,
- Active carbon,
- Cinnamaldehyde,
- Cinnamyl alcohol,
- Selective hydrogenation
1. [1]
  (1) Arvela, P. M.; Hajek, J.; Salmi, T.; Murzin, D. Y. Appl. Catal. A: Gen. 2005, 292, 1.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev. 1998, 40, 81.
3. [3]
  (3) Chen, X. F.; Li, H. X.; Dai,W. L. Appl. Catal. A: Gen. 2003, 253, 359.
4. [4]
  (4) Li, H. X.; Chen, X. F.;Wang, M. H. Appl. Catal. A: Gen. 2002, 225, 117.
5. [5]
  (5) Wang, H.; Shu, Y. Y.; Zheng, M. Y. Catal. Lett. 2008, 124, 219.
6. [6]
  (6) Galletti, A. M. R.; Antonetti, C.; Venezia, A. M.; Giambastiani, G. Appl. Catal. A: Gen. 2010, 386, 124.
7. [7]
  (7) Qiu, J. S.; Zhang, H. Z.;Wang, X. N. Catal. Lett. 2006, 88, 269.
8. [8]
  (8) Li, Y.; Li, Z. G.; Zhou, R. X. J. Mol. Catal. A 2008, 279, 140.
9. [9]
  (9) Mahata, N.; ncalves, F.; Pereira, M. F. R.; Figueiredo, J. L. Appl. Catal. A: Gen. 2008, 339, 159.
10. [10]
  (10) Hajek, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2030.
11. [11]
  (11) Hajek, J.;Warna, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2039.
12. [12]
  (12) Carrillo, J. H.; Aramendia, M. A.; Marinas, A.; Marinas, J. M.; Urbano, F. J. Appl. Catal. A: Gen. 2010, 385, 190.
13. [13]
  (13) Hsu, C. Y.; Chiu, T. C.; Shih, M. H.; Tsai,W. J.; Chen,W. Y.; Lin, C. H. J. Phys. Chem. 2010, 114, 4502.
14. [14]
  (14) Chatterjee, M.; Ikushima, Y.; Yokoyama, T.; Suzuki, T. Microporous Mesoporous Mat. 2009, 117, 201.
15. [15]
  (15) Plomp, A. J.; Vuori, H.; Krause, A. O. I.; Jong, K. P.; Bitter, J. H. Appl. Catal. A: Gen. 2008, 351, 9.
16. [16]
  (16) Li, Y.; Ge, C. H.; Zhao, J.; Zhou, R. X. Catal. Lett. 2008, 126, 280.
17. [17]
  (17) Ma, H. X.;Wang, L. C.; Chen, L. Y.; Dong, C.; Yu,W. C.; Huang, T.; Qian, Y. T. Catal. Commun. 2007, 8, 452.
18. [18]
  (18) Han, X. X.; Zhou, R. X.; Yue, B. H.; Zheng, X. M. Catal. Lett. 2006, 109, 3.
19. [19]
  (19) Mao, J. Z.; Yan, X. H.; Gu, H. Z.; Jiang, L. C. Chin. J. Catal. 2009, 30, 182. [毛建忠, 严新焕, 顾辉子, 江玲超. 催化学报, 2009, 30, 182.]
20. [20]
  (20) Englisch, M.; Ranade, V. S.; Lercher, J. A. Mol. Catal. A: Chem. 1997, 121, 69.
21. [21]
  (21) Amornpattana,W. K.;Winterbottom, J. M. Catal. Today 2001, 66, 277.
1. [1]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-0. doi: 10.3866/PKU.WHXB202406009
2. [2]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
3. [3]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
4. [4]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
5. [5]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
6. [6]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
7. [7]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
8. [8]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
9. [9]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
10. [10]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
11. [11]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
12. [12]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
13. [13]
  Guilan He , Yaofeng Yuan . 手性二茂铁双膦配体Xyliphos的合成及应用. University Chemistry, 2025, 40(8): 130-137. doi: 10.12461/PKU.DXHX202409122
14. [14]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
17. [17]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
18. [18]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106

Get Citation

PDF

XML

Metrics

PDF Downloads(865)
Abstract views(2644)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142