Citation: XIAO Yao-Ming, WU Ji-Huai, YUE Gen-Tian, LIN Jian-Ming, HUANG Miao-Liang, FAN Le-Qing, LAN Zhang. Preparation of Single-Crystalline TiO₂ Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 578-584. doi: 10.3866/PKU.WHXB201201032 shu

Preparation of Single-Crystalline TiO₂ Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells

1.
Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou 362021, Fujian Province, P. R. China

Received Date: 18 October 2011
Available Online: 3 January 2012

Single-crystalline TiO₂ nanowires (SCTNWs) were prepared using a hydrothermal growth method. The (010) crystal face of the titania particles was eroded by NaOH solution to produce Na₂Ti₄O₉ at high temperature and pressure. H₂Ti₄O₉·H₂O was generated after washing with distilled water and HCl, which was then linked to a wire by hydrogen bonding. Finally, sintering gave SCTNWs. The SCTNWs were characterized by transmission electron microscopy (TEM), selected area electron diffraction (SAED), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). The influence of hydrothermal growth time was investigated. A flexible photoanode was fabricated on Ti foil using a highly stable and uniform titania colloid including the SCTNWs. The photovoltaic performance of dye-sensitized solar cells (DSSCs) containing different contents of SCTNWs was evaluated using scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), ultraviolet-visible (UV-Vis) spectrophotometry, and photovoltaic tests. Under optimized conditions with 7.5% (w) SCTNW, a flexible DSSC with a lightto- electrical energy conversion efficiency of 6.48% was achieved under irradiation with simulated solar light with an intensity of 100 mW·cm^-2.
- Flexible dye-sensitized solar cell,
- Titania,
- Nanowire,
- Hydrothermal method,
- Flexible photoanode
1. [1]
  (1) O' Regan, B.; Gratzel, M. Nature 1991, 353, 737.
2. [2]
  (2) Gratzel, M. Acc. Chem. Res. 2009, 42, 1788.
3. [3]
  (3) Kasuga, T.; Hiramatsu, M.; Hoson, A.; Sekino, T.; Niihara, K. Langmuir 1998, 14, 3160.
4. [4]
  (4) Liu, R. H.; Zhang, S.; Xia, X. Y.; Yun, D. Q.; Bian, Z. Q.; Zhao, Y. L. Acta Phys. -Chim. Sin. 2011, 27 (7), 1701. [刘润花, 张森, 夏新元, 云大钦, 卞祖强, 赵永亮. 物理化学学报, 2011, 27 (7), 1701.]
5. [5]
  (5) Wang,W.; Lin, H.; Li, J.;Wang, N. J. Am. Ceram. Soc. 2008, 91, 628.
6. [6]
  (6) Wu, L. Z.; Zhi, J. F. Acta Phys. -Chim. Sin. 2007, 23 (8), 1173. [吴良专, 只金芳. 物理化学学报, 2007, 23 (8), 1173.]
7. [7]
  (7) Zhang, X.; Yao, B.; Zhao, L.; Liang, C.; Zhang, L.; Mao, Y. J. Electrochem. Soc. 2001, 148 (7), G398.
8. [8]
  (8) Dong, X.; Tao, J.; Li, Y. Y.;Wang, T.; Zhu, H. Acta Phys. -Chim. Sin. 2009, 25 (9), 1874. [董祥, 陶杰, 李莹滢, 汪涛, 朱宏. 物理化学学报, 2009, 25 (9), 1874.]
9. [9]
  (9) Lei, Y.; Zhang, L. D.; Meng, G.W.; Li, G. H.; Zhang, X. Y.; Liang, C. H.; Chen,W.;Wang, S. X. Appl. Phys. Lett. 2001, 78 (8), 1125.
10. [10]
  (10) Zheng, M.; Dong, S. X. Nano Lett. 2002, 2, 717.
11. [11]
  (11) Tian, Z. R.; Voight, J. A.; Liu, J.; Mckenzie, B.; Xu, H. F. J. Am. Chem. Soc. 2003, 125, 12384.
12. [12]
  (12) Lon , C.; Freitas, J.; DePaoli, M. J. Photochem. Photobio. A: Chem. 2003, 159, 33.
13. [13]
  (13) Gratzel, M. Chem. Commun. 2006, 38, 4004.
14. [14]
  (14) Kang, M. G.; Park, N. G.; Ryu, K. S.; Chang, S. H.; Kim, K. J. Sol. Energy Mater. Sol. Cells 2006, 90, 574.
15. [15]
  (15) Xiao, Y. M.;Wu, J. H.; Li, Q. H.; Xie, G. X.; Yue, G. T.; Ye, H. F.; Lan, Z.; Huang, M. L.; Lin, J. M. Chin. Sci. Bull. 2010, 55, 980. [肖尧明, 吴季怀, 李清华, 谢桂香, 岳根田, 叶海峰, 兰章, 黄妙良, 林建明. 科学通报, 2009, 54 (16), 2425.]
16. [16]
  (16) Xiao, Y. M.;Wu, J. H.; Yue, G. T.; Xie, G. X.; Lin, J. M.; Huang, M. L. Electrochim. Acta 2010, 55, 4573.
17. [17]
  (17) Lin, X.;Wu, M. X.; An, J.; Miao, Q. Q.; Qin, D.; Ma, T. L. Acta Phys. -Chim. Sin. 2011, 27 (11), 2577. [林逍, 武明星, 安江, 苗青青, 覃达, 马廷丽. 物理化学学报, 2011, 27 (11), 2577.]
18. [18]
  (18) Yuan, Z.; Su, B. Colloids & Surfaces. A, 2004, 241, 173.
19. [19]
  (19) Wu, J. H.; Lan, Z.; Lin, J. M.; Huang, M. L.; Hao, S. C.; Stao, T.; Yin, S. Adv. Mater. 2007, 19, 4006.
20. [20]
  (20) Wu, J. H.; Hao, S. C.; Lan, Z.; Lin, J. M.; Huang, M. L.; Huang, Y. F.; Li, P. J.; Yin, S.; Stao, T. J. Am. Chem. Soc. 2008, 130, 11568.
21. [21]
  (21) Lan, Z.;Wu, J. H.; Hao, S. C.; Lin, J. M.; Huang, M. L.; Huang, Y. F. Energy Environ. Sci. 2009, 2, 524.
22. [22]
  (22) Xiao, Y. M.;Wu, J. H.; Yue, G. T.; Lin, J. M.; Huang, M. L.; Lan, Z. Electrochim. Acta 2011, 56, 8545.
23. [23]
  (23) Gratzel, M. Prog. Photovoltaic Res. Applic. 2000, 8, 171.
24. [24]
  (24) Liang, J.; Ma, S. F.; Han, P. D.; Sun, C. Y.; Xu, B. S. Rare Metal Mater. Engin. 2005, 34 (2), 287. [梁建, 马淑芳, 韩培德, 孙彩云, 许并社. 稀有金属材料与工程, 2005, 34 (2), 287.]
25. [25]
  (25) Yin, S.; Hasegawa, H.; Maeda, D.; Ishitsuka, M.; Sato, T. J. Photochem. Photobiol. A: Chem. 2004, 163, 1.
26. [26]
  (26) Feist, T.; Davies, P. J. Solid State Chem. 1992, 101 (2), 275.
27. [27]
  (27) Uchida, S.; Yamamoto, Y.; Fujishiro, Y.;Watanabe, A.; Ito, O.; Sato, T. J. Chem. Soc. Faraday Trans. 1997, 93, 3229.
28. [28]
  (28) Mei, X.; Cho, S.; Fan, B.; Ouyang, J. Y. Nanotechnology 2010, 21, 395202.
29. [29]
  (29) Li, G.;Wang, F.; Jiang, Q.; Gao, X.; Shen, P. Angew. Chem. Int. Edit. 2010, 49, 3653.
30. [30]
  (30) Mor, G.; Shankar, K.; Paulose, M.; Varghese, O.; Grimes, C. Nano Lett. 2006, 6, 215.
31. [31]
  (31) Lin, H.;Wang, N.; Zhang, L. Adv. Technol. Mater. Mater. Process. J. 2007, 9, 5.
32. [32]
  (32) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Muller, E.; Liska, P.; Vlachopoulos, N.; Gratzel, M. J. Am. Ceram. Soc. 1993, 115, 6382.
33. [33]
  (33) Nazeeruddin, M. K.; De Angelis, F.; Fantacci, S.; Selloni, A.; Viscardi, G.; Liska, P.; Ito, S.; Takeru, B.; Gratzel, M. J. Am. Chem. Soc. 2005, 127, 16835.
34. [34]
  (34) Ito, S.; Yoshida, S.;Watanabe, T. Chem. Lett. 2000, 29, 70.
1. [1]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
2. [2]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
3. [3]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
4. [4]
  Nengmin ZHU , Wenhao ZHU , Xiaoyao YIN , Songzhi ZHENG , Hao LI , Zeyuan WANG , Wenhao WEI , Xuanheng CHEN , Weihai SUN . Preparation of high-performance CsPbBr₃ perovskite solar cells by the aqueous solution solvent method. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1131-1140. doi: 10.11862/CJIC.20240419
5. [5]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-0. doi: 10.3866/PKU.WHXB202407025
6. [6]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
7. [7]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
8. [8]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
9. [9]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
10. [10]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
11. [11]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
12. [12]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
13. [13]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
14. [14]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
15. [15]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
16. [16]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
17. [17]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
18. [18]
  Mingxuan Qi , Lanyu Jin , Honghe Yao , Zipeng Xu , Teng Cheng , Qi Chen , Cheng Zhu , Yang Bai . Recent progress on electrical failure and stability of perovskite solar cells under reverse bias. Acta Physico-Chimica Sinica, 2025, 41(8): 100088-0. doi: 10.1016/j.actphy.2025.100088
19. [19]
  Ying Liang , Yuheng Deng , Shilv Yu , Jiahao Cheng , Jiawei Song , Jun Yao , Yichen Yang , Wanlei Zhang , Wenjing Zhou , Xin Zhang , Wenjian Shen , Guijie Liang , Bin Li , Yong Peng , Run Hu , Wangnan Li . Machine learning-guided antireflection coatings architectures and interface modification for synergistically optimizing efficient and stable perovskite solar cells. Acta Physico-Chimica Sinica, 2025, 41(9): 100098-0. doi: 10.1016/j.actphy.2025.100098
20. [20]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006

Get Citation

PDF

XML

Metrics

PDF Downloads(1770)
Abstract views(3051)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Single-Crystalline TiO2 Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Single-Crystalline TiO₂ Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells