Citation: LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs. Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2762-2766. doi: 10.3866/PKU.WHXB20112762 shu

Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)

1.
1. China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, LiaoningProvince, P. R. China;
2. Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,Dalian 116023, Liaoning Province, P. R. China;
3. College of Chemical Engineering and the Environment, Dalian University,Dalian 116622, Liaoning Province, P. R. China

Received Date: 20 April 2011
Available Online: 26 September 2011
Fund Project: 国家自然科学基金(21073189, 21006007, 20901076, 21176033) (21073189, 21006007, 20901076, 21176033)中国科学院大连化学物理研究所创新基金(K2009D03)资助项目 (K2009D03)

Experimental dynamic viscosity and conductivity data of the air- and water-stable hydrophobic ionic liquids (ILs) N-alkylpyridinium bis(trifluoromethylsulfonyl)imide ([C_npy][NTf₂] n=2, 4, 5) were recorded at temperatures ranging from 298.15 to 338.15 K and from 283.15 to 338.15 K with an interval of 5 K. The dynamic viscosity and conductivity values of the [C_npy][NTf₂] (n=2, 4, 5) ILs were fitted using the Arrhenius equation and the Fulcher equation. The molar conductivity was calculated at temperatures ranging from 283.15 to 338.15 K from the conductivity and density data. The relationship between the dynamic viscosity and the molar conductivity was discussed in terms of Walden's rule.
- Ionic liquids,
- Dynamic viscosity,
- Conductivity,
- Molar conductivity,
- Walden rule
1. [1]
  (1) Tsunashima, K.; Sugiya, M. Electrochem. Commun. 2007, 9, 2353.
2. [2]
  (2) Seki, S.; Kobayashi, Y.; Miyashiro, H.; Ohno, Y.; Usami, A.; Mita, Y.;Watanabe, M.; Terada, N. Chem. Commun. 2006, 544.
3. [3]
  (3) Itoh, H.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 2004, 126, 3026.
4. [4]
  (4) Du, Z.; Yu, Y. L.;Wang, J. H. Chem. Eur. J. 2007, 13, 2130.
5. [5]
  (5) Endres, F.; Abedin, S. Z. E. Phys . Chem . Chem . Phys. 2006, 8, 2101.
6. [6]
  (6) Fuller, J.; Carlin, R. T.; Long, H. C. D.; Haworth, D. J. Chem. Soc. Chem. Commun. 1994, 299.
7. [7]
  (7) rdon, C. M.; Holbrey, J. D.; Kennedy, R.; Seddon, K. R. J. Mater. Chem. 1998, 8, 2627.
8. [8]
  (8) Bonhote, P.; Dias, A. P.; Papageorgiou, N.; Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35, 1168.
9. [9]
  (9) Cammarata, L.; Kazarian, S. G.; Salter, P. A.;Welton, T. Phys. Chem. Chem. Phys. 2001, 3, 5192.
10. [10]
  (10) Liu, Q. B.; Janssen, M. H. A.; Rantwijk, F. V.; Sheldon, R. A. Green Chem. 2005, 7, 39.
11. [11]
  (11) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 680.
12. [12]
  (12) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 886.
13. [13]
  (13) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 1636.
14. [14]
  (14) Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, M. A. B. H.; Watanabe, M. J. Phys. Chem. B 2005, 109, 6103.
15. [15]
  (15) Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172.
16. [16]
  (16) Fang, S. H.; Yang, L.;Wei, C.; Peng, C. X.; Tachibana, K.; Kamijima, K. Electrochem. Commun. 2007, 9, 2696.
17. [17]
  (17) Kazock, J.; Tag ugui, M.; Anouti, M.;Willman, P.; Carré, B.; Lemordant, D. J. Appl. Electrochem. 2009, 39, 2461.
18. [18]
  (18) Sakaebe, H.; Matsumoto, H. Electrochem. Commun. 2003, 5, 594.
19. [19]
  (19) Yang, L.; Zhang, Z. X.; Gao, X. H.; Zhang, H. Q.; Mashita, K. J. Power Sources 2006, 162, 614.
20. [20]
  (20) Matsumoto, H.; Sakaebe, H.; Tatsumi, K.; Kikuta, M.; Ishiko, E.; Kono, M. J. Power Sources 2006, 160, 1308.
21. [21]
  (21) Orita, A.; Kamijima, K.; Yoshida, M. J. Power Sources 2010, 195, 7471.
22. [22]
  (22) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.;Welz- Biermann, U. J. Chem. Eng. Data 2010, 55, 4928.
23. [23]
  (23) Tokuda, H.; Tsuzuki, S.; Susan, M. A. B. H.; Hayamizu, K.; Watanabe, M. J. Phys. Chem. B 2006, 110, 19593.
24. [24]
  (24) Pan, Y.; Boyd, L. E.; Kruplak, J. F.; Cleland,W. E., Jr.;Wilkes, J. S.; Hussey, C. L. J. Electrochem. Soc. 2011, 158, F1.
25. [25]
  (25) MacFarlane, D. R.; Meakin, P.; Sun, J.; Amini, N.; Forsyth, M. J. Phys. Chem. B 1999, 103, 4164.
26. [26]
  (26) Orita, A.; Kamijima, K.; Yoshida, M.; Yang, L. J. Power Sources 2010, 195, 6970.
27. [27]
  (27) Harris, K. R.;Woolf, L. A.; Kanakubo, M. J. Chem. Eng. Data 2005, 50, 1777.
28. [28]
  (28) Wu, T. Y.; Su, S. G.; Gung, S. T.; Lin, M.W.; Lin, Y. C.; Lai, C. A.; Sun, I.W. Electrochimica. Acta 2010, 55, 4475.
29. [29]
  (29) Carpio, R. A.; King, L. A.; Kibler, F. C., Jr.; Fannin, A. A., Jr. J. Electrochem. Soc. 1979, 126, 1650.
30. [30]
  (30) Hagiwara, R.; Matsumoto, K.; Nakamori, Y.; Tsuda, T.; Ito, Y.; Matsumoto, H.; Momota, K. J. Electrochem. Soc. 2003, 150, D195.
31. [31]
  (31) Yoshizawa, M.; Xu,W.; Angell, C. A. J. Am. Chem. Soc. 2003, 125, 15411.
32. [32]
  (32) Angell, C. A.; Byrne, N.; Belieres, J. P. Accounts Chem. Res. 2007, 40, 1228.
33. [33]
  (33) Xu,W.; Cooper, E. I.; Angell, C. A. J. Phys. Chem. B 2003, 107, 6170.
34. [34]
  (34) MacFarlane, D. R.; Forsyth, M.; Iz rodina, E. I.; Abbott, A. P.; Annat, G.; Fraser, K. Phys. Chem. Chem. Phys. 2009, 11, 4962.
35. [35]
  (35) Xu,W.;Wang, L. M.; Nieman, R. A.; Angell, C. A. J. Phys. Chem. B 2003, 107, 11749.
36. [36]
  (36) Fraser, K. J.; Iz rodina, E. I.; Forsyth, M.; Scott, J. L.; MacFarlane, D. R. Chem. Commun. 2007, 3817.
37. [37]
  (37) Matsumoto, K.; Hagiwara, R. Inorg. Chem. 2009, 48, 7350.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dynamic Viscosity and Conductivity of Ionic Liquids [Cnpy][NTf2] (n=2, 4, 5)

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Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)