Citation: LIU Qing-Shan, YAN Pei-Fang, YANG Miao, TAN Zhi-Cheng, LI Chang-Ping, WELZ-BIERMANN Urs. Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2762-2766. doi: 10.3866/PKU.WHXB20112762 shu

Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)

1.
1. China Ionic Liquid Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, LiaoningProvince, P. R. China;
2. Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,Dalian 116023, Liaoning Province, P. R. China;
3. College of Chemical Engineering and the Environment, Dalian University,Dalian 116622, Liaoning Province, P. R. China

Received Date: 20 April 2011
Available Online: 26 September 2011
Fund Project: 国家自然科学基金(21073189, 21006007, 20901076, 21176033) (21073189, 21006007, 20901076, 21176033)中国科学院大连化学物理研究所创新基金(K2009D03)资助项目 (K2009D03)

Experimental dynamic viscosity and conductivity data of the air- and water-stable hydrophobic ionic liquids (ILs) N-alkylpyridinium bis(trifluoromethylsulfonyl)imide ([C_npy][NTf₂] n=2, 4, 5) were recorded at temperatures ranging from 298.15 to 338.15 K and from 283.15 to 338.15 K with an interval of 5 K. The dynamic viscosity and conductivity values of the [C_npy][NTf₂] (n=2, 4, 5) ILs were fitted using the Arrhenius equation and the Fulcher equation. The molar conductivity was calculated at temperatures ranging from 283.15 to 338.15 K from the conductivity and density data. The relationship between the dynamic viscosity and the molar conductivity was discussed in terms of Walden's rule.
- Ionic liquids,
- Dynamic viscosity,
- Conductivity,
- Molar conductivity,
- Walden rule
1. [1]
  (1) Tsunashima, K.; Sugiya, M. Electrochem. Commun. 2007, 9, 2353.
2. [2]
  (2) Seki, S.; Kobayashi, Y.; Miyashiro, H.; Ohno, Y.; Usami, A.; Mita, Y.;Watanabe, M.; Terada, N. Chem. Commun. 2006, 544.
3. [3]
  (3) Itoh, H.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 2004, 126, 3026.
4. [4]
  (4) Du, Z.; Yu, Y. L.;Wang, J. H. Chem. Eur. J. 2007, 13, 2130.
5. [5]
  (5) Endres, F.; Abedin, S. Z. E. Phys . Chem . Chem . Phys. 2006, 8, 2101.
6. [6]
  (6) Fuller, J.; Carlin, R. T.; Long, H. C. D.; Haworth, D. J. Chem. Soc. Chem. Commun. 1994, 299.
7. [7]
  (7) rdon, C. M.; Holbrey, J. D.; Kennedy, R.; Seddon, K. R. J. Mater. Chem. 1998, 8, 2627.
8. [8]
  (8) Bonhote, P.; Dias, A. P.; Papageorgiou, N.; Kalyanasundaram, K.; Grätzel, M. Inorg. Chem. 1996, 35, 1168.
9. [9]
  (9) Cammarata, L.; Kazarian, S. G.; Salter, P. A.;Welton, T. Phys. Chem. Chem. Phys. 2001, 3, 5192.
10. [10]
  (10) Liu, Q. B.; Janssen, M. H. A.; Rantwijk, F. V.; Sheldon, R. A. Green Chem. 2005, 7, 39.
11. [11]
  (11) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 680.
12. [12]
  (12) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 886.
13. [13]
  (13) Zhou, Z. B.; Matsumoto, H.; Tatsumi, K. Chemistry Letters 2004, 33, 1636.
14. [14]
  (14) Tokuda, H.; Hayamizu, K.; Ishii, K.; Susan, M. A. B. H.; Watanabe, M. J. Phys. Chem. B 2005, 109, 6103.
15. [15]
  (15) Jacquemin, J.; Husson, P.; Padua, A. A. H.; Majer, V. Green Chem. 2006, 8, 172.
16. [16]
  (16) Fang, S. H.; Yang, L.;Wei, C.; Peng, C. X.; Tachibana, K.; Kamijima, K. Electrochem. Commun. 2007, 9, 2696.
17. [17]
  (17) Kazock, J.; Tag ugui, M.; Anouti, M.;Willman, P.; Carré, B.; Lemordant, D. J. Appl. Electrochem. 2009, 39, 2461.
18. [18]
  (18) Sakaebe, H.; Matsumoto, H. Electrochem. Commun. 2003, 5, 594.
19. [19]
  (19) Yang, L.; Zhang, Z. X.; Gao, X. H.; Zhang, H. Q.; Mashita, K. J. Power Sources 2006, 162, 614.
20. [20]
  (20) Matsumoto, H.; Sakaebe, H.; Tatsumi, K.; Kikuta, M.; Ishiko, E.; Kono, M. J. Power Sources 2006, 160, 1308.
21. [21]
  (21) Orita, A.; Kamijima, K.; Yoshida, M. J. Power Sources 2010, 195, 7471.
22. [22]
  (22) Liu, Q. S.; Yang, M.; Yan, P. F.; Liu, X. M.; Tan, Z. C.;Welz- Biermann, U. J. Chem. Eng. Data 2010, 55, 4928.
23. [23]
  (23) Tokuda, H.; Tsuzuki, S.; Susan, M. A. B. H.; Hayamizu, K.; Watanabe, M. J. Phys. Chem. B 2006, 110, 19593.
24. [24]
  (24) Pan, Y.; Boyd, L. E.; Kruplak, J. F.; Cleland,W. E., Jr.;Wilkes, J. S.; Hussey, C. L. J. Electrochem. Soc. 2011, 158, F1.
25. [25]
  (25) MacFarlane, D. R.; Meakin, P.; Sun, J.; Amini, N.; Forsyth, M. J. Phys. Chem. B 1999, 103, 4164.
26. [26]
  (26) Orita, A.; Kamijima, K.; Yoshida, M.; Yang, L. J. Power Sources 2010, 195, 6970.
27. [27]
  (27) Harris, K. R.;Woolf, L. A.; Kanakubo, M. J. Chem. Eng. Data 2005, 50, 1777.
28. [28]
  (28) Wu, T. Y.; Su, S. G.; Gung, S. T.; Lin, M.W.; Lin, Y. C.; Lai, C. A.; Sun, I.W. Electrochimica. Acta 2010, 55, 4475.
29. [29]
  (29) Carpio, R. A.; King, L. A.; Kibler, F. C., Jr.; Fannin, A. A., Jr. J. Electrochem. Soc. 1979, 126, 1650.
30. [30]
  (30) Hagiwara, R.; Matsumoto, K.; Nakamori, Y.; Tsuda, T.; Ito, Y.; Matsumoto, H.; Momota, K. J. Electrochem. Soc. 2003, 150, D195.
31. [31]
  (31) Yoshizawa, M.; Xu,W.; Angell, C. A. J. Am. Chem. Soc. 2003, 125, 15411.
32. [32]
  (32) Angell, C. A.; Byrne, N.; Belieres, J. P. Accounts Chem. Res. 2007, 40, 1228.
33. [33]
  (33) Xu,W.; Cooper, E. I.; Angell, C. A. J. Phys. Chem. B 2003, 107, 6170.
34. [34]
  (34) MacFarlane, D. R.; Forsyth, M.; Iz rodina, E. I.; Abbott, A. P.; Annat, G.; Fraser, K. Phys. Chem. Chem. Phys. 2009, 11, 4962.
35. [35]
  (35) Xu,W.;Wang, L. M.; Nieman, R. A.; Angell, C. A. J. Phys. Chem. B 2003, 107, 11749.
36. [36]
  (36) Fraser, K. J.; Iz rodina, E. I.; Forsyth, M.; Scott, J. L.; MacFarlane, D. R. Chem. Commun. 2007, 3817.
37. [37]
  (37) Matsumoto, K.; Hagiwara, R. Inorg. Chem. 2009, 48, 7350.
1. [1]
  Fangyan Zhang , Yuhan Li , Bowen He , Meng Lin , Ying Ma . Determination of Sodium Carbonate Content: A Conductometric Titration Approach. University Chemistry, 2026, 41(3): 373-380. doi: 10.12461/PKU.DXHX202505023
2. [2]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
3. [3]
  Wan Li , Xiaohang Qiu , Xiuyun Wang , Mei Shi , Xiuqiong Zeng , Yanping Ren , Faqiong Zhao , Min Hu , Yiru Wang , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Wenwei Zhang , Weihong Li , Yong Fan , Jianrong Zhang , Shuyong Zhang . Specifications of Laboratory Water and Suggestions on the Use of Conductivity Meter. University Chemistry, 2026, 41(3): 77-86. doi: 10.12461/PKU.DXHX202507036
4. [4]
  Yibo Wang , Ruiyuan Xu , Binye Cao , Wanmei Li . Unlocking the Secrets of Battery Aging: Understanding the Life Cycle of Batteries. University Chemistry, 2026, 41(3): 330-335. doi: 10.12461/PKU.DXHX202503119
5. [5]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
6. [6]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
7. [7]
  Yameen Ahmed , Xiangxiang Feng , Yuanji Gao , Yang Ding , Caoyu Long , Mustafa Haider , Hengyue Li , Zhuan Li , Shicheng Huang , Makhsud I. Saidaminov , Junliang Yang . Interface Modification by Ionic Liquid for Efficient and Stable FAPbI₃ Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(6): 2303057-0. doi: 10.3866/PKU.WHXB202303057
8. [8]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
9. [9]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
10. [10]
  Qiaorong RU . Synthesis and characterization of tripyridine functionalized polyionic liquid luminescent materials. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 111-119. doi: 10.11862/CJIC.20250121
11. [11]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
12. [12]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-0. doi: 10.3866/PKU.WHXB202309041
13. [13]
  Yan Long , Wenbo Zhao , Qing Cao , Xiangyu Li , Fukui Li , Yanwei Hu , Shiyu Song , Kaikai Liu . Phosphorescent carbon nanodot inks for scalable and high-resolution invisible printing. Acta Physico-Chimica Sinica, 2026, 42(3): 100198-0. doi: 10.1016/j.actphy.2025.100198
14. [14]
  Chunfang Zhang , Cuimiao Zhang , Shuai Liu , Yaduo Zheng , Lin Yang , Kehan Jiang , Mingtao Run . Refined Experiment for Magnetic Susceptibility Determination: A Digital Empowered Experiment Based on WeChat Mini Program and Animated Video. University Chemistry, 2026, 41(1): 244-252. doi: 10.12461/PKU.DXHX202505056
15. [15]
  Hequn Yang , Fei Rao , Dean Pan , Liu Chen , Numan Abbas , Gangqiang Zhu . Rare earth praseodymium single atoms on g-C₃N₄ tubes for enhanced in-plane charge transfer towards H₂O₂ production in pure water. Acta Physico-Chimica Sinica, 2026, 42(6): 100210-. doi: 10.1016/j.actphy.2025.100210
16. [16]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
17. [17]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
18. [18]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
19. [19]
  Jianquan Liu , Xiangshan Wang . Teaching Design and Practice of Naming Rules for Circular Isomer Configuration under the Guidance of Information Literacy. University Chemistry, 2025, 40(7): 352-358. doi: 10.12461/PKU.DXHX202409082
20. [20]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103

Get Citation

PDF

XML

Metrics

PDF Downloads(1471)
Abstract views(4183)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dynamic Viscosity and Conductivity of Ionic Liquids [Cnpy][NTf2] (n=2, 4, 5)

Metrics

通讯作者: 陈斌, bchen63@163.com

Dynamic Viscosity and Conductivity of Ionic Liquids [C_npy][NTf₂] (n=2, 4, 5)