Citation: NG Yan-Yan, LIU Min, JIA Song-Yan, FENG Jian-Ping, SONG Chun-Shan, GUO Xin-Wen. Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 686-692. doi: 10.3866/PKU.WHXB201112292 shu

Production of 5-Hydroxymethylfurfural from Inulin Catalyzed by Sulfonated Amorphous Carbon in an Ionic Liquid

1.
1. State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China;
2. EMS Energy Institute and Department of Energy and Mineral Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, USA

Received Date: 27 September 2011
Available Online: 29 December 2011
Fund Project: 国家自然科学基金(20803005)资助项目 (20803005)

The production of 5-hydroxylmethylfurfural (HMF) from inulin over sulfonated amorphous carbon was studied in an ionic liquid, 1-butyl-3-methylimidazolium chloride ([Bmim]Cl). The effects of reaction solvent, water content, reaction temperature, reaction time, and catalyst dosage on the yield of HMF were investigated. Experimental results indicated that optimum reaction conditions required a reaction temperature of 100 °C, a reaction time of 60 min, an R value of 5 (R represents the molar ratio of added water to fructose units in inulin), and a mass ratio of catalyst to inulin of 1:3, affording HMF in yields of up to 50%.
- Inulin,
- 5-Hydroxymethylfurfural,
- Sulfonated amorphous carbon,
- Ionic liquid,
- Fructose
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