Citation: GUO Yuan-Hui, MEI Qun-Bo, YAN Fang, WANG Ling-Xia, WENG Jie-Na, ZHANG Bin, HUANG Wei. Application of Iridium(III) Complexes in Phosphorescent Chemosensors[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 739-750. doi: 10.3866/PKU.WHXB201112222 shu

Application of Iridium(III) Complexes in Phosphorescent Chemosensors

1.
Key Laboratory for Organic Electronics & Information Displays, and Institute of Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210046, P. R. China

Received Date: 10 October 2011
Available Online: 22 December 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2009CB930601) (973) (2009CB930601) 国家自然科学基金(50803027, 50903001, 20905038) (50803027, 50903001, 20905038)江苏省高校自然科学基础研究面上项目(08KJD430020)资助 (08KJD430020)

Chemosensors have developed quickly because they are widely used in biology. Compared to organic fluorescent chemosensors, phosphorescent chemosensors based on heavy metal complexes have attracted great attention because of distinctive merits such as relatively long lifetimes and significant Stokes shifts. Iridium complexes had been successfully used as phosphorescent chemosensors because of their relatively short excited state lifetime, high photoluminescence efficiency, and wide range emission colors that can be tuned by the coordinated ligands. In this review, we have summarized the applications of iridium complexes in cation, anion, oxygen, amino acid, and pH sensors. Furthermore, the advantages and disadvantages of these chemosensors have been compared to others. Finally, some prospects for future study are proposed.
- Chemosensor,
- Charged iridium complex,
- Neutral iridium complex,
- Phosphorescence,
- Energy transfer
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沈阳化工大学材料科学与工程学院沈阳 110142