Citation: RAO Gui-Shi, CHENG Mei-Qin, ZHONG Yan, DENG Xiao-Cong, YI Fei, CHEN Zhi-Ren, ZHONG Qi-Ling, FAN Feng-Ru, REN Bin, TIAN Zhong-Qun. Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2373-2378. doi: 10.3866/PKU.WHXB20111008 shu

Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation

1.
1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. China;
2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 29 March 2011
Available Online: 17 August 2011
Fund Project: 国家自然科学基金(20663002) (20663002) 厦门大学固体表面物理化学国家重点实验室基金(200511) (200511)江西省自然科学基金(0620025)资助项目 (0620025)

Pt hollow nanospheres with a particle diameter of 110 nm and a shell thickness of about 5 nm were synthesized in bulk using selenium colloids with a particle diameter of 100 nm as a template. Transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy dispersive X-ray spectrocopy (EDX), and scanning electron microscopy (SEM) were used to determine their morphologies and structures. The electrocatalytic activity of the Pt hollow nanospheres modifying glassy carbon electrode toward methanol oxidation was measured by using methanol as the probe molecule. We show that the multiporous Pt hollow nanospheres composited of atomic clusters have a uniform particle size, od dispersity, a stable structure, a big surface area and od mass transfer performance. Cyclic voltammetry (CV) showed that when the current density of methanol oxidation was 0.10 mA·cm^-2 and upon positive scanning the methanol oxidation potential of the Pt hollow nanospheres was around 110 and 64 mV negative than that of the Pt solid nanoparticles and Pt black, respectively. Upon negative scanning the former species was about 51 and 13 mV negative than that of the latter two species, respectively. After 800 segments cyclic voltammetry scanning, upon positive scanning the peak current density of methanol oxidation on the Pt hollow nanospheres was found to be 13 and 15 times as high as that of the Pt solid nanoparticles and Pt black, respectively. Upon negative scanning the former species was about 19 and 38 times as high as that of the two latter species. Our experimental results show that the Pt hollow nanospheres have od electrocatalytic activity and stability toward methanol oxidation.
- Platinum hollow nanospheres,
- Selenium sphere template,
- Preparation,
- Electrocatalysis,
- Methanol oxidation
1. [1]
  (1) Kuver, A.;Wielstih,W. J. Power Sources 1998, 74, 211.
2. [2]
  (2) Arico, A. S.; Srinivasan, S.; Antonucci, V. Fuel Cells 2001, 1, 133.
3. [3]
  (3) Hogarth, M. P.; Ralph, T. R. Platinum Metals Rev. 2002, 46, 146.
4. [4]
  (4) Ren, X.; Zelenay, P.; Thomas, S.; Davey, J.; ttesfeld, S. J. Power Sources 2000, 86, 111.
5. [5]
  (5) Witham, C. K.; Chun,W.; Valdez, T. I.; Narayanan, S. R. Electrochem. Solid State Lett. 2000, 3, 497.
6. [6]
  (6) Reddington, E.; Sapienza, A.; Gurau, B.; Viswanathan, R.; Sarangapani, S.; Smotkin, E. S.; Mallouk, T. E. Science 1998, 280, 1735.
7. [7]
  (7) Cruickshank, J.; Scott, K. J. Power Source 1998, 70, 40.
8. [8]
  (8) Gurau, B.; Smotkin, E. S. J. Power Sources 2002, 112, 339.
9. [9]
  (9) Kauranen, P. S.; Skou, E. J. Electroanal. Chem. 1996, 408, 189.
10. [10]
  (10) Miyake, M.;Wainright, J. S.; Savinell, R. R. J. Electrochem. Soc. 2001, 148, A905.
11. [11]
  (11) Hobson, L. J.; Nakano, Y.; Ozq, H.; Hayase, S. J. Power Sources 2002, 104, 79.
12. [12]
  (12) Mikhaylova, A. A.; Khazova, O. A. J. Electroanal. Chem. 2000, 225, 480.
13. [13]
  (13) Alivisatos, A. P. J. Phys. Chem. 1996, 100, 13226.
14. [14]
  (14) Nabika, H.; Deki, S. J. Phys. Chem. B 2003, 107, 9161.
15. [15]
  (15) Schmid, G. Clusters anc Colloids: From Theory to Application; VCH:Weinheim, 1994.
16. [16]
  (16) Yu, A.; Liang, Z. J.; Cho, J. H.; Caruso, F. Nano Lett. 2003, 3, 1203.
17. [17]
  (17) Stamm, K. L.; Garno, J. C.; Liu, G. Y.; Brock, S. L. J. Am. Chem. Soc. 2003, 125, 4036.
18. [18]
  (18) Alivisatos, A. P. Science 1996, 271, 933.
19. [19]
  (19) El-Sayed, M. A. Acc. Chem. Res. 2001, 34, 257.
20. [20]
  (20) Hu, J. T.; Odom, T.W.; Lieber, C. M. Accounts Chem. Res. 1999, 32, 435.
21. [21]
  (21) Sun, Y. G.; Xia, Y. N. Science 2002, 298, 2176.
22. [22]
  (22) Hu, J. Q.; Zhang, Y.; Liu, B.; Liu, J. X.; Zhou, H. H.; Xu, Y. F.; Jiang, Y. X.; Yang, Z. L.; Tian, Z. Q. J. Am. Chem. Soc. 2004, 126, 9470.
23. [23]
  (23) Teng, X.W.; Black, D.;Watkins, N. J.; Gao, Y. L.; Yang, H. Nano Lett. 2003, 3, 261.
24. [24]
  (24) Tian, N.; Zhou, Z. Y.; Sun, S. G.; Ding, Y.;Wang, Z. L. Science 2007, 316, 732.
25. [25]
  (25) Zhang, B.; Li, J. F.; Zhong, Q. L.; Ren, B.; Tian, Z. Q.; Zou, S. Z. Langmuir 2005, 21, 7449.
26. [26]
  (26) Mayers, B.; Jiang, X.; Sunderland, D.; Cattle, B.; Xia, Y. J. Am. Chem. Soc. 2003, 125, 13364.
27. [27]
  (27) Guo, S. J.; Dong, S. J.;Wang, E. K. J. Phys Chem. C 2009, 113, 5485.
28. [28]
  (28) Kim, S.W.; Kim, M.; Lee,W. Y.; Hyeon, T. J. Am. Chem. Soc. 2002, 124, 7642.
29. [29]
  (29) Sun, Y.; Xia, Y. Anal. Chem. 2002, 74, 5297.
30. [30]
  (30) Caruso, F. O. Chem. Eur. J. 2000, 6 (3), 413; Adv. Mater. 2001, 13 (1), 11.
31. [31]
  (31) Liang, H. P.; Zhang, H. M.; Hu, J. S.; Guo, Y. G.;Wan, L. J.; Bai, C. L. Angew. Chem. Int. Edit. 2004, 43, 1540.
32. [32]
  (32) Chem, Z.W.;Waje, M.; Li,W. Z.; Yan, Y. S. Angew. Chem. 2007, 119, 4138.
33. [33]
  (33) Iida, M.; Sasaki, T.;Watanabe, M. Chem. Mater. 1998, 10, 3780.
34. [34]
  (34) Liu, J. G.;Wilcox, D. L. J. Mater. Res. 1994, 10,84.
35. [35]
  (35) Hotz, J.; Meier,W. Langmuir 1998, 14, 1031.
36. [36]
  (36) Fowler, C. E.; Khushalani, D. D.; Mann, S. Chem. Commun. 2001, 19, 2028.
37. [37]
  (37) Zhao, M.; Sun, L.; Crooks, R. M. J. Am. Chem. Soc. 1998, 120, 4877.
38. [38]
  (38) Xu, H. L.;Wang,W. Z. Angew. Chem. Int. Edit. 2007, 46, 1.
39. [39]
  (39) Wijnhoven, J. E. G.; Vos,W. L. Science 1998, 281, 802.
40. [40]
  (40) Caruso, F.; Caruso, R. A. Science 1998, 282, 1111.
41. [41]
  (41) Velev, O. D.; Kaler, E.W. Adv. Mater. 2000, 12, 531.
42. [42]
  (42) Kim, S.W.; Kim, M.; Lee,W. Y.; Hyeon, T. J. Am. Chem. Soc. 2002, 124, 7642.
43. [43]
  (43) Graf, C.; Blaaderen, A. Langmuir 2002, 18, 524.
44. [44]
  (44) Zhang, J. H.; Zhan, P.; Liu, H. Y.;Wang, Z. L.; Ming, N. B. Mater. Lett. 2006, 60, 280.
45. [45]
  (45) Sun, Y.; Mayers, B.T.; Xia, Y. Nano Lett. 2002, 2, 481.
46. [46]
  (46) Teranishi, H.; Hosoe, M.; Miyake, M. Adv. Mater. 1997, 9, 65.
47. [47]
  (47) Xia, Y.; Gates, B.; Yin, Y.; Lu. Y. Adv. Mater. 2000, 12, 693.
48. [48]
  (48) Yan, L. L.; Jiang, Q. N.; Liu, D. Y.; Zhong, Y.;Wen, F. P.; Deng, X. C.; Zhong, Q. L.; Ren, B.; Tian, Z. Q. Acta Phys. -Chim. Sin. 2010, 26 (9), 2337.
49. [49]
  [颜亮亮, 江庆宁, 刘德宇, 钟艳, 温飞鹏, 邓小聪, 钟起玲, 任斌, 田中群. 物理化学学报, 2010, 26 (9), 2337.]
50. [50]
  (49) Trasatti, S.; Petrii,O. A. Pure Appl. Chem. 1991, 63, 711.
51. [51]
  (50) Sun, S. G.; Chen, A. C.; Huang, T. S.; Li, J. B.; Tian, Z.W. J. Electroanal. Chem.1992, 213, 340.
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