Citation: YAN Shi, HUANG Qin-Dong, LIN Jing-Dong, YUAN You-Zhu, LIAO Dai-Wei. Photocatalytic Activity of Cobalt Doped Titania for H₂ Evolution[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2406-2410. doi: 10.3866/PKU.WHXB20110929 shu

Photocatalytic Activity of Cobalt Doped Titania for H₂ Evolution

YAN Shi ¹ ,
HUANG Qin-Dong ¹ ,
LIN Jing-Dong ^1,2, ,
YUAN You-Zhu ^1,2,3 ,
LIAO Dai-Wei ^1,2,3

1.
1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, Xiamen 361005, Fujian Province, P. R. China
3. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen 361005, Fujian Province, P. R. China

Received Date: 1 April 2011
Available Online: 26 July 2011
Fund Project: 国家重点基础研究发展规划项目(973)(2011CBA00508)资助 (973)(2011CBA00508)

Cobalt-doped titania (Co/TiO₂) photocatalysts were synthesized by the polymerized complex method (PCM). The materials were characterized by thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), Fourier transform-infrared spectroscopy (FT-IR), X-ray diffraction (XRD), nitrogen adsorption-desorption, ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of the samples was evaluated by hydrogen evolution. The results show that anatase type titania exists in the materials and cobalt is evenly dispersed. The activity of the cobalt doped titania was found to be superior to that of pure titania. The maximum activity obtained at 0.3% Co/Ti molar ratio was nearly 6 times as high as that of pure titania. The amount of hydrogen produced was up to 2499 μmol. The doping mechanism of cobalt is discussed.
- Cobalt-doped,
- Titania,
- Polymerized complex method,
- Photocatalysis,
- H₂ evolution
1. [1]
  (1) Lewis, N.; Nocera, D. Proc. Natl. Acad. Sci. U. S. A. 2006, 113, 15729.
2. [2]
  (2) Fox, M.; Dulay, M. Chem. Rev. 1993, 93, 341.
3. [3]
  (3) Kamat, P. J. Phys. Chem. C 2007, 111, 2834.
4. [4]
  (4) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253.
5. [5]
  (5) Osterloh, F. Chem. Mater. 2008, 20, 35.
6. [6]
  (6) Fujishima, A.; Honda, K. Nature 1972, 238, 37.
7. [7]
  (7) Hoffmann, M.; Martin, S.; Choi,W. Y.; Bahnemannt, D. Chem. Rev. 1995, 95, 69.
8. [8]
  (8) Ni, M.; Leung, M. K. H.; Leung, D. Y. C.; Sumathy, K. Renew. Sust. Energ. Rev. 2007, 11, 401.
9. [9]
  (9) Liang,W. P.; Yang, J. L.; Chen, Y. J.; Li, C. Physical Chemistry in the New Century; Science Press: Beijing, 2004; pp 148-153.
10. [10]
  [梁文平, 杨俊林, 陈拥军, 李灿. 新世纪的物理化学. 北京: 科学出版社, 2004: 148-153.]
11. [11]
  (10) Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Science 2001, 293, 269.
12. [12]
  (11) Yu, Z. Y.; Zhang,W.; Ma, M.; Cui, X. L. Acta Phys. -Chim. Sin. 2009, 25, 35.
13. [13]
  [余志勇, 张维, 马明, 崔晓莉. 物理化学学报, 2009, 25, 35.]
14. [14]
  (12) Umebayashi, T.; Yamaki, T.; Itoh, H.; Asai, K. Appl. Phys. Lett. 2002, 81, 454.
15. [15]
  (13) Jing, D.W.; Guo, L. J. J. Phys. Chem. Solids 2007, 68, 2363.
16. [16]
  (14) Kakihana, M.; Yoshimura, M. B. Chem. Soc. Jpn. 1999, 72, 1427.
17. [17]
  (15) Lin, H. Y.; Chang, Y. S. Int. J. Hydrogen Energ. 2010, 35, 8463.
18. [18]
  (16) Hu, C. C.; Teng, H. J. Catal. 2010, 272, 1.
19. [19]
  (17) Wu, Y. Q.; Lu, G. X.; Li, S. B. Chin. J. Inorg. Chem. 2005, 21, 309.
20. [20]
  [吴玉琪, 吕功煊, 李树本. 无机化学学报, 2005, 21, 309.]
21. [21]
  (18) Bascha, A.; Alberingb, J. J. Power Sources 2011, 196, 3290.
22. [22]
  (19) Dvoranova, D.; Brezova, V.; Mazur, M.; Malati, M. Appl. Catal. B -Environ. 2002, 37, 91.
23. [23]
  (20) Wu, S. X.; Ma, Z.; Qin, Y. N.; Qi, X. Z.; Liang, Z. C. Acta Phys. -Chim. Sin. 2004, 20, 138.
24. [24]
  [吴树新, 马智, 秦永宁, 齐晓周, 梁珍成. 物理化学学报, 2004, 20, 138.]
25. [25]
  (21) Choi,W. Y.; Termin, A.; Hoffmann, M. J. Phys. Chem. 1994, 98, 13669.
26. [26]
  (22) Soria, J.; Conesa, J.; Augugliaro, V.; Palmisano, L.; Schiavello, M.; Sclafani, A. J. Phys. Chem. 1991, 95, 274.
27. [27]
  (23) Gratzel, M.; Howe, R. J. Phys. Chem. 1990, 94, 2566.
1. [1]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
2. [2]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-0. doi: 10.3866/PKU.WHXB202406024
3. [3]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
4. [4]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
7. [7]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
8. [8]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
9. [9]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
10. [10]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
11. [11]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
12. [12]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
16. [16]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
17. [17]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
18. [18]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
19. [19]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
20. [20]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036

Get Citation

PDF

XML

Metrics

PDF Downloads(1360)
Abstract views(3173)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Photocatalytic Activity of Cobalt Doped Titania for H2 Evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Photocatalytic Activity of Cobalt Doped Titania for H₂ Evolution