Citation: WEN Sheng, NG Chun-Li, TSAI Fang-Chang, YEH Jen-Taut. Properties of SPES/AlOOH Composite Proton Exchange Membranes[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1886-1892. doi: 10.3866/PKU.WHXB20110737 shu

Properties of SPES/AlOOH Composite Proton Exchange Membranes

1.
1. Faculty of Material Science and Engineering, Hubei University, Wuhan 430062, P. R. China;
2. Faculty of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430073, P. R. China;
3. Faculty of Chemistry and Materials Science, Xiaogan University, Xiaogan 432000, Hubei Province, P. R. China

Received Date: 1 March 2011
Available Online: 8 June 2011
Fund Project: 湖北省自然科学基金(2010CDB00301)资助项目 (2010CDB00301)

Novel sulfonated polyether sulfone (SPES)/AlOOH organic/inorganic composite membranes were prepared by doping SPES with AlOOH, which lowered the methanol crossover and increased the proton conductivity at high temperatures. The structure and performance of the obtained membranes were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) etc. Compared with the pure SPES membrane the composite membranes had higher thermal stability and water uptake. The morphology of the composite membranes indicated that AlOOH was uniformly distributed throughout the SPES matrix. The network-like structure began to form when the AlOOH content was around 10%. The proton conductivity was still ca 0.014 S·cm^-1 even at a temperature as high as 120 °C. Additionally, the methanol resistance improved greatly as the content of AlOOH increased. The SPES/AlOOH composite membrane is a promising candidate for direct methanol fuel cell (DMFC) applications.
- Sulfonated poly(ether sulfone),
- AlOOH,
- Composite membrane,
- Direct methanol fuel cell
1. [1]
  
  (1) Fu, X. Z.; Li, J.; Lu, C. H.; Liao, D.W. Progress in Chemistry 2004, 16 (1), 77. [符显珠, 李俊, 卢成慧, 廖代伟. 化学进展, 2004, 16 (1), 77.]
2. [2]
  (2) ng, C. L.; Zhou, Y.; Yan, L. C.;Wen, S.; Zheng, G.W. Acta Phys.-Chim. Sin. 2010, 26 (11), 2967. [龚春丽, 周毅, 闫礼成, 文胜, 郑根稳. 物理化学学报, 2010, 26 (11), 2967.]
3. [3]
  (3) Deng, H. N.; Li, L.; Xu, L.;Wang, Y. X. Acta Phys. -Chim. Sin. 2007, 23 (8): 1235. [邓会宁, 李磊, 许莉, 王宇新. 物理化学学报, 2007, 23 (8), 1235.]
4. [4]
  (4) Rhee, C. H.; Kim, H. K.; Chang, H.; Lee, J. S. Chem. Mater. 2005, 17, 1691.
5. [5]
  (5) Yang, S. F.; ng, C. L.; Guan, R.; Zou, H.; Dai, H. Polym. Adv. Technol. 2006, 17, 360.
6. [6]
  (6) Yi, B. L. Fuel Cells-Principle Technology Application: Chemical Industry Press: Beijing, 2003; p 351. [衣宝廉. 燃料电池-原理·技术·应用. 北京: 化学工业出版社, 2003: 351.]
7. [7]
  (7) Nolte, R.; Ledjeff, K.; Bauer, M.;Mülhaupt, R. J. Membr. Sci. 1993, 83, 211.
8. [8]
  (8) Guan, R.; Dai, H.; Li, C.; Liu, J.; Xu, J. J. Membr. Sci. 2006, 277, 148.
9. [9]
  (9) Kopitzke, R.W.; Linkous, C. A.; Anderson, H. R.; Nelson, G. L. J. Electrochem. Soc. 2000, 147, 1677.
10. [10]
  (10) Dai, H.; Guan, R.; Li, C.; Liu, J. Solid State Ionics 2007, 178, 339.
11. [11]
  (11) Tsai, J. C.; Kuo, J. F.; Chen, C.Y. J. Power Sources 2007, 174, 103.
12. [12]
  (12) Su, Y. H.; Liu, Y. L.; Sun, Y. M.; Lai, J. Y.;Wang, D. M.; Gao, Y.; Liu, B.; Guiver, M. D. J. Membr. Sci. 2007, 296, 21.
13. [13]
  (13) Nunes, S. P.; Ruffmann, B.; Rikowski, E.; Vetter, S.; Richau, K. J. Membr. Sci. 2002, 203, 215.
14. [14]
  (14) Jin, H.; Xie, X. F.; Shang, Y. M.; Feng, S. G.; Lv, Y. F. Chemical Industry and Engineering Progress 2007, 26 (4), 507. [靳豪, 谢晓峰, 尚玉明, 冯少广, 吕亚非. 化工进展, 2007, 26 (4), 507.]
15. [15]
  (15) Shen, J.; Xi, J. Y.; Zhu,W. T.; Chen, L. Q.; Qiu, X. P. J. Power Sources 2006, 159, 894.
16. [16]
  (16) Yan, J. S.; Long, J.; Tian, H. P. Petroleum Processing and Petrochemicals 2004, 35 (9), 38. [严加松, 龙军, 田辉平. 石油炼制与化工, 2004, 35 (9), 38.]
17. [17]
  (17) Ye, T. X.; Liu, J.Y.; Zhang, B.; Ma, X. N. Chinese Journal of Applied Chemistry 2009, 26 (9), 1114. [叶天旭, 刘京燕, 张斌, 马雪妮. 应用化学, 2009, 26 (9), 1114.]
18. [18]
  (18) Lv, J. G.; Zhang, J.; Ding,W. P.; Shen, B.; Guo, X. F. Chinese Journal of Inorganic Chemistry 2007, 23 (5), 897. [吕建刚, 张娟, 丁维平, 沈彬, 郭学峰. 无机化学学报, 2007, 23 (5), 897.]
19. [19]
  (19) Liu, C. H.; Liao, H. D.; Long, X. Y. Journal of Southwest China Normal University 2003, 28 (2), 263. [刘昌华, 廖海达, 龙翔云. 西南师范大学学报(自然科学版, 2003, 28 (2), 263.]
20. [20]
  (20) Zheng, G.W.; ng, C. L.;Wen, S.; Zhou, H. B.; Xie, X. L. Acta Phys.-Chim. Sin., 2009, 25 (3), 575. [郑根稳, 龚春丽, 文胜, 周环波, 解孝林. 物理化学学报, 2009, 25 (3), 575.]
21. [21]
  (21) Shu, Y. C.; Chuang, F. S.; Tsen,W. C.; ng, C. L.;Wen, S. J. Appl. Polym. Sci. 2008, 108, 1783.
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