Citation: WU Mei-Fen, WEN Zhao-Yin, LIU Yu. Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1695-1700. doi: 10.3866/PKU.WHXB20110708 shu

Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode

1.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received Date: 18 February 2011
Available Online: 18 May 2011
Fund Project: 国家自然科学基金(50973127) (50973127) 国家重点基础研究发展计划项目(973) (2007CB209700) (973) (2007CB209700)上海市科委(08DZ2210900)资助 (08DZ2210900)

To get rid of impurities on a Li surface and avoid hydrogen gas generation during the preparation of a lithium pyrrolide film, tetrahydrofuran (THF) was used to pretreat the surface of a Li electrode. We found that THF pretreatment can obviously refresh the Li surface as well as improve the uniformity and density of the lithium pyrrolide film. The interface resistance effectively decreases and the interfacial stability improves. Additionally, the reversibility of the lithium deposition/dissolution process increases. All the ‘sponge-shaped’ lithium deposits are homogeneously distributed on the electrode surface and the lithium cycling efficiency is enhanced by THF pretreatment.
- Li metal,
- Tetrahydrofuran,
- Pyrrole,
- Passive film,
- Pretreatment
1. [1]
  
  (1) Scrosati, B.; Garche, J. J. Power Sources 2010, 195, 2419.
2. [2]
  (2) Hassoun, J.; Fernicola, A.; Navarra, M. A.; Panero, S.; Scrosati, B. J. Power Sources 2010, 195, 574.
3. [3]
  (3) Wang, L.; He, X. M.; Pu,W. H. Progress in Chemistry 2006, 18(5), 641. [王莉, 何向明, 蒲薇华. 化学进展, 2006, 18 (5), 641.]
4. [4]
  (4) Akridge, J. R.; Mikhaylik, Y. V.; White, N. Solid State Ionics 2004, 175, 243.
5. [5]
  (5) Mirzaeian, M.; Hall, P. J. Electrochim. Acta 2009, 54, 7444.
6. [6]
  (6) Padbury, R.; Zhang, X.W. J. Power Sources 2011, 196, 4436.
7. [7]
  (7) Lane, G. H.; Best, A. S.; MacFarlane, D. R.; Forsyth, M.; Hollenkamp, A. F. Electrochim. Acta 2010, 55 (6), 2210.
8. [8]
  (8) Zhuang, Q. C.;Wu, S. Chinese Journal of Power Sources 2004, 28 (2), 104. [庄全超, 武山. 电源技术, 2004, 28 (2), 104.]
9. [9]
  (9) Eineli, Y.; Aurbach, D. J. Power Sources 1995, 54, 281.
10. [10]
  (10) Ding, F.; Zhang, C. F.; Hu, X. G. Rare Metal Materials and Engineering, 2006, 35 (4), 585. [丁飞, 张翠芬, 胡信国. 稀有金属材料与工程, 2006, 35 (4), 585.]
11. [11]
  (11) Aurbach, D.; Zingrad, E.; fer, Y.; Teller, H. Solid State Ionics 2002, 148, 405.
12. [12]
  (12) Cohen, Y. S.; Cohen, Y.; Aurbach, D. J. Phys. Chem. B 2000, 104, 1228.
13. [13]
  (13) Koch, V. R.; Mass, F. Aprotic Solvent Electrolytes and Batteries Using Same. US Patent 4118550, 1978-10-3.
14. [14]
  (14) Abraham, K. M.; Foos J. S.; ldman, J. L. J. Electrochem. Soc. 1984, 131, 2197.
15. [15]
  (15) Wu, M. F.;Wen, Z. Y.; Liu, Y.; Huang, L. Z. Morphology and electrochemical behavior of Li metal behavior with pyrrole treatment for lithium secondary battery. In Solid State Ionics. Proceedings of the12th Asian Conference on Solid State Ionics- Fundamental Researches and Technological Applications, Wuhan, P. R. China, May 2-6, 2010, Chowdari, B. V. R.; Liu, H. X.; Chen,W.; Xu, Q.; Yu, Z. Y. Eds.;Wuhan University of Technology Press:Wuhan, c2010; pp 844-851.
16. [16]
  (16) Boukamp, B. A. Solid State Ionics 1986, 20 (1), 31.
17. [17]
  (17) Li, Q.; Sun, H.Y.; Takeda,Y.; Imanishi, N.;Yang, J.;Yamamoto, O. J. Power Sources 2001, 94 (2), 201.
18. [18]
  (18) Orsini, F.; Dolle, M.; Tarascon, J. M. Solid State Ionics 2000, 135, 213.
19. [19]
  (19) Aurbach, D. J. Power Sources 2000, 89 (2), 206.
20. [20]
  (20) Ding. F. Study on Lithium Metal Anode Material of High Specific Energy Lithium Secondary Battery. Ph. D. Dissertation, Harbin Institute of Technology, Harbin, 2006. [丁飞. 高比能量二次锂电池中金属锂负极材料的研究[D]. 哈尔滨: 哈尔滨工业大学, 2006.]
21. [21]
  (21) Cao, C. N.; Zhang, J. Q. An Introduction to Electrochemical Impedance. Science Press: Beijing, 2002; pp: 92-95. [曹楚南, 张鉴清. 电化学阻抗谱导论. 北京: 科学出版社, 2002: 92-95.]
22. [22]
  (22) Broussely, M.; Biensan, P.; Bonhomme, F.; Blanchard, P.; Herreyre, S.; Nechev, K.; Staniewicz, R. J. J. Power Sources 2005, 146 (1-2), 90.
23. [23]
  (23) Aurbach, D.; Einely, Y.; Zaban, A. J. Electrochem. Soc. 1994, 141 (1), L1.
24. [24]
  (24) Aurbach, D.;Weissman, I.; Schechter, A.; Cohen, H. Langmuir 1996, 12, 3991.
25. [25]
  (25) Zaban, A.; Aurbach, D. J. Electroanal. Chem. 1993, 348, 155.
26. [26]
  (26) Osaka, T.; Momma, T.; Matsumoto, Y.; Uchida, Y. J. Power Sources 1997, 68, 497.
1. [1]
  Leyu DING , Ying HE , Zhihe WEI , Yang PENG , Zhao DENG . Conductive polypyrrole-confined Co-MOF-74 for high-performance lithium metal anodes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2491-2502. doi: 10.11862/CJIC.20250176
2. [2]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
3. [3]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
4. [4]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
5. [5]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100021-0. doi: 10.3866/PKU.WHXB202311005
6. [6]
  Qiuxiang FANG , Xinyue CHEN , Yuyang GUO , Penghui XIE , Pengbiao GENG . Application of metal-organic framework derived materials in lithium-sulfur battery separators. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 1910-1932. doi: 10.11862/CJIC.20260188
7. [7]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
8. [8]
  Chunyue Fang , Xiaoxuan Tan , Chunhong Wang , Yang He , Xiaoyuan Pei , Yu Zhang , Sarani binti Zakaria , Guangwei Fu , Jiangang Wang , Li Chen , Kun Liu , Ting Xu , Chuanling Si . Janus liquid metal@Mxene/Fe₃O₄ nanofiber membranes with polydopamine-confined liquid metal for electromagnetic interference shielding and infrared control. Acta Physico-Chimica Sinica, 2026, 42(10): 100281-0. doi: 10.1016/j.actphy.2026.100281
9. [9]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
10. [10]
  Zhiming Cui , Yuanlong Wu . 综合创新实验：基于原位聚合技术的固态锂金属电池的构筑及性能评价. University Chemistry, 2026, 41(9): 313-323. doi: 10.12461/PKU.DXHX202508043
11. [11]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
12. [12]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
13. [13]
  Hua Zhou , Yuqing Li , Rui Zhang , Jialong Qian , Zhenhua Li , Mingfei Shao . 电解水制氢耦合5-羟甲基糠醛氧化制2,5-呋喃二甲酸创新实验设计. University Chemistry, 2026, 41(8): 321-330. doi: 10.12461/PKU.DXHX202507123
14. [14]
  Huiru Sheng , Rui Qi , Chao Shen , Hao Xu , Jiabin Shen , Pengfei Zhang . Green synthesis of pyrrolo[1,2-a]quinoxaline derivatives as antineoplastic agents: a comprehensive chemistry laboratory teaching exploration. University Chemistry, 2026, 41(7): 266-273. doi: 10.12461/PKU.DXHX202505015
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
17. [17]
  Ruizhi Duan , Xiaomei Wang , Panwang Zhou , Yang Liu , Can Li . The role of hydroxyl species in the alkaline hydrogen evolution reaction over transition metal surfaces. Acta Physico-Chimica Sinica, 2025, 41(9): 100111-0. doi: 10.1016/j.actphy.2025.100111
18. [18]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
19. [19]
  Hongli CHEN , Ziling XU , Shiwen DU , Ting WANG , Liguang WU . Controlled preparation of HKUST-1 based on polyvinylpyrrolidone and CO₂ separation performance of its doped mixed-matrix membranes. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 571-583. doi: 10.11862/CJIC.20250263
20. [20]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291

Get Citation

PDF

XML

Metrics

PDF Downloads(1081)
Abstract views(3378)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142