Citation: WU Mei-Fen, WEN Zhao-Yin, LIU Yu. Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1695-1700. doi: 10.3866/PKU.WHXB20110708 shu

Effects of Tetrahydrofuran Pretreatment on the Performance of Pyrrole Modified Li Metal Electrode

1.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received Date: 18 February 2011
Available Online: 18 May 2011
Fund Project: 国家自然科学基金(50973127) (50973127) 国家重点基础研究发展计划项目(973) (2007CB209700) (973) (2007CB209700)上海市科委(08DZ2210900)资助 (08DZ2210900)

To get rid of impurities on a Li surface and avoid hydrogen gas generation during the preparation of a lithium pyrrolide film, tetrahydrofuran (THF) was used to pretreat the surface of a Li electrode. We found that THF pretreatment can obviously refresh the Li surface as well as improve the uniformity and density of the lithium pyrrolide film. The interface resistance effectively decreases and the interfacial stability improves. Additionally, the reversibility of the lithium deposition/dissolution process increases. All the ‘sponge-shaped’ lithium deposits are homogeneously distributed on the electrode surface and the lithium cycling efficiency is enhanced by THF pretreatment.
- Li metal,
- Tetrahydrofuran,
- Pyrrole,
- Passive film,
- Pretreatment
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沈阳化工大学材料科学与工程学院沈阳 110142