Citation: YAO Wei, WANG Hong-Ning, WANG Jian-Wu, ZHONG Jing, CHEN Ruo-Yu. Preparation, Characterization and Adsorption Mechanism for Phenols of CTMAB-ZrP[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1763-1771. doi: 10.3866/PKU.WHXB20110704 shu

Preparation, Characterization and Adsorption Mechanism for Phenols of CTMAB-ZrP

1.
School of Petrochemical Technology, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China

Received Date: 27 December 2010
Available Online: 16 May 2011
Fund Project: 江苏省自然科学基金(BK2008143)资助项目 (BK2008143)

Cetyltrimethyl ammonium bromid (CTMAB)-ZrP complexes that contained different amounts of CTMAB that intercalate into α-zirconium phosphate were successfully prepared while methylamine weakened the interlayer forces in α-zirconium phosphate. The CTMAB-ZrP samples were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and N₂ sorption isotherm analysis. We discuss the arrangement of CTMAB in the interlayers of zirconium phosphate according to the characterization results. The results of the adsorption of phenol by CTMAB-ZrP showed that the amount of phenol adsorption depended on the content of CTMAB in the complex, the interlayer steric hindrance, and the pH value of the solution. The adsorption of phenol, 2-chlorophenol, 2,4-dichlorophenol, p-methylphenol, and 3,5- dimethylphenol onto CTMAB-ZrP showed that the amount of adsorption correlated positively with the hydrophobicity of the phenols and it was not related to the acidity of the phenolic compounds. The sorption isotherms of phenol, 2-chlorophenol, and 2,4-dichlorophenol fit the Henry and Freundlich equations well. Therefore, the adsorption mechanism is mainly associated with the partition of different phenols in the organic phase of the intercalated CTMAB-ZrP.
- α-ZrP,
- Cetyltrimethyl ammonium bromid,
- Phenol,
- Adsorption,
- Partition
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沈阳化工大学材料科学与工程学院沈阳 110142