Citation: YUE Jun-Pei, YANG Fang-Zu, TIAN Zhong-Qun, ZHOU Shao-Min. Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1446-1450. doi: 10.3866/PKU.WHXB20110620 shu

Electrocrystallization of Pd-Ni Alloys on Glassy Carbon Electrode

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 16 December 2010
Available Online: 4 May 2011
Fund Project: 国家自然科学基金(20873114, 20833005) (20873114, 20833005)国家重点基础研究发展计划(2009CB930703)资助项目 (2009CB930703)

Using the Scharifker and Hills model and Heerman and Tarallo model, cyclic voltammetry and chronoamperometry were used to study the nucleation mechanism upon the electrodeposition of a Pd-Ni alloy from an electrolyte. The results show that the electrodeposition of the Pd-Ni alloy onto glassy carbon electrode consisted of nucleation and growth, and the nucleation process according to the Scharifker and Hills model follows three dimension-progressive nucleation, which is controlled by the diffusion of the electroactive species. By applying the Heerman and Tarallo model, the kinetic parameters associated with the crystal nucleation and growth processes were obtained. The nucleation rate constant and the density of active nucleation sites increased from 0.83 to 7.71 s^-1 and from 2.77×10⁴ to 7.09×10⁴ cm^-2, respectively, as the step potential was changed from -0.85 to -0.92 V (vs SCE).
- Pd-Ni alloy,
- Electrocrystallization,
- Cyclic voltammetry,
- Chronoamperometry
1. [1]
  
  (1) Fleischmann, M.; Liler, M. Trans. Faraday Soc. 1958, 54, 1370.
2. [2]
  (2) Fleischmann, M.; Thirsk, H.R. Trans. Faraday Soc. 1955, 51, 71.
3. [3]
  (3) Fleischmann, M.; Thirsk, H.R. Electrochim. Acta 1958, 1, 146.
4. [4]
  (4) Gunawardena, G.A.; Hills, G.; Montenegro, I.; Scharifker, B. J. Electroanal. Chem. 1982, 138, 225.
5. [5]
  (5) Scharifker, B.; Hills, G. Electrochim. Acta 1983, 28, 879.
6. [6]
  (6) Scharifker, B.; Mostany, J. J. Electroanal. Chem. 1984, 177, 13.
7. [7]
  (7) Sluyters-Rehbach, M.;Wijenberg, J. H. O. J.; Bosco, E.; Sluyters, J. H. J. Electroanal. Chem. 1987, 236, 1.
8. [8]
  (8) Heerman, L.; Tarallo, A. J. Electroanal. Chem. 1999, 470, 70.
9. [9]
  (9) Hyde, M. E.; Compton, R. G. J. Electroanal. Chem. 2003, 549, 1.
10. [10]
  (10) Franz, S.; Yasumura, K. Galvanotechnik 2002, 93, 1210.
11. [11]
  (11) Hiramoto, O. ECS Transactions 2008, 3, 11.
12. [12]
  (12) Abys, J. A.; Straschil, H. K.; Kadija, I. V.; Kudrak, E. J.; Blee, J. J. Metal Finish. 1991, 89, 43.
13. [13]
  (13) Valcarcel, A.; Morfin, F.; Piccolo, L. J. Catal. 2009, 263, 315.
14. [14]
  (14) Lou, Y.; Shao, Y.T .; Li, P.; Li, Z. L.; Niu, Z. J. J. Electroanal. Chem. 2008, 624, 33.
15. [15]
  (15) Du, C. Y.; Chen, M.;Wang,W. G.; Yin, G. P.; Shi, P. F. Electrochem. Commun. 2010, 12, 843.
16. [16]
  (16) Qiu, C. C.; Shang, R.; Xie, Y. F. ; Bu, Y. R. ; Li, C. Y. ; Ma, H. Y. Mater. Chem. Phys. 2010, 120, 323.
17. [17]
  (17) Shobha, T.; Aravinda, C. L.; Parthasarathi, B.; mathi, D. L.; Mayanna, S. M. Mater. Chem. Phys. 2003, 80, 656.
18. [18]
  (18) Yang, F. Z.; Huang, L.; Xu, S. K.; Zhou, S. M. Acta. Phys.-Chim. Sin. 2004, 20,463.
19. [19]
  [杨防祖, 黄令, 许书楷, 周绍民. 物理化学学报, 2004, 20,463.]
20. [20]
  (19) Danaee, I.; Shoghi, F.; Dehghani, M. M.; Kameli, M. J. Solid State Electrochem. 2010, 14, 57.
21. [21]
  (20) Safonova, T. Y. ; Khairullin, D. R.; Tsirlina, G. A.; Petrii, O. A.; Vassiliev, S. Y. Electrochim. Acta 2005, 50, 4752.
22. [22]
  (21) Fletcher, S. Electrochim. Acta 1983, 28, 917.
23. [23]
  (22) Fletcher, S.; Halliday, C. S.; Gates, D.;Westcott, M.; Lwin, T.; Nelson, G. J. Electroanal. Chem. 1983, 159, 267.
24. [24]
  (23) Alvarez, A. E.; Salinas, D. R. Electrochim. Acta 2010, 55, 3714.
25. [25]
  (24) Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamental and Applications, 2nd ed.; JohnWiley: New York, 2001; pp 228-239.
26. [26]
  (25) Feng, G.; Xiong, Y.;Wang, H.; Yang, Y. Electrochim. Acta 2008, 53, 8253.
27. [27]
  (26) Heerman, L.; Tarallo, A. J. Electroanal. Chem. 1998, 451, 101.
28. [28]
  (27) Michailova, E.; Milchev, A. J. Appl. Electrochem. 1991, 21, 170.
1. [1]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
2. [2]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
3. [3]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
4. [4]
  Yan Xiao , Shuling Li , Yifan Li , Jianing Fan , Linlin Shi . Discovering the Beauty of Life: Adding Some “Ingredients” to Crystals. University Chemistry, 2024, 39(6): 366-372. doi: 10.3866/PKU.DXHX202312025
5. [5]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
6. [6]
  Na Li , Limin Shao . Deduction of the General Formula of the Inverse Function of the Titration Curve. University Chemistry, 2025, 40(3): 390-401. doi: 10.12461/PKU.DXHX202409134
7. [7]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
8. [8]
  Xuewei Qian , Xingwen Sun , Houjin Li , Zhanxiang Liu , Yuan Zheng , Lin Wu , Shuanglian Cai , Ying Xiong , Guangao Yu , Qingwen Liu , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Shuyong Zhang , Jianrong Zhang . Basic Operations and Specification Suggestions for Organic Chemical Recrystallization Experiments. University Chemistry, 2025, 40(5): 66-75. doi: 10.12461/PKU.DXHX202503126
9. [9]
  Chengshan Yuan , Xiaolong Li , Xiuping Yang , Xiangfeng Shao , Zitong Liu , Xiaolei Wang , Yongwen Shen . Standardized Operational Guidelines for Mixed-Solvent Recrystallization in Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 122-127. doi: 10.12461/PKU.DXHX202504073
10. [10]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
11. [11]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
12. [12]
  Xueting Cao , Shuangshuang Cha , Ming Gong . 电催化反应中的界面双电层：理论、表征与应用. Acta Physico-Chimica Sinica, 2025, 41(5): 100041-. doi: 10.1016/j.actphy.2024.100041
13. [13]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
16. [16]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
17. [17]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
18. [18]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
19. [19]
  Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206
20. [20]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

Get Citation

PDF

XML

Metrics

PDF Downloads(1175)
Abstract views(2283)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142