Citation: JIANG Gui-Ming, GAO Bao-Jiao, XU Wen-Mei, WANG Xiao-Hua. Adsorption Behavior and Thermodynamics of Iminodiacetic Acid-Type Material IDAA-PGMA/SiO₂ for Heavy Metal Ions and Rare Earth Ions[J]. Acta Physico-Chimica Sinica, ;2011, 27(06): 1474-1481. doi: 10.3866/PKU.WHXB20110529 shu

Adsorption Behavior and Thermodynamics of Iminodiacetic Acid-Type Material IDAA-PGMA/SiO₂ for Heavy Metal Ions and Rare Earth Ions

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, P. R. China

Received Date: 31 December 2010
Available Online: 15 April 2011
Fund Project: 山西省自然科学基金(201002100843)资助项目 (201002100843)

Glycidyl methacrylate (GMA) was grafted onto micron-sized silica gel particles and the grafted particles of PGMA/SiO₂ were obtained. Subsequently, a ring-opening reaction of the epoxy groups on the grafted PGMA was carried out using iminodiacetic acid (IDAA) as a reagent, which resulted in IDAA group bonding and in the preparation of the composite chelating particles IDAA-PGMA/SiO₂. In this work, the adsorption behavior and adsorption thermodynamics of IDAA-PGMA/SiO₂ toward heavy metal ions and rare earth ions were investigated, and the adsorption mechanism was investigated in depth. The experimental results show that the particles IDAA-PGMA/SiO₂ possess strong adsorption action for heavy metal ions and the adsorption capacity of the Pb²⁺ ions reached 0.235 g·g^-1. The adsorption of heavy metal ions on IDAA-PGMA/SiO₂ is exothermic and is driven by enthalpy, leading to a decrease in the adsorption capacity as temperature is raised. The adsorption of rare earth ions on IDAA-PGMA/SiO₂ is driven by entropy. The adsorption ability of IDAA-PGMA/SiO₂ toward heavy ions is much stronger than that toward the rare earth ions.
- Iminodiacetic acid,
- Glycidyl methacrylate,
- Chelating action,
- Heavy metal ion,
- Rare earth ion
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沈阳化工大学材料科学与工程学院沈阳 110142

Adsorption Behavior and Thermodynamics of Iminodiacetic Acid-Type Material IDAA-PGMA/SiO2 for Heavy Metal Ions and Rare Earth Ions

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通讯作者: 陈斌, bchen63@163.com

Adsorption Behavior and Thermodynamics of Iminodiacetic Acid-Type Material IDAA-PGMA/SiO₂ for Heavy Metal Ions and Rare Earth Ions