Citation: ZHANG Yi, CHEN Biao, YANG Zu-Pei, ZHANG Zhi-Jun. Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1261-1266. doi: 10.3866/PKU.WHXB20110512 shu

Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites

ZHANG Yi ^1,2 ,
CHEN Biao ² ,
YANG Zu-Pei ^1, ,
ZHANG Zhi-Jun ^2,

1.
1. School of Chemistry and Materials Science, Shaanxi Normal University, Xi′an 710062, P. R. China;
2. Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, P. R. China

Received Date: 3 January 2011
Available Online: 31 March 2011
Fund Project: 国家自然科学基金(20873090, 21073224)资助项目 (20873090, 21073224)

Fe₃O₄ nanoparticle-graphene oxide (M ) composites were prepared by chemically binding carboxylic acid-modified Fe₃O₄ nanoparticles to polyethylenimine-functionalized graphene oxide ( ). The structure, morphology, and magnetic properties of the composites were characterized by transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), and vibrating sample magnetometry (VSM). The results show that the Fe₃O₄ nanoparticle content in the M composites can be easily controlled by changing the ratio of Fe₃O₄ nanoparticles to in the reaction mixture. The M composites obtained are superparamagnetic with high saturation magnetization, which can potentially be applied in magnetic targeted drug delivery, gene transport, magnetic resonance imaging, bioseparation, and magnetic guided removal of aromatic contaminants in waste water and in other fields.
- Graphene oxide,
- Fe₃O₄ nanoparticle,
- Composite,
- Controlled synthesis,
- Characterization
1. [1]
  
  (1) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
2. [2]
  (2) Shen, J. F.; Hu, Y. Z.; Shi, M.; Li, N.; Ma, H. W.; Ye, M. X. J. Phys. Chem. C 2010, 114, 1498.
3. [3]
  (3) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science 2004, 306, 666.
4. [4]
  (4) Berger, C.; Song, Z. M.; Li, T. B.; Li, X. B.; Ogbazghi, A. Y.; Feng, R.; Dai, Z. T.; Marchenkov, A. N.; Conrad, E. H. J. Phys. Chem. B 2004, 108, 19912.
5. [5]
  (5) Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K. M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Nature 2006, 442, 282.
6. [6]
  (6) Di, C. A.; Wei, D. C.; Yu, G.; Liu, Y. Q.; Guo, Y. L.; Zhu, D. B. Adv. Mater. 2008, 20, 3289.
7. [7]
  (7) Wu, J. S.; Pisula, W.; Mullen, K. Chem. Rev. 2007, 107, 718.
8. [8]
  (8) Huang, J.; Zhang, L. M.; Chen, B.; Ji, N.; Chen, F. H.; Zhang, Y.; Zhang Z. J. Nanoscale 2010, 2, 2733.
9. [9]
  (9) Zhang, X. Y.; Yang, X. Y.; Ma, Y. F.; Huang, Y.; Chen, Y. S. Journal of Nanoscience and Nanotechnology 2010, 10, 2984.
10. [10]
  (10) Yang, X. Y.; Zhang, X. Y.; Ma, Y. F.; Huang, Y.; Wangand, Y. S.; Chen, Y. S. J. Mater. Chem. 2009, 19, 2710.
11. [11]
  (11) Zhang, L. M.; Xia, J. G.; Zhao, Q. H.; Liu, L. W.; Zhang, Z. J. Small 2010, 6, 537.
12. [12]
  (12) Si, Y. C.; Samulski, E. T. Chem. Mater. 2008, 20, 6792.
13. [13]
  (13) Muszynski, R.; Seger, B.; Kamat, P. V. J. Phys. Chem. C 2008, 112, 5263.
14. [14]
  (14) Xu, C.; Wang, X.; Zhu, J. W. J. Phys. Chem. C 2008, 112, 19841.
15. [15]
  (15) Cong, H. P.; He, J. J.; Lu, Y.; Yu, S. H. Small 2010, 6, 169.
16. [16]
  (16) He, F.; Fan, J. T.; Ma, D.; Zhang, L. M.; Leung, C. W.; Chan, H. L. Carbon 2010, 48, 3139.
17. [17]
  (17) Zhang, Y.; Chen, B.; Zhang, L. M.; Huang, J.; Chen, F. H.; Yang, Z. P.; Yao. J. L.; Zhang, Z. J. Nanoscale, published online: 07 Feb, 2011, DOI: 10.1039/C0NR00776E.
18. [18]
  (18) Sun, S. H.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.; Wang, S. X.; Li, G. X. J. Am. Chem. Soc. 2004, 126, 273.
19. [19]
  (19) Chen, Z. P.; Zhang, Y.; Xu, K.; Xu, R. Z.; Liu, J. W.; Gu, N. Journal of Nanoscience and Nanotechnology 2008, 8, 12.
20. [20]
  (20) Hummers, W.; Offeman, R. J. Am. Chem. Soc. 1958, 80, 1339.
21. [21]
  (21) Zhu, C. X.; Peng, D. F. Speciality Petrochemicals 2010, 27, 57.
22. [22]
  (22) Paredes, J. I.; Villar-Rodil, S.; Solis-Fernandez, P.; Martinez-Alonso, A.; Tascon, J. M. D. Langmuir 2009, 25, 5957.
23. [23]
  (23) Bourlinos, A. B.; urnis, D.; Petridis, D.; Szabo, T.; Szeri, A.; Dekany, I. Langmuir 2003, 19, 6050.
24. [24]
  (24) Stankovich, S. S.; Piner, R. D.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2006, 44, 3342.
25. [25]
  (25) Chin, S. F.; Iyer, K. S.; Raston, C. L. Lab. Chip. 2008, 8, 439.
26. [26]
  (26) Rocchiccioli-Deltche, C.; Franck, R.; Cabuil, V.; Massart, R. J. Chem. Res. 1987, 5, 126.
27. [27]
  (27) Popplewell, J.; Sakhnini, L. J. Magn. Mater. 1995, 142, 72.
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Controlled Synthesis and Characterization of the Structure and Property of Fe₃O₄ Nanoparticle-Graphene Oxide Composites