Citation: HE Sheng-Nan, CUI Ya-Juan, YAO Yan-Ling, FANG Rui-Mei, SHI Zhong-Hua, NG Mao-Chu, CHEN Yao-Qiang. Effects of Alkaline Earth Metal on Performance of ZrO₂-Al₂O₃ Support and Pd-Rh Close-Coupled Catalyst[J]. Acta Physico-Chimica Sinica, ;2011, 27(05): 1157-1162. doi: 10.3866/PKU.WHXB20110509 shu

Effects of Alkaline Earth Metal on Performance of ZrO₂-Al₂O₃ Support and Pd-Rh Close-Coupled Catalyst

1.
Key Laboratory of Green Chemistry & Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Received Date: 10 January 2011
Available Online: 30 March 2011
Fund Project: 国家自然科学基金(20773090, 20803049) (20773090, 20803049)教育部博士点新教师基金(20070610026)资助项目 (20070610026)

A series of alumina supports stabilized by alkaline earth metals and zirconia were prepared by the peptizing method. Pd-Rh close-coupled catalysts supported on modified alumina were prepared by the impregnation method. The supports were characterized by low temperature nitrogen adsorption-desorption method, X-ray diffraction (XRD), and NH3-temperature programmed desorption (NH3-TPD). For the catalysts, H₂-temperature programmed reduction (H₂-TPR) and X-ray photoelectron spectroscopy (XPS) were carried out. We also carried out catalytic activity tests for C₃H₈ conversion. Results show that the addition of alkaline earth metals increases the surface area of the supports and the surface area of Sr-Zr-Al reaches 164 m²·g^-1 after calcination at 1000 °C for 5 h. The introduction of alkaline earth metals into the ZrO₂-Al₂O₃ supports also improves their catalytic activity toward propane oxidation and the activities of the Pd-Rh catalysts containing alkaline earth metals are higher than that of the catalyst prepared with a ZrO₂-Al₂O₃ support.
- Alkaline earth metal,
- ZrO₂-Al₂O₃,
- Pd-Rh,
- Close-coupled catalyst,
- Propane
1. [1]
  
  (1) Heck, R. M.; Farrauto, R. J. Appl. Catal. 2001, 221, 443.
2. [2]
  (2) Kašpar, J.; Fornasiero, P.; Hickey, N. Catal. Today 2003, 77, 419.
3. [3]
  (3) Farrauto, R. J.; Heck, R. M. Catal. Today 2000, 55, 179.
4. [4]
  (4) Shinjoh, H.; Hatanaka, M.; Nagai, Y.; Tanabe, T.; Takahashi, N.; Yoshida, T.; Miyake, Y. Top. Catal. 2009, 52, 1967.
5. [5]
  (5) Wilcox, L.; Burnside, G.; Kiranga, B.; Shekhawat, R.; Mazumder, M. K.; Hawk, R. M.; Lindquist, D. A. Chem. Mater. 2003, 15, 51.
6. [6]
  (6) Wu, X. D.; Yang, B.;Weng, D. J. Alloy. Compd. 2004, 376, 241.
7. [7]
  (7) Yue, B. H.; Zhou, R. X.; Zheng, X. M. Chin. J. Inorg. Chem. 2007, 23, 533.
8. [8]
  [岳宝华, 周仁贤, 郑小明. 无机化学学报, 2007, 23, 533.]
9. [9]
  (8) Liotta, L. F.; Macaluso, A.; Arena, G. E.; Livi, M.; Centi, G.; Deganello, G. Catal. Today 2002, 75, 439.
10. [10]
  (9) ng, M. C.;Wen, M.; Zhang, J.; Lin, Z. E.; Yang, Y. H.; Chen, Y. Q. Chin. J. Inorg. Chem. 2001, 17, 50.
11. [11]
  [龚茂初, 文梅, 章洁, 林之恩, 羊彦衡, 陈耀强. 无机化学学报, 2001, 17, 50.]
12. [12]
  (10) Church, J. S.; Cant, N.W.; Trimm, D. L. Appl. Catal. 1993, 101, 105.
13. [13]
  (11) Horiuchi, T.; Teshima, Y.; Osaki, T.; Sugiyama, T.; Suzuki, K.; Mori, T. Catal. Lett. 1999, 62, 107.
14. [14]
  (12) Zhang, L. J.; Dong,W. P.; Guo, J. X.; Yuan, S. H.; Zhang, L.; ng, M. C.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 1738.
15. [15]
  [张丽娟, 董文萍, 郭家秀, 袁书华, 张磊, 龚茂初, 陈耀强. 物理化学学报, 2007, 23, 1738.]
16. [16]
  (13) Guo, J. X.; ng, M. C.; Yuan, S. H.; Chen, Y. Q. J. Rare Earths 2006, 24, 554.
17. [17]
  [郭家秀, 龚茂初, 袁书华, 陈耀强. 稀土学报, 2006, 24, 554.]
18. [18]
  (14) Lassi, U.; Polvinen, R.; Suhonen, S.; Kallinen, K.; Savimäki, A.; Härkönen, M.; Valden, M.; Keiski, R. L. Appl. Catal. 2004, 263, 241.
19. [19]
  (15) Zimowska, M.;Wagner, J. B.; Dziedzic, J.; Camra, J.; Borzecka-Prokop, B.; Najbar, M. Chem. Phys. Lett. 2006, 417, 137.
20. [20]
  (16) Asakura, K.; Iwasawa, Y. J. Phys. Chem. 1992, 96, 73.
21. [21]
  (17) Narui, K.; Furuta, K.; Yata, H.; Nishida, A.; Kohtoku, Y.; Matsuzaki, T. Catal. Today 1998, 45, 173.
22. [22]
  (18) Qin, D.; Lapszewicz, J.; Jiang, X. J. Catal. 1996, 159, 140.
23. [23]
  (19) Huang, W.; Zuo, Z. J.; Han, P. D.; Li, Z. H.; Zhao, T. D. J. Electr. Spectrosco. Relat. Phenom. 2009, 173, 88.
24. [24]
  (20) Benkhaled, M.; Morin, S.; Pichon, Ch.; Thomazeau, C.; Verdon, C.; Uzio, D. Appl. Catal. 2006, 312, 1.
25. [25]
  (21) Fujimoto, K. I.; Ribeiro, F. H.; Avalos-Borja, M.; Iglesia, E. J. Catal. 1998, 179, 431.
26. [26]
  (22) Li, X.; Meng, M.; Liu, Y.; Luo, J. Y. Chin. J. Catal. 2007, 28, 835.
27. [27]
  [李想, 孟明, 刘咏, 罗金勇. 催化学报, 2007, 28, 835.]
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Effects of Alkaline Earth Metal on Performance of ZrO₂-Al₂O₃ Support and Pd-Rh Close-Coupled Catalyst