Citation: WANG Yu, YU Gang, CAI Bin, ZHU Yue-Xiang, XIE You-Chang. Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 729-735. doi: 10.3866/PKU.WHXB20110321 shu

Delicately Controlled Synthesis of Mesoporous Carbon Materials with Thin Pore Walls

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 12 October 2010
Available Online: 15 February 2011
Fund Project: 国家自然科学基金(20773004) (20773004)国家重点基础研究发展规划项目(973) (2011CB808702)资助 (973) (2011CB808702)

Mesoporous carbon materials with a range of pore sizes were synthesized by a delicately controlled procedure using disordered γ-alumina as template and sucrose as carbon source. Under optimized conditions, the carbon materials had narrow pore size distribution, large surface area (>1000 m²·g^-1), large pore volume (up to 3.82 cm³·g^-1), high mesopore ratio (>99%), and thin pore walls with thickness of 1-2 graphene layers. In the present work, we employed three types of alumina, and investigated the correlation of their texture with that of the resultant carbon materials. A mechanism for the formation of the carbon materials was proposed and tested against experimental data. A carbon sample prepared by this method can approximately duplicate the pore structure of the template, if the carbon layer in the precursor carbon-covered alumina is complete and sufficiently robust. The mesopores of the carbons had two sources, one from the removal of the template particles and the other from the original pores of the template. Calculated pore volumes strongly support the proposed mechanism.
- Mesoporous carbon,
- Thin pore wall,
- Controllable synthesis,
- Disordered template,
- Mechanism,
- Alumina
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