Citation: HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong. Controlled Synthesis of Mesoporous MnO₂ Nanospindles[J]. Acta Physico-Chimica Sinica, ;2011, 27(03): 743-748. doi: 10.3866/PKU.WHXB20110318 shu

Controlled Synthesis of Mesoporous MnO₂ Nanospindles

1.
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China

Received Date: 27 September 2010
Available Online: 28 January 2011
Fund Project: 上海市纳米技术项目(0852nm00700) (0852nm00700)上海大学创新项目(A.10-0101-09-023)资助 (A.10-0101-09-023)

We synthesized mesoporous MnO₂ nanospindles by a one-step hydrothermal process in an aqueous solution of KMnO₄ and glucose. The structure, morphology, purity, and size of the products were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption (BET) measurements. The reaction time and concentrations of glucose influenced the final structures and shapes of the MnO₂ nanospindles. The length to diameter ratio of the MnCO₃ precursor nanospindles can be easily tuned from 1.35:1 to 2.89:1. A possible formation mechanism for the mesoporous MnO₂ nanospindles is proposed and discussed.
- Hydrothermal method,
- Spindle,
- MnO₂,
- Mesoporous
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沈阳化工大学材料科学与工程学院沈阳 110142

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Controlled Synthesis of Mesoporous MnO₂ Nanospindles