Citation: HAN Rong-Cheng, YU Min, SHA Yin-Lin. Interaction between CdSeS Quantum Dots and ld Nanoparticles in Solution[J]. Acta Physico-Chimica Sinica, ;2011, 27(01): 255-261. doi: 10.3866/PKU.WHXB20110135 shu

Interaction between CdSeS Quantum Dots and ld Nanoparticles in Solution

1.
1. Department of Biophysics, School of Basic Medical Sciences, Peking University, Beijing 100191, P. R. China;
2. Biomed-X Center, Peking University, Beijing 100871, P. R. China

Received Date: 29 July 2010
Available Online: 16 December 2010
Fund Project: 国家重点基础研究发展规划项目(2007CB935801)资助 (2007CB935801)

We studied the interaction between CdSeS quantum dots (QDs) and ld nanoparticles (AuNPs) in solution. We found that the photoluminescence (PL) intensity of the QDs was efficiently quenched by the AuNPs with extraordinarily high Stern-Volmer quenching constant (K_sv) values that approach 108 L·mol^-1. The quenching efficiency is strongly related to the spectral overlap and the distance between the QDs and AuNPs and is independent of solvent polaritym, ion strength, and pH value. These results suggest that this superquenching behavior can be attributed to a long-range (Förster-type) energy transfer. Our findings allow for the design of exquisite multiple örster resonance energy transfer (FRET)-based biosensors for the highly sensitive and simultaneous monitoring of multiple molecules in live cells.
- Quantum dots,
- ld nanoparticles,
- Quenching,
- Energy transfer
1. [1]
  
  1. Alivisatos, A. P. J. Phys. Chem., 1996, 100:13226
2. [2]
  2. Bruchez, M.; Moronne, M.; Gin, P.;Weiss, S.; Alivisatos, A. P.Science, 1998, 281: 2013
3. [3]
  3. Chan,W. C.W.; Nie, S. M. Science, 1998, 281: 2016
4. [4]
  4. Michalet, X.; Pinaud, F. F.; Bentolila, L. A.; Tsay, J. M.; Doose,S.; Li, J. J.; Sundaresan, G.;Wu, A. M.; Gambhir, S. S.;Weiss, S.Science, 2005, 307: 538
5. [5]
  5. Liu, X. O.; Atwater, M.;Wang, J. H.; Huo, Q. Colloids Surf. B,2007, 58: 3
6. [6]
  6. Dulkeith, E.; Morteani, A. C.; Niedereichholz, T.; Klar, T. A.;Feldmann, J.; Levi, S. A.; van Veggel, F. C. J. M.; Reinhoudt, D.N.; Moller, M.; Gittins, D. I. Phys. Rev. Lett., 2002, 89: 203002
7. [7]
  7. Dubertret, B.; Calame, M.; Libchaber, A. J. Nat. Biotechnol.,2001, 19: 680
8. [8]
  8. Du, H.; Disney, M. D.; Miller, B. L.; Krauss, T. D. J. Am. Chem.Soc., 2003, 125: 4012
9. [9]
  9. Nikoobakht, B.; Burda, C.; Braun, M.; Hun, M.; EI-Sayed, M. A.Photochem. Photobiol., 2002, 75: 591
10. [10]
  10. Gueroui, Z.; Libchaber, A. Phys. Rev. Lett., 2004, 93:166108
11. [11]
  11. Kulakovich, O.; Strekal, N.; Yaroshevich, A.; Maskevich, S.;Gaponenko, S.; Nabiev, I.;Wog n, U.; Artemyev, M. Nano Lett.,2002, 2: 1449
12. [12]
  12. Shimizu, K. T.;Woo,W. K.; Fisher, B. R.; Eisler, H. J.; Bawendi,M. G. Phys. Rev. Lett., 2002, 89:117401
13. [13]
  13. Dyadyusha, L.; Yin, H.; Jaiswal, S.; Brown, T.; Baumberg, J. J.;Booy, F. P.; Melvin, T. Chem. Commun., 2005: 3201
14. [14]
  14. Oh, E.; Hong, M. Y.; Lee, D.; Nam, S. H.; Yoon, H. C.; Kim, H. S.J. Am. Chem. Soc., 2005, 127: 3270
15. [15]
  15. Bailey, R. E.; Nie, S. M. J. Am. Chem. Soc., 2003, 125: 7100
16. [16]
  16. Jang, E.; Jun, S.; Pu, L. Chem. Commun., 2003: 2964
17. [17]
  17. Pellegrino, T.; Manna, L.; Kudera, S.; Liedl, T.; Koktysh, D.;Rogach, A. L.; Keller, S.; Radler, J.; Natile, G.; Parak,W. J. NanoLett., 2004, 4: 703
18. [18]
  18. Brust, M.;Walker, M.; Bethell, D.; Schiffrin, D.; Whyman, R.J. Chem. Soc., Chem. Commun., 1994, 7: 801
19. [19]
  19. Solt, JW; Geuze, H J. Eur. J. Cell Biol., 1985, 38: 87
20. [20]
  20. Birks, J. B.; Georghio, S. J. Phys. B- At. Mol. Opt. Phys., 1968, 1:958
21. [21]
  21. Eisenthal, K. B.; Siegel, S., J. Chem. Phys., 1964, 41, 652
22. [22]
  22. Bennett, R. G. J. Chem. Phys., 1964, 41: 3037
23. [23]
  23. Lakowicz, J. R. Principles of fluorescence spectroscopy. 3rd ed.Springer: 2006, 954-960
24. [24]
  24. Medintz, I. L.; Clapp, A. R.; Mattoussi, H.; ldman, E. R.;Fisher, B.; Mauro, J. M. Nature Materials, 2003, 2: 630
25. [25]
  25. Chen, L. H.; McBranch, D.W.;Wang, H. L.; Helgeson, R.;Wudl,F.; Whitten, D. G. Proc. Nat. Acad. Sci. U. S. A., 1999, 96: 12287
26. [26]
  26. Jiang, H.; Zhao, X. Y.; Schanze, K. S. Langmuir, 2006, 22: 5541
27. [27]
  27. Harrison, B. S.; Ramey, M. B.; Reynolds, J. R.; Schanze, K. S.J. Am. Chem. Soc., 2000, 122: 8561
28. [28]
  28. Guan, H. L.; Zhou, P.; Zhou, X. L.; He, Z. K. Talanta., 2008, 77:319
29. [29]
  29. Fan, C. H.;Wang, S.; Hong, J.W.; Bazan, G. C.; Plaxco, K.W.;Heeger, A. J. Proc. Nat. Acad. Sci. U. S. A., 2003, 100: 6297
30. [30]
  30. Swager, T. M. Acc. Chem. Res., 1998, 31: 201
31. [31]
  31. Demers, L. M.; Ostblom, M.; Zhang, H.; Jang, N. H.; Liedberg,B.; Mirkin, C. A. J. Am. Chem. Soc., 2002, 124: 11248.
32. [32]
  32. Storhofff, J. J.; Elghanian, R.; Mirkin, C. A.; Letsinger, R. L.Langmuir, 2002, 18: 6666
33. [33]
  33. Resch-Genger, U.; Grabolle, M.; Cavaliere-Jaricot, S.; Nitschke,R.; Nann, T. Nat. Methods, 2008, 5: 763
34. [34]
  34. Wang, F. B.; Peng, Y.; Fan, M. Y.; Liu, Y. N.; Huang, K. L. ActaPhys. -Chim. Sin., 2009, 25: 1125
35. [35]
  [王芳斌, 彭勇, 范美意, 刘又年, 黄可龙. 物理化学学报, 2009, 25: 1125]
36. [36]
  35. Ray, P. C.; Darbha, G. K.; Ray, A.;Walker, J.; Hardy,W.Plasmonics, 2007, 2: 173
37. [37]
  36. Greenham, N. C.; Peng, X. G.; Alivisatos, A. P. Phys. Rev. BCondens.Matter, 1996, 54: 17628
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