Citation: LIU Bai-Jun, MENG Qing-Lei, WANG Hui, MENG Qing-Min. Synthesis and Characterization of Al MCM-41 Mesoporous Molecular Sieves[J]. Acta Physico-Chimica Sinica, ;2010, 26(12): 3257-3262. doi: 10.3866/PKU.WHXB20101140 shu

Synthesis and Characterization of Al MCM-41 Mesoporous Molecular Sieves

1.
Key Laboratory of Catalysis, China National Petroleum Corporation, China University of Petroleum, Beijing 102249, P. R. China

Received Date: 3 July 2010
Available Online: 20 October 2010
Fund Project: 国家自然科学基金(20576077)资助项目 (20576077)

Al MCM-41 mesoporous molecular sieves were synthesized by a hydrothermal method at 110 °C using the cationic surfactant cetyltrimethylammonium bromide as a template, sodium silicate as the silicon source, and pseudoboehmite as the aluminum source. The obtained Al MCM-41 molecular sieve was characterized by X-ray powder diffraction (XRD), N₂ adsorption-desorption, solid-state ²⁹Si, ²⁷Al magic angle spinning nuclear magnetic resonance (MAS NMR), scanning electron microscopy (SEM), and pyridine adsorption in Fourier transform infrared (FTIR) spectroscopy. The results showed that the Al MCM-41 molecular sieves had an ordered hexa nal packed structure, high relative crystallinity, high BET surface area, large pore volume, and a narrow pore size distribution. Furthermore, strong bonding between the silicon atoms in the Al MCM-41 framework resulted in od crystallization. The presence of the four-coordinate aluminum in the framework resulted in higher acidity.
- Pseudoboehmite,
- Al MCM-41 mesoporous molecular sieves,
- Magic angle spinning nuclear magnetic resonance,
- Framework aluminum,
- Acidity
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