Citation: CHI Jun-Hong, WANG Juan. Synthesis, Morphology and Optical Properties of Mn Doped SnO2 One-Dimensional Nanostructures[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2306-2310. doi: 10.3866/PKU.WHXB20100820 shu

Synthesis, Morphology and Optical Properties of Mn Doped SnO2 One-Dimensional Nanostructures

CHI Jun-Hong ,
WANG Juan

1.
Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University, Lanzhou 730000, P. R. China

Received Date: 31 January 2010
Available Online: 24 June 2010
Fund Project: 国家自然科学基金青年科学基金(50901037) (50901037)国家基础科学人才培养基金(J0630313)资助项目 (J0630313)

Mn doped SnO₂ one-dimensional nanostructures (nanowires and nanobelts) were fabricated using catalyst assisted chemical vapor deposition (CVD). X-ray diffraction revealed a rutile structure of SnO₂ in all the products. The morphology and the growth mechanism of the products were sensitive to the fabrication temperature and the concentration of the gaseous source materials. The growth mechanisms of the nanowires and nanobelts can be ascribed to vapor-liquid-solid (VLS) and vapor-solid (VS) processes, respectively. Four new peaks appeared at 500, 543, 694, and 720 cm^-1 in the Raman spectra were attributed to the active infrared mode and the surface mode. A photolumines-cence peak was observed at 520 nm and the intensity of the peak was closely dependent on the concentration of oxygen vacancies.
- Nanostructure,
- Mn doped SnO₂,
- Chemical vapor deposition,
- Optical property,
- Growth mechanism
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