Citation: CHE Hong-Wei, HAN Shu-Hua, HOU Wan-Guo, LIU Ai-Feng. Novel Synthesis of Mesoporous Nanocrystalline Zirconia[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2177-2181. doi: 10.3866/PKU.WHXB20100803 shu

Novel Synthesis of Mesoporous Nanocrystalline Zirconia

1.
1. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China;
2. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, P. R. China

Received Date: 26 March 2010
Available Online: 25 May 2010
Fund Project: 国家自然科学基金(50572057)资助项目 (50572057)

A novel strategy involving the combination of soft-templating and the solid-liquid method (CSSL) is presented for the synthesis of mesoporous nanocrystalline zirconia with a high specific surface area. The mesostructured zirconia hybrid is firstly synthesized by the soft-templating method using 1-hexadecyl-3-methylimidazolium bromide (C₁₆mim⁺Br^-) as the structure-directing agent and zirconium sulphate as an inorganic precursor. It is then ground in the presence of solid copper nitrate followed by heat-treatment in air. The resulting zirconia material, after calcination at 600 ℃, possesses a wormlike arrangement of mesopores surrounded by tetra nal ZrO₂ nanocrystallites of ca 2.50 nm diameter. The Brunauer-Emmett-Teller (BET) surface area is 240.0 m²·g^-1 and the pore size is 4.10 nm. However, no mesoporous structure exists in the obtained zirconia material that was produced using the simple soft-templating method at the same calcination temperature. The BET surface area is only 9.5 m²·g^-1 for this material.
- Mesoporous,
- Zirconia,
- Nanocrystalline,
- Soft-templating method,
- Thermal stability
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沈阳化工大学材料科学与工程学院沈阳 110142