Home

Citation: LI Xiao-Jing, LI Jing, WANG Chuan-Kui. Two-Photon Absorption Properties of Two Kinds of Compounds with Fluorene as Centre[J]. Acta Physico-Chimica Sinica, ;2009, 25(11): 2319-2324. doi: 10.3866/PKU.WHXB20091033 shu

Two-Photon Absorption Properties of Two Kinds of Compounds with Fluorene as Centre

1.
College of Physics and Electronics, Shandong Normal University, Jinan 250014, P. R. China

Received Date: 28 April 2009
Available Online: 9 September 2009

The two-photon absorption properties of two newly synthesized compounds containing fluorene as a π centre (denoted SK-G1 and NT-G1) were calculated using a response function method with density functional theory. Results show that both compounds have large one-photon and two-photon absorption abilities. In the low energy region, the maximum one-photon absorption strength of NT-G1 is twice as much as that of SK-G1 and its maximum absorption is red shifted compared to that for SK-G1. The maximum two-photon absorption cross section of NT-G1 is about five times as large as that of SK-G1 and those are found for the second excited states. Furthermore, NT-G1 has a wider two-photon absorption energy band. The optical properties of the molecules are closely related to their charge transfer processes when they are excited. The solvent effect on their one-photon absorption properties was calculated using the Onsager model. The numerical calculation is found to be in od agreement with experimental measurements.
- One-photon absorption,
- Two-photon absorption,
- Response function method,
- Molecule photonics
1. [1]
  Xiaojun Liu , Lang Qin , Yanlei Yu . Dynamic Manipulation of Photonic Bandgaps in Cholesteric Liquid Crystal Microdroplets for Applications. Acta Physico-Chimica Sinica, 2024, 40(5): 2305018-0. doi: 10.3866/PKU.WHXB202305018
2. [2]
  Zhiqing Jia , Xinju Gong , Di Lan , Huanhuan Sun , Yu Liu , Yuping Gao , Siyao Guo . Electrostatically induced dual-coupled interfaces of defect polarization enhanced PBA/MXene heterostructures for boosting electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100312-0. doi: 10.1016/j.actphy.2026.100312
3. [3]
  Bo Liang , Yuyijian Zhao , Siyu Wang , Shihan Huang , Fangke Zhou , Chuankun Zhang , Yue Wang , Xiaoming Guo . Synergistic molecular assembly and impedance matching in polyimide-derived porous carbon nanosheets for advanced microwave absorption. Acta Physico-Chimica Sinica, 2026, 42(6): 100285-0. doi: 10.1016/j.actphy.2026.100285
4. [4]
  Shihao Tan , Caiyun Cui , Shuwei Ma , Liangsen Zhu , Xianguo Liu . Introducing nanocrystalline/amorphous heterostructures on laminated FeSiBCr to synchronously enhance absorption, expand absorption bandwidth and reduce matching thickness. Acta Physico-Chimica Sinica, 2026, 42(7): 100283-. doi: 10.1016/j.actphy.2026.100283
5. [5]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
6. [6]
  Fengying Zhang , Yanglin Mei , Yuman Jiang , Shenshen Zheng , Kaibo Zheng , Ying Zhou . Research progress of transient absorption spectroscopy in solar energy conversion and utilization. Acta Physico-Chimica Sinica, 2025, 41(9): 100118-0. doi: 10.1016/j.actphy.2025.100118
7. [7]
  Peiru Fan , Lichun Zhang , Hongjie Song , Yi Lv , Rui Liu . Exploring Atomic Absorption Spectroscopy: From Phenomenon to Technological Innovation. University Chemistry, 2026, 41(2): 344-352. doi: 10.12461/PKU.DXHX202503038
8. [8]
  Cailin Song , Wenqi Liu , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Iron/Zinc/Copper/Manganese in Aloe vera and Ganoderma lucidum Using Flame Atomic Absorption Spectrometry. University Chemistry, 2026, 41(4): 356-362. doi: 10.12461/PKU.DXHX202505098
9. [9]
  Dongfang Liu , Di Lan , Yanze Yin , Junru Kong , Yanhong Meng , Yan Liu , Yaru Qiu , Guofei Xia , Dong Liu . Interface engineered Mo₂C high-performance electromagnetic absorption and thermal insulation. Acta Physico-Chimica Sinica, 2026, 42(7): 100275-. doi: 10.1016/j.actphy.2026.100275
10. [10]
  Tianzeng Liu , Di Lan , Shijie Zhang , Pei Wang , Shuhui Zhang , Xiaomiao Zhao , Xiaowei Liang , Zhiwei Zhao . Doping-regulated schottky interfaces for built-in electric field enhanced electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(7): 100289-. doi: 10.1016/j.actphy.2026.100289
11. [11]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
12. [12]
  Linghua Chen . 基于双联动“三学”模式的食品专业分析化学教学改革. University Chemistry, 2025, 40(8): 78-91. doi: 10.12461/PKU.DXHX202409095
13. [13]
  Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040
14. [14]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
15. [15]
  Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
16. [16]
  Lingling Li , Zhe Chen . Charge transfer mechanism investigation of S-scheme photocatalyst using soft X-ray absorption spectroscopy. Acta Physico-Chimica Sinica, 2026, 42(4): 100215-0. doi: 10.1016/j.actphy.2025.100215
17. [17]
  Yanan Liu , Xiaogang Su , Di Lan , Jiangyong Liu , Weihai Ma , Yaqing Liu . Bimetallic MOF-derived CoZn-C/MWCNTs composite for lightweight and wideband microwave absorption. Acta Physico-Chimica Sinica, 2026, 42(6): 100276-0. doi: 10.1016/j.actphy.2026.100276
18. [18]
  Shengdi Mao , Ruifeng Miao , Di Lan , Shijie Zhang , Jiguang Zhou , Xun Liu , Suxuan Du , Zhiwei Zhao , Guanglei Wu . Advances and challenges in flexible electromagnetic protection materials for electromagnetic interference shielding and wave absorption. Acta Physico-Chimica Sinica, 2026, 42(6): 100279-0. doi: 10.1016/j.actphy.2026.100279
19. [19]
  Renwei Feng , Congmin Fan , Di Lan , Lanxiang Liu , Qinchuan He , Yiqun Wang . Anchoring strategy-induced conductive loss in Ni-MOF@expanded graphite composites to achieve broadband microwave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100301-0. doi: 10.1016/j.actphy.2026.100301
20. [20]
  Weiheng Liu , Juhua Luo , Jiahuan Shi , Di Lan , Shuangshuang Mao , Yu Xie . Honeycomb-like BiCo@NC composites derived from bimetallic organic frameworks for high-efficiency electromagnetic wave absorption. Acta Physico-Chimica Sinica, 2026, 42(8): 100313-0. doi: 10.1016/j.actphy.2026.100313

Get Citation

PDF

XML

Metrics

PDF Downloads(1228)
Abstract views(2643)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return