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Citation: YU Yan-Chun, XIAO He-Ming. Synthesis, Structure and Hydration of Sodium Dioleyl Sulfosuccinate[J]. Acta Physico-Chimica Sinica, ;2009, 25(01): 30-34. doi: 10.3866/PKU.WHXB20090106 shu

Synthesis, Structure and Hydration of Sodium Dioleyl Sulfosuccinate

1.
Molecule and Material Computing Institution, Institute of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China; Institute of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, Jiangsu Province, P. R. China

Received Date: 1 July 2008
Available Online: 24 November 2008

The reaction yield of sodiumdioleyl sulfosuccinate (SDSS) was greatly improved by increasing the sulfonation reaction time, by replenishing NaHSO3 during the reaction and by purifying the product using extraction instead of recrystallization. The geometry and electronic structure of the anionic surfactant SDSS were fully optimized with density functional theory at B3LYP/6-31G* level. The trans isomer was more steady than the cis isomer. This was explained by protein extraction with reversed micelles of SDSS. The interaction between the anionic SDSS with H2O was also calculated at B3LYP/6-31G* level. The geometry, electronic structure and hydration energy of this interaction is also reported. The hydrophilic mechanismof the anionic SDSS was also determined.
- Surfactants; Sodiumdioleyl sulfosuccinate; Synthesis; Density functional theory; Hydration
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