Home

Citation: TONG Bo, TAN Zhi-Cheng, WANG Shao-Xu. Thermodynamic Properties of 1-Docosanol[J]. Acta Physico-Chimica Sinica, ;2008, 24(09): 1699-1702. doi: 10.3866/PKU.WHXB20080930 shu

Thermodynamic Properties of 1-Docosanol

1.
Thermochemisty Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China; College of Environmental & Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China

Received Date: 23 January 2008
Available Online: 4 July 2008

Heat capacity Cp,m of 1-docosanol was precisely measured in the temperature range from 78 to 400 K by means of an automated adiabatic calorimeter. The dependence of heat capacity on the temperature was fitted to polynomial equations with least square method. The melting temperature, molar enthalpy, and molar entropy of fusion were determined to be 340.844 K, 85.07 kJ·mol-1, and 249.6 J·K-1·mol-1, respectively. The thermodynamic functions, [HT-H298.15] and [ST-S298.15], were derived from the thermodynamic equations in the temperature range from 80 to 400 K with an interval of 5 K. The thermostability of the compound was further investigated by DSC and TG techniques from400 to 900 K.
- 1-Docosanol; Heat capacity; DSC; TG; Thermodynamic property
1. [1]
  Zihao Xu , Jia Yao , Xiaogang Peng . Statistical thermodynamics of heat capacity of liquid and gas. University Chemistry, 2026, 41(6): 92-99. doi: 10.12461/PKU.DXHX202511181
2. [2]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
3. [3]
  Chunguang Rong , Miaojun Xu , Xingde Xiang , Song Liu . 化学热力学熵变计算的教学探讨. University Chemistry, 2025, 40(8): 323-329. doi: 10.12461/PKU.DXHX202409146
4. [4]
  Youjun Fan , Xiuyun Wu , Wei Chen , Jianhua Qiu , Dongcheng Liu . Reflection on Standard States in Chemical Thermodynamics Teaching. University Chemistry, 2026, 41(6): 441-448. doi: 10.12461/PKU.DXHX202503051
5. [5]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
6. [6]
  Tongqi Ye , Yanqing Wang , Qi Wang , Huaiping Cong , Xianghua Kong , Yuewen Ye . Reform of Classical Thermodynamics Curriculum from the Perspective of Computational Chemistry. University Chemistry, 2025, 40(7): 387-392. doi: 10.12461/PKU.DXHX202409128
7. [7]
  Fengmei Wang , Xin Zhang , Hong Yan , Xiangyu Xu , Guirong Wang . Inverted 'Π' Graphic Memory Method for Thermodynamic Basic Equations and the Application in Teaching Practice. University Chemistry, 2025, 40(11): 369-375. doi: 10.12461/PKU.DXHX202412087
8. [8]
  Xiangming Feng , Jinyun Zheng , Ruoyu Cao , Dan Li , Xinxin Guan , Zhaohui Li , Weihua Chen , Jianmin Zhang . Visualization of throttling expansion and thermodynamic functions for Van der Waals gases. University Chemistry, 2026, 41(7): 401-405. doi: 10.12461/PKU.DXHX202506002
9. [9]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
10. [10]
  Ziyu Bai , Jiaxin Zhou , Sisi Zhao , Siyu Teng , Xinxin Li , Xiting Wang , Yuwei Dong , Zhen Zhao . Delving into the Captivating Color Transformation of Cobalt: Digital Empowerment of Intelligent Visual Robot Monitoring System for Measuring Thermodynamic Parameters. University Chemistry, 2026, 41(1): 122-132. doi: 10.12461/PKU.DXHX202505103
11. [11]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
12. [12]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
13. [13]
  Hongxiao Yang , Zhilian Liu , Weimin Zhang , Jitao Liu . Integratingscenario, knowledge, and problem lines in a problem-driven framework: teaching thermodynamics and kinetics in general chemistry. University Chemistry, 2026, 41(6): 100-107. doi: 10.12461/PKU.DXHX202511184
14. [14]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
15. [15]
  Qingtao Niu , Xinyao Xu , Weiyue Yu , Shuxiang Meng , Zhiguo Lv , Manman Jin . Exploration and Practice of Science-Education Integration in Chemical Engineering Thermodynamics Teaching for Chemical Engineering Majors: A Case of Chemical Engineering Physical Property Data Estimation and Chemical Reaction Equilibrium. University Chemistry, 2025, 40(10): 1-9. doi: 10.12461/PKU.DXHX202412029
16. [16]
  Weifeng Yu , Junqiao Zhuo . Stereoisomeric Analysis of Adamantane and Hexamethylenetetramine. University Chemistry, 2026, 41(6): 434-440. doi: 10.12461/PKU.DXHX202503125
17. [17]
  Xiqing Liang , Tian Zhao , Jiawei Li , Haohui Tan , Hai Chen , Liyan Zeng . Pentaerythritol’s Journey of Making Friends. University Chemistry, 2025, 40(10): 175-185. doi: 10.12461/PKU.DXHX202412009
18. [18]
  Zhanhui Yang , Aijun Gao . Clarifying the Chinese nomenclature of “pinacolyl alcohol” and “pinacol”. University Chemistry, 2026, 41(7): 455-458. doi: 10.12461/PKU.DXHX202506030
19. [19]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
20. [20]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111

Get Citation

PDF

XML

Metrics

PDF Downloads(1933)
Abstract views(4446)
HTML views(202)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return