Citation:
ZHOU Yong-Hua, YE Hong-Qi. Deposition of Pd Nano-Particles in W/O Microemulsion by Chemical Demulsifying[J]. Acta Physico-Chimica Sinica,
;2008, 24(03): 487-491.
doi:
10.3866/PKU.WHXB20080324
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Palladium nano-particles were synthesized by W/O microemulsion composed of nonionic surfactant (alkylpolyglycol ethers) named Marlipal O13/50, water and cyclohexane. The deposition of palladium nano-particles by chemicals demulsifying was investigated. The results showed that the sequence of deposition rate of palladium nano-particles from microemulsion under the action of different chemical demulsifier is 1,4-dioxane>THF>methanol>ethanol >n-butanol. The effects on interfacial tension and amphiphilicity of chemical demulsifier were studied. The results showed that the demulsifying process of microemulsion is also a process of interfacial tension increasing and a process gradually near to Lifschitz line.
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